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Hydroxy-5, 10-dihydrophenophosphazine 10-oxide (1) reacted with SOCl2, and then with MeONa in MeOH to give a methyl phosphinate (2) which can be converted to a dinitro compound 3 (62%) by nitration and the resulting dinitro compound 3 can further be converted to 2, 8-diamino-10-methoxy-5, 10-dihydrophenophosphazine 10-oxide (4, 71%) by hydrogenation over Pd/C (w = 0.05). And the effect of amount of Pd/C (w = 0.05) on the reduction was also studied.

10-羟基-5,10-二氢磷杂吖嗪-10-氧化物(1)经醯氯化、甲基化得到10-甲氧基-5, 10-二氢磷杂吖嗪-10-氧化物(2),2经硝化得到10-甲氧基-2,8-二硝基-5,10-二氢磷杂吖嗪-10-氧化物(3,62%)。3在Pd/C(w = 0.05)存在下,用氢气还原为2,8二氨基-10-甲氧基-5,10-二氢磷杂吖嗪-10-氧化物(4,71%),考察了Pd/C(w = 0.05)用量对氢化还原反应的影响。

From the investigation into the visible spectra and performances on textile of these azo dyes, as acid dye, it was found that these dyes had deep coloring effects on dyeing wool or silk, and five of which could dye wool into black one at 3% o. w. f., especially the diazo dye derived from 2, 8-diamino-10-methoxy-5, 10-dihydrophenophosphazine 10-oxide and acet-J-acid, it could not only dye wool into black one but each fastness of the obtained dyed sample was good.

对这些已知结构的染料进行浸染染色,结果发现,它们作为酸性染料,在羊毛及丝绸纤维上染色时,能够获得比一般偶氮染料不宜获得的深色效应,其中5支染料得到黑色染样,尤其由2,8-二氨基-10-甲氧基-5,10-二氢磷杂吖嗪与乙酰J-酸形成的双偶氮染料得到黑色染样,其各项牢度都比较理想。

The recent progress in molecular design and synthesis of polyborosilazane precurosors for SiBCN ceramics is reviewed.Especially the borazine modified polyborosilazane,monofunctional borane modified polyborosilazane on side chai...

本文分4个方面,即基于硼吖嗪的聚硼硅氮烷、侧基含有环硼氮烷或单硼烷的聚硼硅氮烷、基于多官能硼烷构筑的聚硅氮烷和含硼聚硅基碳化二亚胺,从聚硼硅氮烷分子结构设计、改性、合成及在多维尺寸材料中初步应用的角度综述了该领域国内外研究的新进展,指出了聚硼硅氮烷陶瓷前驱体设计合成研究发展中值得关注的新方向。

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In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

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