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High speed countercurrent chromatography was successfully used for the separation and preparation of isomeric compounds .

应用高速逆流色谱法对同分异构体的分离纯化进行研究。

Any isomeric saturated hydrocarbon found in petroleum and used as a fuel and solvent .

这种碳氢化合物的任何一种同分异构体,见于石油中,用作燃料和溶剂。

Indicate by an arrow the position most likely to react in each of the following three isomeric nitrotoluenes.

答:用箭头标出与硝基甲苯的三种同分异构体发生反应最有可能发生的位置并解释。

Any of three colorless, flammable isomeric hydrocarbons, C5H12, derived from petroleum and used as solvents.

戊烷有三种同分异构体的无色可燃烷烃,c5h12,从石油中提炼,可用做溶剂

Both active components of plant herbs with an analogical isomeride structure were chosen as research targets. A combination of intrinsic fluorescence, UV-Vis, FTIR and the molecular modeling techniques has been used to characterize the binding between both flavones and human gammaglobulin.

将互为同分异构体的两种植物药活性组分山姜素和豆蔻明作为研究对象,应用荧光光谱法、紫外光谱法以及红外光谱法并结合分子对接技术首次对这两种黄酮类化合物与人-γ球蛋白(Human gammagobulin, HG)的相互作用进行了详细研究。

Isopentanol, nitrochlorobenzene, nitrotoluene and diethylbenzene were well separated in the range of optimal carrier gas velocity of 13~17cm/s.

SE-30系列毛细管色谱柱的最佳载气线这范因为13~17cm/s,且在最佳线速度下很好地分离了异戊醇、硝基氯苯、硝基甲苯及二乙苯同分异构体体系。

In this part, the densities of sodium benzoate, sodium nitrobenzoate, sodium chlorobenzoate and sodium methylbenzoate in DMFwater mixed solvents have been measured at 298.15K with an Anton Paar Model 55 densimeter. From these densities, apparent molar volumes and partial molar volumes have been calculated, transfer volumes from water to DMF-water mixtures and substituent contributions to the transfer volumes have also been obtained. Solvent and substituent effects are discussed in detail. The Scaled Partical Theory has been applied to the ternary solutions to evaluate the partial molar volumes of cavity formation and the volumes change associated with solute-solvent interaction.

选择了含有取代基团的芳香类有机电解质,主要是苯甲酸钠、硝基苯甲酸钠、氯苯甲酸钠和甲基苯甲酸钠的邻、间、对同分异构体作为研究对象,用DMA 55型振荡管密度计测定了它们在不同质量百分数组成的DMF-水混合溶剂中的密度,利用这些密度数据,计算了表观摩尔体积和偏摩尔体积,得到了这些单取代苯甲酸钠从水到DMF-水混合溶剂中的迁移偏摩尔体积及苯环上不同位置的取代基对迁移偏摩尔体积的贡献值,讨论了溶剂效应和取代基效应,并将定标粒子理论应用于此三元电解质溶液中。

The lowest surface tension of N_xB solution was better at 25℃, and lowest surface tension would down with carbon . cmc( critical micelle concentration) and γ_ in N_(12)B are 4.1 × 10~(-4)mol/L, 24.5 mN.m~(-1),what was smaller than LAS . The cmc of N_(12)B- NaCl are down with NaCl up.The surface tension and cmc of N_(12)B and N_(16)B are higher than that of N_(12)OB and N_(16)OB because of hydrophilic group ,but that of N_(12)B is lower than that of N_(16)B because of hydrophobic group .5. The borate structure and semipolar bond were studied in different pH by infrared spectrum .It indicated that N_xB and N_xOB have not semipolar bond at pH

4、25℃,N_xB系列都有较低的表面张力,并随碳原子数的增加而最低表面张力下降。N_(12)B比同碳原子数的十二烷基苯磺酸钠的最低表面张力34.5mN/m低,且临界胶束浓度为4.1×10~(-5)mol/L,也比LAS低,且随着NaCl浓度的增加而略有下降,比较N_(12)B和N_(16)B,由于C_(16)疏水基的异构体使N_(12)B的临界胶束浓度和临界胶束浓度时的表面张力γ_(cmc都低,由于增加了亲水基团使得N_(12)OB和N_(16)OB的表面张力和临界胶束浓度都要高于N_(12)B和N_(16)B。

Structural analysis reveals that the assemblies of these complexes are mainly directed by counter anions, followed with the change of anions from simple inorganic species (SCN~-/dca/Cl~-) to organic ones (ip/nip/tp/chdc), diversiform structures are formed varying from mononuclear, tetranuclear molecules to infinite 1-D and 2-D frameworks.

第三章利用4-bpt的同分异构体4-氨基-3,5-双(2-吡啶基)-1,2,4-三唑(2-bpt)作为螯合试剂,与多种无机/有机阴离子以及金属Cd~盐反应,得到了一系列Cd~配位化合物(7-15)。

Compounds 22 and 23 are attained with two-fold interpenetrated 3D frameworks through using 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene.

当采用配体1,4-双三氮唑时,得到了两个同构的化合物22和23,它们展示了二重穿插的3D框架。

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