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同分异构体

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Curing kinetics for two kinds of isomeric compound different proportion BPF-epoxy resin/MeTHPA/DMP-30 system is studied by means of differential scanning calorimetryand the extreme value method.

利用差示扫描量热法和极值法对两种同分异构体分布不同的双酚F环氧树脂/甲基四氢苯酐/DMP-30体系固化动力学进行了研究,求得了体系的固化动力学参数,并对同分异构体分布与固化特性之间的关系进行了初步讨论。

In addition nC〓, nC〓, two isomers of C〓 sterene and three isomers of C〓 isoprenoid hydrocarbons were also identified from aliphatic fraction of pyrolyzed product at 200℃. After pyrolyzed at 300℃, the main aliphatic hydrocarbons were normal alkanes ranged from C〓 to C〓, with C〓 as the main peak and C〓 as the second main peak. Meanwhile, pristane, phytane and C〓 sterane were also detected. In the pyrolysates at 400℃ and 500℃, the content of saturated hydrocarbons decreased, the range of normal alkanes distribution became narrow and the main peak was nC〓. Low concentration of C〓-C〓 steranes was detected and the content of C〓-C〓 increased more.

在200℃热模拟产物饱和烃馏分中除检测出两种长链烯烃外,还检测到正十九碳单烯烃、正三十五碳双烯烃、两个碳二十八甾烯的同分异构体和三个C〓类异戊二烯烷烃化合物同分异构体。300℃模拟产物饱和烃主要为正烷烃,正烷烃的碳数分布范围为C〓-C〓,以C〓为主峰、C〓为次主峰;另外,样品中还检出姥鲛烷、植烷和C〓甾烷等化合物。400和500℃热模拟产物中的饱和烃含量下降,正烷烃系列碳数分布范围变窄,主峰碳后移至C〓,检测到低浓度的C〓-C〓甾烷系列化合物,另外,C〓-C〓藿烷系列化合物含量进一步增加。

The optimal carrier gas velocity of prepared SE-30 series capillary chromatographic columns was studied and used to separate isomeric compounds. The efficiency of SE-30 capillary chromatographic columns has been studied with different diameters, film thicknesses and oven temperatures, using n-do-decane, phenol, aminobenzene, and butyl acetate as test samples.

研究自制的SE-30系列毛细管气相色谱柱的载气最佳线速度,并应用于同分异构体的色谱分离分别用十二烷、苯酚、苯胺、醋酸丁酯作试祥在不同载气线速条件下对不同口径、不同膜厚、不同柱温的SE-30毛细管色谱柱的柱效进行考察,并在最佳线速度条件下分离异戊醇、硝基氯苯、硝基甲苯及二乙苯同分异构体体系。

By means of molecular designing, a series of sodium branched-alkyl benzene sulfonates weresynthesized through seven process, involving Frieded-Crafts reaction, Grignard reaction, sulfonationand neutralization. Those isomers have similar structure, carbons of same quantity, but the position ofalkylaryl dissimilarity. Liner fat acid, metaxylene and halogenated hydrocarbon of different carbonnumber were used as the starting materials. Optimum processing condition was confirmed consideringinfluence of a series of reaction factors such as feed proportioning, quantity of catalysts, quantitysolvent, reaction time, temperature and pressure. Eight kinds of isomers of sodium hexadecylxylolsulfonates were finally synthesized, and characterized by FT-IR.

本文通过分子设计,以不同碳数直链脂肪酸、间二甲苯以及不同碳数的卤代烷为原料,经酰基化、格氏反应、加氢还原、磺化及中和等反应,合成了结构相似、烷烃链碳数一定、芳基在烷烃链不同位置的烷基芳基磺酸盐同分异构体;并考察了原料配比、催化剂用量、反应时间、反应温度、溶剂用量、反应压力等一系列因素对各反应的影响,进而确定最佳工艺条件,最终合成出十六烷基二甲苯磺酸钠的八种同分异构体,利用 FT-IR 对产物结构进行了分析。

There are three isomeric pentene(C5H10)that yield 2-methylbutane on catalytic hydrogenation. Write structural formulas for these three isomers and indicate their relative stabilities based on the ΔH values

答:戊烯的三种同分异构体在催化加氢后可生成2-甲基丁烷,写出3个同分异构体的结构式,并依据他们的ΔH值判断出它们的相对稳定性

Monosaccharide Isomerization Simple aldoses and ketoses containing the same number of carbon atoms are isomers of each other; that is, a hexose and a hexulose both have the empirical formula (C6 H1206 )and can be interconverted by isomerization.

单糖异构化含有相同数目碳原子的单醛糖和酮糖互为同分异构体,也就是说一个已醛糖和一个已酮糖都符合经验分子式C6 H1206,并且可通过异构化作用相互转化

There are some isomeric compounds of hydroxypyridinone. The compounds of 2-hydroxy-6-pyridinone have been used to dyestuff and pesticide widely. The compounds of 3-hydroxy-2-pyridinone and 3-hydroxy-4-pyridinone are paid attention to, because they are very useful heavy metal chelations. Especially, they are wonderful candidate medicament for the toxicosis of depleted uranium, so they can settle the DU jeopardize to the people.

羟基吡啶酮化合物有不同的同分异构体,2-羟基-6-吡啶酮已被广泛用于染料和农药行业,而3-羟基-2-吡啶酮和3-羟基-4-吡啶酮也引起了人们的重视,因为这两种异构体的化合物是非常理想的重金属络合剂,尤其重要的是,它可作为解决贫铀中毒的候选药物,有望解决战争中由于贫铀中毒带来的危害。

Following host injury, the balance between the epimers and isomers is a determining factor in the overall regulation of hematopoiesis, TH/TH(2) balance, and host resistance to infections and tumor growth.

在宿主损伤以后,雄甾烯的异构体和同分异构体之间的平衡是全部生血作用的控制、平衡细胞/体液免疫、宿主抗感染和抗肿瘤增殖的决定因素。

X+_ Following host injury, the balance between the epimers and isomers is a determining factor in the overall regulation of hematopoiesis, TH/TH(2) balance, and host resistance to infections and tumor growth.

在宿主损伤以后,雄甾烯的异构体和同分异构体之间的平衡是全部生血作用的控制、平衡细胞/体液免疫、宿主抗感染和抗肿瘤增殖的决定因素。8p*f:kz\-JT6Z,l

This paper introduces tests of constituents and isomeric compound contents of PXE、PEPE and M/DBT produced by several chemical plant by way of gas chromatography and gas chromatography-mass spectrograph combination , and also gibes some comments on present status and quality control of the insulation oil.

本文介绍了采用气相色谱分析及气质联用分析方法对各厂家生产的PXE、PEPE、M/DBT的组份及其同分异构体的含量进行测定的情况,对绝缘油品质的现状及质量的控制提出了一些见解。关键词:绝缘油;气相色谱;组分分析;同分异构体

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