合金法

Stainless steel 35-42 °Be FeCl 3 35-55 Mild steel 35-42 °Be FeCl 3 35-55 Beryllium copper 30-42 °Be FeCl 3 or 40-55 ammoniacal copper or 33 °Be acidic CuCl 2 Copper and copper 30-42 °Be FeCl 3 or 40-55 alloys ammoniacal copper or 33 °Be acidic CuCl 2 Inconel and other 38-42 °Be FeCl 3 or 45-55 high nickel alloys conc nitric/conc hydrochloric acid/water 1:1:3 Aluminium 20% NaOH 60-90 or conc hydrochloric 20-65 acid/water 1:4 55 or alkaline potassium ferricyanide Brass 30-42 °Be FeCl 3 or 40-55 ammoniacal copper or 33 °Be acidic CuCl 2 Molybdenum Alkaline potassium 55 ferricyanide 40-55 or 40 °Be Fe(NO 3 ) 3 Titanium 10-50% HF 30-50 (optionally with HNO 3 )*The concentration of etchant (column 2) is measured in Degrees Baume where:°Be = 145 (SG - 1/SG); and SG is the specific gravity of the solution.

表美- 00002表2金属共同腐蚀剂*温度° C的不锈钢35-42 °成为氯化铁三 35-55低碳钢35-42 °成为氯化铁三 35-55铍铜30-42 °成为氯化铁3或40-55氨铜或33 °是酸性CuCl的2铜及铜30-42 °成为氯化铁三或40-55合金氨铜或33 °是酸性CuCl的2镍铬铁合金和其他38-42 °成为三氯化铁3或45-55高镍合金浓硝酸/浓盐酸/水1时01分03秒铝20％的NaOH浓盐酸60-90或20-65酸/水1：4 55或氰化钾铜30-42 °碱性钾成为三氯化铁3或40-55氨铜或33 °是酸性CuCl的二钾55钼碱性铁氰化钾40-55或40 °成为铁Fe（NO 3）3钛10-50％的HF 30-50*的浓度对侵蚀剂（栏2）测量波美度其中：°成为= 145（法兴- 1/SG）；和SG是比重。

In Ni-Al alloys the first peak position of Ni-Al pair correlation function is smaller than the sum of Ni and Al atomic radii, meaning a strong interaction between Ni and Al atoms and a chemical bonding with weak covalence.

计算表明，Ni-Al非晶态合金可以用猝冷法制备，它们的结构与液态Ni-Al合金类似但与液态合金相比更加有序且有部分晶化趋向。

The growth process of nanocrystalline copper particles into single crystals, induced by electron irradiation, has been observed by TEM, and Kikuchi lines exist in its electron diffiaction microphotograph, indicating that the thickness of the single crystal formed by electron irradiation is more than 100nm.

用γ射线辐照法成功地制备出Ag-Cu及Au-Cu合金粉末。通过改变实验条件如调节溶液中金属离子的浓度比则可控制所制备合金的组成。因此，发展γ射线辐照法制备合金粉末具有重要的应用价值。

Using JDM-30 strain gauge measurement and 4192A impedometer, effect of magnetization field and stress on the magnetostrictive properties d33, k33 and μ of the Fe83Ga17 alloy are measured.

采用真空感应熔炼法制备出铸态Fe83Ga17合金，用定向凝固的方法制备出取向多晶Fe83Ga17合金，使用JDM-30型磁致伸缩参数自动测量仪和4192A型阻抗分析仪，研究了磁化场和预压力对取向多晶Fe83Ga17合金磁致伸缩性能参数d33、k33及μ的影响。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80～100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100～300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能，且合金内的V元素会向表面富集，因此，钛合金真空热处理和表面涂层的烧结温度不能过高，即应低于其相转变点；通过对生物活性梯度涂层的组成和结构的设计，分析和计算了梯度涂层内的应力大小和分布，结果表明：对于本研究，当成分分布系数n=1.5时，可以获得较合理的涂层力学性能，即在沉积开始时，采用富含BG颗粒的悬浮液，以便在钛合金侧获得同底层BG有良好过渡的富BG涂层；梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定，改变成分分布系数，只能改变涂层内应力变化的趋势；涂层的厚薄不影响涂层内的应力分布规律，但涂层越薄，涂层内的应力变化越快，但这并不意味着涂层越厚越好，因为涂层越厚，涂层允许的变形越小，对于应用于弯曲受力部位的涂层而言，涂层应薄一点为好(50μm)；而对于仅纯受剪切应力的部位，如牙根种植体，涂层可适当加厚(80～100μm)；通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现，它们在水溶液体系中很难发生电沉积；在无水乙醇溶液中，HA颗粒带正电，可在阴极钛合金片上发生均匀的电泳沉积，而BG颗粒则带负电荷；利用复分解反应法，可以制得100～300nm的HA，通过诱导HA在BG颗粒表面结晶，可对BG颗粒进行表面包覆，获得了被HA包覆的BG颗粒，改变了BG颗粒表面的带电特性，使BG和HA颗粒在无水乙醇中均带上正电荷，从而实现了HA和BG颗粒在阴极上的共沉积。

