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With the electronegativity of heteroatom (such as sulfur, oxygen and nitrogen attaching directly to phosphorus) increasing, 31P NMR chemical shift moves to low field.

与磷相邻基团的电负性增加时,31P NMR化学位移向低场位移,如:杂原子硫、氧、氮,与磷直接相连将使磷谱向低场位移。

Using Hankel digital filter algorithm and inverse spine interpolation algorithm to simulate electromagnetic fields of the horizontal layers , we contrast the calculational Cagniard apparent resistivity with its results and field experimentation.

利用汉克尔数值滤波算法和逆样条插值算法对水平层状电磁场进行正演计算,并与计算的卡尼亚视电阻率的对比和野外试验结果表明:该方法的结果在远区等价卡尼亚电阻率,在近区和过渡带则明显地改善了卡尼亚电阻率的非波场区场畸变,从而能更好地接近基底的真电阻率,更形象地反映了地下介质的垂向电性变化。

Analyzing the relation between earthquake and structure distortion, main fault belt, crust, upper mantle, ground fracture, hotspring, geotherm, conductance frame, stress state in Guanzhong area is analyzed with earthquake mechanism, isoseismal line, crustal stress measure, fault displacement measure, and simulating test results. Earthquake formation mechanism is discussed with dynamics mechanism in Guanzhong base. There are 3 forces and a good medium environment, which are main reasons caused earthquake happened in Guanzhong area. The first force is NE and NEE level extrusion one which is parallel with long axis of Guanzhong base. The second one is level strain which is vertical with long axis of the base.

对地震与构造形变、主要断裂带、地壳及上地幔、地裂缝、温泉和地热、电性结构等关系进行了分析研究,通过震源机制解、地震等烈度线、地应力测量、断层位移测量及模拟试验等成果,分析了关中地区的地应力状态,从关中盆地的动力学机制,对该区的地震成因机制进行了探讨,认为与关中盆地长轴平行的NE和NEE向的水平挤压力、与盆地长轴方向垂直的水平张力及地幔上涌力三组力的作用,加之壳内高导层这一有利的介质环境,是导致关中地区地震发生的主要原因。

These important electrical characters are possibly caused by the India plate subduction to the north. The variation in characters of the large-scale conductive bodies from west to east may be the proof that plate collision causes substance moving to the east.

这些重要的电性特征可能是印度板块向北俯冲所形成的,深部大规模的良导体特征沿东西向的差异可能是板块碰撞引起物质沿东西向运移作用的结果。

These important electrical characters are possibly caused by the India plate un derthrusting to the north. The variation in characters of the largescale condu ctive bodies from west to east may be the proof that plate collision causes mate rials moving to the east

这些重要的电性特征可能是印度板块向北俯冲所形成的,深部大规模的良导体特征沿东西向的差异可能是板块碰撞引起物质沿东西向运移作用的结果。

Focused on the above two problems, the authors applied 2D finite cell numerical modeling to simulating the influence of the static effect on the TE, TM polarized apparent resistivity curves and the vertical resolution of conductive folia.

研究表明:TM模式视电阻率受静态影响严重,TE模式视电阻率对深部地质体的反映优于TM模式;TM极化模式放大了横向上不同电性体的电性差别,在山区找水中对断层反映敏感;AMT对导电薄层的垂向分辨力与围岩的电阻率比值有关,加密点距,并不能提高垂向分辨率。

This text introduces the work principle of the method of controlled source audio-frequency magnetotellurics, analies the effect of this method in detecting buried fault in coal mine, And the means of field exploration in a coal mine in Shanxi solves the problems in design and production of coal mines and, proves that the advance forecast of such method in detecting buried fault in coal mine is reliable.

