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The reaction process in methanol solvent can be deduced from the computational results with CPCM solvent model and the supermolecular handling, namely the reaction involves four steps in the methanol solvent. The nucleophilic addition of trimethylamine to acraldehyde generates an enolate. Nucleophilic attack of the enolate on the aldehyde forms the carbon-carbon bond, followed by the proton-transfer process and the further elimination generating the product and liberating the trimethylamine catalyst.

对于CH3OH对反应体系的影响,可以综合考虑CPCM溶剂模型及超分子模型下的研究结果,即CH3OH溶剂中反应按四步进行,催化剂三甲胺首先与丙烯醛发生亲核加成,生成的两性离子中间体与甲醛发生类似于Aldol的醛醇缩合,形成碳-碳键,之后发生分子内质子转移,最后经E1cb消除得到产物,并释放催化剂三甲胺。

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体,初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用,20℃和20mol%催化剂量下,获得了32.5%ee和72%收率的产物。

The nucleophilic attack step of a classical Aldol reaction was studied using acetaldehyde anion and formaldehyde as reactants.

采用乙醛负离子和甲醛作为反应物,对经典的醛醇缩合反应中的亲核进攻步骤进行了研究。

Multistep deposition process has been adopted in the preparation of superfine inorganic composite antibacterial powder, Ag~+ as crystal nucleus, packed outside by the hydroxid and phosphate precipitate of Ti and Zr elements etc., The optimal process conditions have been found from one-factor influence tests and multi-factor orthogonal test,and the optimal process conditions were: Ag iron was imported by silver ammine, and then 100ml Titanyl sulphate solution mixing with zirconium sulfate keep hot at 90 ℃ for 30 mins, and the Zr/Ti ratio is 0.15,and Na_2HPO_4 was added in the end.

超细无机复合抗菌粉体的制备采用以Ag~+沉淀物作为晶核,外包裹Ti、Zr等金属的氢氧化物沉淀和磷酸盐沉淀物的多步沉淀工艺,并利用单因素和正交试验法对制备工艺进行了优化,其最佳工艺条件是:Ag~+以银氨络合物引入,沉淀钛锆的反应时间为0.5h,反应温度为90℃,水解反应时体系总液量为100ml、Zr/Ti为0.15,沉淀物经水洗、干燥,于700℃煅烧4.0h;即得最终产品。

As far as to be concerned, the allelopathic effects of Syngonium podophyllum extracts showed inhibition effect on Chlorella pyrenoidosa at first and then promotion effect, while Ficus microcarpa showed steadily inhibitory effects.

从化感作用的效果上看,合果芋浸提液对蛋白核小球藻呈现先抑制后促进的作用特性,而榕树浸提液始终具有抑制作用。

Key words:cerebral ischemia;dentate gyrus;learning and memory;bromodeoxyuridine;nitric oxide synthase

关键词]脑缺血;齿状回;学习记忆;5。溴脱氧尿核苷;一氧化氮合酶

"The determent policy has been dubbed MaD, an appropriate acronym which stands for mutual assured destruction."

"核禁政策称为MaD,很贴切,是表示保证互相毁灭的缩合字。"

The determent policy has been dubbed MAD , an appropriate acronym which stands for mutual assured

核禁政策称为 MAD ,很贴切,是表示保证互相毁灭的缩合字。

The determent policy is dubbed MAD, an appropriate acronym which stands for mutual assured destruction

核禁政策称为MAD,很贴切,是表示保证互相毁灭的缩合字

According literature above,its considerd that the former is proper to be interpreted by means of multiple alleles hypothesis,and the fertility heredity of the latter is appropriate to be interpreted using inhibition.

根据大白菜及其近缘芸薹属作物核不育材料育成的纯合两型系和杂合两型系可育株间互交F~1|可育株自交,其子代可能出现无育性分离情况或者产生13∶3两种表型的育性比资料,认为前者宜用复等位基因假说解释,而后者用抑制作用解释为妥。

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Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势,并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。

This dramatic range, steeper than the Himalayas, is the upturned rim of the eastern edge of Tibet, a plateau that has risen to 5 km in response to the slow but un stoppable collision of India with Asia that began about 55 million years ago and which continues unabated today.

这一引人注目的地域范围,比喜马拉雅山更加陡峭,是处于西藏东部边缘的朝上翻的边框地带。响应启始于约5500万年前的、缓慢的但却不可阻挡的印度与亚洲地壳板块碰撞,高原已上升至五千米,这种碰撞持续至今,毫无衰退。