后表面

The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力，结合它们的表面物理和化学性质的变化分析，确认微波改性活性炭的脱硫性能有显著提高，其作用机理在于微波处理后，活性炭表面微观形貌发生了较大的变化，化学基团发生分解，碱性特征增强，表面含氧量减少，以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加，吸附SO〓的表观活化能降低。

Preferential oxidation of Ti on NiTi alloy surface has been observed and was consistent with the experimental result and the free energy of formation A G?(298K) of NiO, TiO, TiO2. Mulliken population and the partial density of state analysis showed that the interaction between Ti and O atoms was mainly donated by O 2p and Ti 4s orbital and O 2p and Ti 3d, 4s, 4p hybridization orbital. The electron structure in NiTi bulk material was not altered during 62 molecule adsorption process and the surface passivation oxide formation.

进一步对钛与氧之间相互作用本质的研究表明，O 2p轨道和Ti 4s轨道以及O 2p轨道和Ti 3d 4s 4p杂化轨道间的相互作用是NiTi合金表面氧分子吸附的驱动力，在此过程中，NiTi合金的体相结构没有发生变化，从而保证了其一系列力学性能和形状记忆特性在表面氧化后不发生明显的变化，使表面改性的工作可以安全、可靠的完成而不影响其植入人体后发挥正常的生理功能。

Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明，出现在A组分中的2275～2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390～3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求，即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中；凝胶渗透色谱结果表明，成膜物质的A、B组分均为低分子量，符合预聚物的要求；涂膜表面能的测算结果表明，涂膜的表面能在33.6～47.17mN／m之间；加入碱式防污剂后涂膜的表面能略有升高；碱式防污剂的释放平稳，随着涂膜在海水中浸泡时间的增长，pH值有增加的趋势；用溶解度参数原则来评价涂料与网绳的涂装，结果表明，本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

Results: In surface anesthesia group, the anesthesia was satisfactory in all cases without additional use of retrobulbar or peribulbar anesthesia and no complication occurred.

结果：表面麻醉组中：30例(100％)均能较好配合手术，术中无一例需追加球周或球后麻醉。球后麻醉组中：球后出血、眼睑皮下出血、球结膜水肿及睑裂狭窄等发生率明显高于表面麻醉组(P.01)，1例发生球后出血，1例发生一过性黑蒙。

The weight percentage for the components of the hyaline coating is as follows: SiO2 45 to 54 percent, B2O3 15 to 20 percent, one or more of Na2O, K2O and Li2O, 10 to 24 percent, one or more of TiO2, ZrO2 and ZnO, 6 to 18 percent , and the rest is one or more of CaO, MgO and CeO2. Firstly, the glass powder is mixed with the mill additions to be pulped and then plated on the surface of titanium or the titanium alloy. After being dried, the surface of titanium or the titanium alloy is directly used for a thermal hydrogen treatment or smelted at a temperature of 900 to 1, 000 DEG C for 15 to 30 minutes and then a hyaline coating with a thickness of 20 to 70 micrometers is formed on the surface of titanium or the titanium alloy; secondly, titanium or the titanium alloy plated with the coating is conducted a thermal hydrogen treatment. After the treatment technique is finished, the coating flakes off automatically in the process of cooling; and finally, a surface treatment is supplemented to meet the requirement of the workpiece surface.

该玻璃质涂层成分按重量百分比：45-54SiO2，15-20B2O3，10-24Na2O、K2O、Li2O中的一种或多种，6-18TiO2、ZrO2、ZnO中的一种或多种，余量CaO、MgO、CeO2一种或多种，将玻璃粉与磨加物混合制浆并涂覆在钛或钛合金表面，干燥后直接用于热氢处理，或在900-1000℃下熔烧15-30min，在钛或钛合金表面制得20-70微米玻璃质涂层，随后将制有该涂层的钛或钛合金置于氢气气氛下进行热氢处理，处理工艺结束后，涂层在冷却过程中自剥落，最后辅以表面处理即可满足工件表面要求。

Between 4-9L exposures, C2H4 has a desorption channel at 155-180K. C2H4 desorption at 130K maybe results from BrCH2CH2Br absorbs in Br atom toward surfaces, after C-Br bond scission, because C2H4 has no opportunity to touch surfaces so it desorbs at low temperature. C2H4 desorption at 210K is likely to be desorption limited that, BrCH2CH2Br docomposes to C2H4, only to desorb at higher temperature. This C2H4 desorption channel maybe comes from defect site desorption.

曝露量在4-9L之间，C2H4在155至180K的范围内也有脱附的管道。130K的C2H4脱附可能是因为BrCH2CH2Br分子以Br原子朝向表面的方式吸附，在断了C-Br键后，C2H4分子没有机会接触到表面在低温就脱附了。210K的C2H4可能是脱附所决定的，亦即BrCH2CH2Br分解后在表面形成C2H4，随后温度升高至较高温才从表面脱附，此C2H4管道也许是来自缺陷位置上的脱附。

The strengths of the plain wood rose along with the compression ratio, while the bending strength and MOE lowered as it reached the maximum compression ratio; the plain wood compressed (33%) and heated 10h with 180℃. its bending strength lowered 40%, MOE lost about 50% and hardness lowered 12% than heated 0.5h; the properties not to be compressed after impregnated with PF resin. had a slow rising with the resin concentration, and compressed (33%) after impregnated with PF resin (30%). its bending strength, MOE and hardness increased 82.9%, 98% and 152% respectively.

三倍体毛白杨素材压缩后，其静曲强度和抗弯弹性模量均随压缩率的增大而提高，但接近最大压缩率时均下降；素材压缩（压缩率为33%）后以180℃空气加热处理10 h，静曲强度比同温度压缩保温0.5 h时下降约40%，抗弯弹性模量下降近50%，表面硬度下降约12%；用PF树脂浸渍处理后不经压缩，随PF树脂含量增加木材静曲强度提高幅度不大；用30%PF树脂浸渍后，当压缩率为33%时，其静曲强度、抗弯弹性模量和表面硬度分别比未压缩素材增加82.9%，98%和152%。

In order to disclosure the reason why the electrocatalysis activeness and selectivity droped after being used several hundred hours continuously, the x-ray diffraction, scanning electron microscopy and energy dispersive spectroscope have been used to characterize the surface condition variations of Monel metal. The results indicated: Monel metal belongs to the Cu-Ni alloy around the electrolysis experiment.And after being used for 600hr, the surface layer element composition and geometry distribution of the alloy changed, namely in the alloy the Cu element /which superficial free enthalpy was smaller,"concentrated" to the alloy surface,and formed one kind of marble structure microcrystallite.Thus the electrode surface becamed rough a

为了揭示蒙乃尔合金阴极在连续使用数百个小时后电催化活性剂选择性下降的原因，采用X射线衍射仪、电子扫描电镜和电子能谱分析仪对电解实验所用的蒙乃尔阴极材料在电解实验前后的表面状态进行了表征，结果表明：所使用的蒙乃尔合金阴极材料在电解实验前后均属于Cu-Ni合金，使用600hr后，由于表面层元素组成和几何排布发生了变化，即合金中表面自由焓较小的Cu元素向合金表面&富集&，形成一种大理石结构的微晶，表面粗糙、不均一，这是造成其对硝基苯电还原的催化活性及选择性随着使用时间延长而逐渐下降的主要原因，同时也为此类电极的修饰改进提供了方向。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。