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Using DC and AC poling methods, three groups of polarized PZT/P 70/30composites have been prepared by poling only the ceramic phase(1), both ceramic and polymerphases in the same(2) and opposite(3) directions. Piezoelectric coefficients of group 1 compositesincrease as the PZT content increasing, while for group 2 composites, the piezoelectric coefficientschange the sign with increasing PZT content because piezoelectricity of copolymer is increasinglycompensated by that of PZT, and PZT content for zero-〓 isn't that for zero-〓. The experimentdata of both group 1 and 2 composites agree well with EMT-Shin model.

对复合材料的压电性能:只极化PZT粒子相的复合材料的压电系数随陶瓷分数的增大而增大,PZT粒子相与共聚物基体同向极化的复合材料的压电系数由于两相效应的部分抵消,随陶瓷含量的增大,发生符号的改变,且〓和〓零点不重合,它们与EMT-Shin模型都符合较好;而两相反向极化的复合材料的压电系数由于AC反向极化会导致陶瓷相极化程度的下降,导致实验值和理论预期偏差较大,尤其在PZT粒子高含量区。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80~100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100~300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能,且合金内的V元素会向表面富集,因此,钛合金真空热处理和表面涂层的烧结温度不能过高,即应低于其相转变点;通过对生物活性梯度涂层的组成和结构的设计,分析和计算了梯度涂层内的应力大小和分布,结果表明:对于本研究,当成分分布系数n=1.5时,可以获得较合理的涂层力学性能,即在沉积开始时,采用富含BG颗粒的悬浮液,以便在钛合金侧获得同底层BG有良好过渡的富BG涂层;梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定,改变成分分布系数,只能改变涂层内应力变化的趋势;涂层的厚薄不影响涂层内的应力分布规律,但涂层越薄,涂层内的应力变化越快,但这并不意味着涂层越厚越好,因为涂层越厚,涂层允许的变形越小,对于应用于弯曲受力部位的涂层而言,涂层应薄一点为好(50μm);而对于仅纯受剪切应力的部位,如牙根种植体,涂层可适当加厚(80~100μm);通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现,它们在水溶液体系中很难发生电沉积;在无水乙醇溶液中,HA颗粒带正电,可在阴极钛合金片上发生均匀的电泳沉积,而BG颗粒则带负电荷;利用复分解反应法,可以制得100~300nm的HA,通过诱导HA在BG颗粒表面结晶,可对BG颗粒进行表面包覆,获得了被HA包覆的BG颗粒,改变了BG颗粒表面的带电特性,使BG和HA颗粒在无水乙醇中均带上正电荷,从而实现了HA和BG颗粒在阴极上的共沉积。

The lowest surface tension of N_xB solution was better at 25℃, and lowest surface tension would down with carbon . cmc( critical micelle concentration) and γ_ in N_(12)B are 4.1 × 10~(-4)mol/L, 24.5 mN.m~(-1),what was smaller than LAS . The cmc of N_(12)B- NaCl are down with NaCl up.The surface tension and cmc of N_(12)B and N_(16)B are higher than that of N_(12)OB and N_(16)OB because of hydrophilic group ,but that of N_(12)B is lower than that of N_(16)B because of hydrophobic group .5. The borate structure and semipolar bond were studied in different pH by infrared spectrum .It indicated that N_xB and N_xOB have not semipolar bond at pH

4、25℃,N_xB系列都有较低的表面张力,并随碳原子数的增加而最低表面张力下降。N_(12)B比同碳原子数的十二烷基苯磺酸钠的最低表面张力34.5mN/m低,且临界胶束浓度为4.1×10~(-5)mol/L,也比LAS低,且随着NaCl浓度的增加而略有下降,比较N_(12)B和N_(16)B,由于C_(16)疏水基的异构体使N_(12)B的临界胶束浓度和临界胶束浓度时的表面张力γ_(cmc都低,由于增加了亲水基团使得N_(12)OB和N_(16)OB的表面张力和临界胶束浓度都要高于N_(12)B和N_(16)B。

Hierarchical Clustering of 6 sheep populations based on 17 quantity indexes including body measurements, ecological and morphological characters indicates that 6 sheep populations can be classified in two types: the first includes Mongolia sheep and Tan sheep distributed in husbandry area and the juncture of agriculture and husbandry area, the second includes Daweihan sheep , Xiaoweihan sheep , Tong sheep , Hu sheep distributed in agriculture area.

以概括体尺、形态、生态特征的17项数量指标为基础的6个群体的系统聚类表明:6个绵羊群体被划分为二大类,一类为牧区及农牧交错区的蒙古羊、滩羊,另一类为农区的大尾寒羊、小尾寒羊、同羊、湖羊。17项数量指标的主成分分析,用已构造的各群体的主成份值进行R型系统聚类,获得与前者类似结果。

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