本文介绍了可控源音频大地电磁测深法的工作原理,并对隐伏断层的电性特征进行了正演计算。通过在山西某煤矿的实地探测分析可知,隐伏正断层的异常表现一般为横向电阻率等值线发生错断、并伴有同向扭曲现象,有比较明显的密集梯度带。

The reservoir rock types in the region of interest are grain limestone, algal limestone, cryptite, siltstone, muddy limestone and mudstone. The thesis identified as a result of changes in the deposition causing the heterogeneity in plane, and then the geological oil reserves have been calculated in accordance with the areal heterogeneity.3、Based on the data of core analysis, bore logging, array induction imaging log and FMI, porosity and permeability model were built using regression analysis. Through testing 45 rock samples, a, b, m, n value were obtained and used to calculate single-layer oil saturation value using the Archie formula. According to the theory of laterolog and inductolog, resistivity ratio and cross plot were used to identification effective thickness. Effective thickness was identified delicately in 103 wells. Based on the over work, active porosity and oil saturation was calculated accurately.4、According to observation of 100 pieces of the thin slices, cast thin slices and 383m core in three wells, the chief diagenesis in this area were compaction, cementation, denudation and cataclasis. Cementation and denudation were universally influenced active porosity this area. The intergranular pores, residual pores and secondary pores were formed in thin carbonated reservoir of lacustrine facies.5、The influence of reservoir heterogeneity to reservoir calculation was analyzed systematically using actual data. And the conclusions were as follows:①The principal reason leading to oil distribution unequal is interior structural feature of reservoir in structural hydrocarbon reservoir.

确定了由于沉积微相的变化而导致的平面非均质性,进而在平面上按照平面非均质单元计算了石油地质储量。3、利用岩心分析、常规测井曲线与阵列感应、成像测井资料相结合,分岩性利用回归分析方法建立了储层孔隙度、渗透率模型;通过对45块岩样进行岩电试验,获取了a、b、m、n值,利用阿尔奇公式计算了各单层含油饱和度值;根据侧向电阻率和感应电阻率串并联特性,利用电阻率比值法与常规交会图法相结合重建了有效厚度图版,对全区103口井目的层段进行了有效厚度精细划分,通过以上工作,准确求取了储量计算单元内有效厚度参数、有效孔隙度参数以及含油饱和度参数。4、通过对研究区3口井383m岩心观察,100余块薄片、铸体薄片镜下鉴定得出:油泉子油田上、下油砂山组储层主要成岩作用是压实作用、胶结作用、溶蚀作用和破裂作用,其中溶蚀作用、胶结作用最普遍,这两种作用对有效孔隙度影响最大,以上成岩作用形成了原生粒间孔、粒间残余孔和次生孔隙(如粒间溶孔、粒内溶孔、铸模孔、晶间孔等)为主的薄层湖相碳酸盐岩储层。5、利用实际资料,系统分析了油藏非均质对储量计算的影响,认为:①对于构造油气藏而言,油气藏构造及断裂特征是造成油气分布不均的首要原因,储集条件相同的条件下,构造高部位有利于储存油气,油气在垂向的重力分异体现了油气藏内部构造的不均一特征。

Cage--like silsesquioxane is a kind of polyhedral compound,which iscomposited of organic and inorganic molecules.The structures of the cage—like silsesquioxane can be determined by 29Si NMR,effectively.Westudied the structures of six kinds of cage—like octa silsesquioxane by NMR.

通过对一类新型含硅材料一笼形倍半硅氧烷结构的研究,总结了这类化合物中29si NMR的影响因素,即取代基R的电负性是影响29si化学位移的主要因素,R电负性增强29Si化学位移移向高场。

The wave propagation and refraction of type "O" irregularities in the counter-electrojet conditions is investigated with a model electrojet in terms of the linear theory of the electrojet instability.

本文分析了反向赤道电射流条件下的不均匀性的对流放大特性。根据电射流不稳定性的线性理论,对一个分层均匀的电射流的模式的数值计算表明:在反向电射流条件下,电射流不均匀性有如下的特性:在波的传播过程中,在上电射流区内,波矢向下旋转,在下电射流区内,波矢向上旋转;在驱动电场E_D数值相同的情况下,反向电射流条件下的射线路径积分增长率r比正常电射流情况的要小得多。

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