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In this paper, various synthetic methods of coenzyme Q10 appeared in about half a century were reviewed with emphasis on the semi-chemosynthetic methods using natural solanesol extracted from tobacco as starting material. The key factors and development direction of coenzyme Q10 chemosynthesis were illustrated in this paper as well.

笔者根据半个世纪以来有关辅酶Q10化学合成的各种文献报道,对辅酶Q10现有的各种化学合成路线及其工艺优劣进行了介绍和比较,重点介绍了从烟草中提取天然茄尼醇为原料的半化学合成辅酶Q10方法,并阐明了化学合成辅酶Q10的关键因素和发展方向。

Pinacol reductive coupling reaction of aldehyde and ketone is one of the most important methods in forming C-C bond, which may also produce vicinal diol as valuable intermediate compound applied in the synthesise of natrual products.

醛酮的Pinacol还原偶联反应是合成C—C键的重要方法之一,同时合成的邻二醇类化合物是重要的有机合成中间体,已被应用于许多含有邻二醇结构的复杂天然化合物总合成中。

The results indicate that both the precipitates produced by Leptospirillum ferriphium strain DY and Acidirhiobacillus ferrooxidans strain GF are composed of jarosite and ammonium jarosite. However, the content of jarosite in the precipitates synthesized by strain GF is 5.53% higher than that synthesized by strain DY, but the content of ammonium jarosite in the precipitates synthesized by strain DY is 15.24% higher than that synthesized by strain GF.

结果表明:无论是嗜铁钩端螺旋菌DY菌株,还是嗜酸氧化亚铁硫杆菌GF菌株合成的沉淀都是黄钾铁矾和黄铵铁矾的混合物;其中,GF合成的沉淀混合物中黄钾铁矾的含量比DY合成的黄钾铁矾约高出5.53%;而DY合成的沉淀中,黄铵铁矾的含量比GF合成的沉淀中的黄铵铁矾的含量约高出15.24%。

In the paper the effects and main differences of maleic anhydride and acrylic acid in the synthesis of polycarboxylate superplasticizers are analyzed according to their respective characteristics and technical requirements for synthesis.

根据马来酸酐与丙烯酸各自的特性和聚羧酸盐减水剂合成的技术要求,分析了它们在合成过程中的作用和主要差别,并概述了马来酸酐在合成中的应用情况,最后提出了马来酸酐在合成中应用的几点建议。

We make chloroacetylaion to N-terminal of Asp, and then convert this compound to GD dipeptide by aminolysis. Followed the lipase -catalyzed peptide synthesis of RGD in aqueous water-miscible organic cosolvent is studied. We set up a new efficient reaction method to synthesize RGD tripeptide. The problem that peptide containing polar amino acid can not be synthesized readily in organic solvent was solved. We offer a new experimental proof for PPL-catalyzed peptide synthesis and make a more general analysis for the effect of some factors in theory.

采用氯乙酰基保护天冬氨酸,然后进行氨解生成GD二肽,利用猪胰脂肪酶催化合成RGD三肽,着重解决了亲水氨基酸/肽片段底物的溶解性与合成产率低的问题,建立了一种新的有效合成RGD三肽的反应模型,并探索解决了极性较强的氨基酸的酶促肽合成的问题,对脂肪酶催化合成肽的影响因素从理论上作了较全面的分析,为肽片段的缩合反应提供了一种新思路。

For TRO there are a little surfacatants whose effect are not good.In this paper,content of sulfonates and composition of alkyl are decided through right design ;under control reaction conditions different alkylbenzene sulfonates are synthesized;Polyreaction catalyst is developed .non-straight high carbon olefine are made through C9-C12 Polyreaction technolgy;clear composition alkylkenzene is sulfanated in falling-film reactor by SO,product can be adjusted,recipe of the surfacate can be used for super-low interfacialtension with Daqing oil -10-3-10-4mN/m,and stablity is good too.According to method issued by Daqing Develop and Explore Research institute,EOR is over 20% in natural core .

本文研究通过烷基苯磺酸盐组成的正确设计,确定了磺酸盐的当量范围和烷基碳数组成和分布;通过对烷基化条件控制,设计合成了不同碳数的直链和支链烷基苯及烷基二甲苯,并用于制备了相应的烷基苯磺酸盐;研制出了新型的烯烃叠合络合催化剂,采用C_9、C_(12)支链烯烃叠合工艺合成了更高碳数的支链烯烃,并进一步合成出相应的烷基苯和烷基二甲苯;以SO_3为磺化剂,通过对磺化条件的选择和控制,采用已知组成的烷基苯混合物进行膜式磺化反应,使合成工艺得以简化;所得磺酸盐组成确定并且可控,最终配方可与大庆原油形成超低界面张力,达10~3~10~(-4)mN/m数量级,且稳定性良好;以合成的烷基苯磺酸盐为主体形成了三元复合驱配方,室内驱油模拟实验表明,按照大庆研究院对复合驱体系活性剂的评价方法,在天然岩芯上的驱油效率在20%以上。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体,合成了七{2,6-二-O-[3-(1,3-二羟基丙氨酸)]}-β-环糊精,再用醋酸酐将其乙酰化,得到了一种淡黄色粘稠液体,合成了一种新型的环糊精衍生物;以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物,再将其烷基化和酰基化,合成了β-环糊精聚合物的不同衍生物,用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上,通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究,结果表明所合成的β-环糊精衍生物对各类化合物,特别是对位置异构体和对映异构体具有较好的分离效果,显示了很强的立体选择性。

After working backwards in this way from the complex to the already known, it is possible to start building, synthesising, the molecule.

他自己还运用逆合成分析法,在试管里合成了100种重要天然物质,在这之前人们认为天然物质是不可能用人工来合成的

The results implied that NO/ROS-induced ABA accumulation come from de novo synthesis pathway rather than degration of conjugated forms. The protein synthesis inhibitor actidone blocked the NO-induced ABA accumulation while having no effects on ROS-induced ABA accumulation, indicating that the action of NO was gene-expression dependent and that of ROS was gene-expression independent. These results suggested that NO may serve as a stress signal in the regulation of ABA-biosynthesis and ROS may serve as substrate in ABA biosynthesis or be involved in the regulation of enzyme activities.

1ABA合成抑制剂fluridone抑制ROS和NO诱导的ABA积累,表明NO/ROS诱导的ABA积累来源于ABA的从新合成而不是已有结合态ABA的代谢;(2)蛋白质合成抑制剂环己亚胺可以抑制NO诱导的ABA积累而对ROS诱导的ABA积累没有影响,说明NO的作用涉及基因表达而ROS的作用与基因表达无关,暗示NO的作用方式可能是作为一种干旱胁迫信号物质参与ABA合成的调节,而ROS则可能参与了相关酶活性的调节或直接参与了ABA合成的底物反应。

The ZSM-5 zeolite sieve was synthesized using aqueous ammonia and EDA as template agent.

利用氨水和乙二胺等为模板剂合成了ZSM-5沸石分子筛,研究了合成温度和时间对分子筛合成的影响。

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Plunder melds and run with this jewel!

掠夺melds和运行与此宝石!

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻,也许正是在通往天国的路上,我体验着这白色的晕旋。

When you click Save, you save the file to the host′s hard disk or server, not to your own machine.

单击"保存"会将文件保存到主持人的硬盘或服务器上,而不是您自己的计算机上。