The results show that the CNTs are dispersed effectively by bell jar immersing precast block casting. The maximal tensile strength and the elongation of the AZ31/CNTs composites are enhanced by 41.3% and 119.4%, respectively, and the elastic modulus and micro-hardness are also raised by 67.8% and 66.9%, respectively, when compared with those of the as-cast AZ31 Mg alloys. The CNTs can greatly refine the grains of the composites, playing a good role in reinforcing the matrixes of AZ31 Mg alloy. The fracture sections of the composites mainly consist of dimples and prisms, which demonstrates quasicleavage fracture modes.

结果表明：钟罩压块法可以有效地将碳纳米管分散到镁合金熔体中；CNTs对AZ31镁合金的力学性能有较强的增强效果，与本研究中的铸造AZ31合金相比，AZ31/CNTs复合材料的最大抗拉强度和伸长率分别提高41.3%和119.4%，弹性模量和显微硬度分别提高67.8%和66.9%；CNTs对AZ31镁合金基体晶粒的细化作用显著，与镁基体界面结合较好；复合材料试样断口形貌由韧窝和撕裂棱组成，呈现准解理断裂特征。

The results show that the CNTs are dispersed effectively by bell jar immersing precast block casting. The maximal tensile strength and the elongation of the AZ31/CNTs composites are enhanced by 41.3% and 119.4%, respectively, and the elastic modulus and micro-hardness are also raised by 67.8% and 66.9%, respectively, when compared with those of the as-cast AZ31 Mg alloys. The CNTs can greatly refine the grains of the composites, playing a good role in reinforcing the matrixes of AZ31 Mg alloy. The fracture sections of the composites mainly consist of dimples and prisms, which demonstrates quasi- cleavage fracture modes.

结果表明：钟罩压块法可以有效地将碳纳米管分散到镁合金熔体中；CNTs对AZ31镁合金的力学性能有较强的增强效果，与本研究中的铸造AZ31合金相比，AZ31/CNTs复合材料的最大抗拉强度和伸长率分别提高41.3%和119.4%，弹性模量和显微硬度分别提高67.8%和66.9%；CNTs对AZ31镁合金基体晶粒的细化作用显著，与镁基体界面结合较好；复合材料试样断口形貌由韧窝和撕裂棱组成，呈现准解理断裂特征。

This study was conducted to examiune the fibrotic effect of Ni-Ti and 317L al loys in esophagus.The extract fluid from Ni-Ti,317L alloys was made according t o the ASTM standards of U.S.A. The Fb of esophageal scar was cultured primarily ,then incubated with alloy abstract fluid. The proliferating activity of Fb was measured by MTT at 4, 24, 48, 72 hours in the course of culturing. The esophagu s embedding test of Ni-Ti,317L alloys was made according to ASTM standards of U .S.A.The tissue around the alloys was taken at weeks 2 and 12,and the pathologi c changes were analysed.

为探讨新型支架材料Ni-Ti、317L合金在食管局部的致纤维化作用，按美国ASTM标准制备NiTi、317L合金的金属浸提液；&组织块培养法&原代培养食管壁疤痕的成纤维细胞，传代后以金属浸提液进行培养，分组后分别培养4、24、48、72 h，MTT法检测不同培养时间后Fb增殖功能的变化；按美国ASTM标准进行NiTi、317L合金试件的食管壁内包埋实验，即将金属试件经表面处理后直接置入食管壁粘膜层与肌层之间，术后2、12周取出包埋组织，分析试件周围组织的病理变化，并进行胶原纤维染色，观察纤维形成状况。

Based on the study of 1420 Al-Li alloy strengthened by a single precipitate, the author study strengthening contributions and their anisotropies of each phase and that of deformed textures to anisotropy in 2090 and 2090+Ce alloys strengthened by two precipitates, by reversion treatment and the exponential additional rule.

在研究单相强化的1420合金的基础上，通过回溶处理和指数叠加法研究了两相强化的2090及2090+Ce合金中各析出相对合金的强化贡献及其各向异性、形变织构对合金各向异性的贡献。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。