合成物质

Synthesis of isopropyl chloroacetate catalyzed by acidic ionic liquids was studied,including influences of different ionic liquids,reaction temperature,reaction time and quantity of ionic liquid.

研究了功能化酸性离子液体催化合成氯乙酸异丙酯的反应，考察了不同离子液体、反应温度、反应时间和离子液体与反应物物质的量比等对反应的影响。

The optimum synthetic conditions of ethyl chloroacetate are: molar ratio of chloroacetic acid to ethanol is 1:8, the quantity of catalyst[Fe2(SO4)3 xH2O] is 10% of the mass of chloroacetic acid, reaction time is 1 hour, 5A zeolite was used as dehydrating agent. In these conditions, the yield of ethyl chloroacetate was up to 73%.

用Fe_2(SO_4)_3·xH_2O作为催化剂合成氯乙酸乙酯的较佳反应条件是：酸醇物质的量之比为1：8，催化剂用量为氯乙酸质量的10％，以5A分子筛作为脱水剂，回流时间1h，收率达73％以上。

The effects of cholic acid concentration and pH of the buffer on separation were studied, and the influences of organic additives such as methanol, acetonitrile, isopropyl alcohol were also examined.

该实验表明电化学检测同样可用于手性物质的分离，从而扩宽了电化学检测的应用范围，并为对映体的定量合成和纯度测定找到了灵敏的检测方法。

With the molar ratio of cobaltous nitrate, phenanthroline and Pyridine-3,4-dicarboxylic acid is 1∶2∶1,under the condition of pH=5,heating at 50-60℃ and stirring,the ternary complex of cobalt is synthesized in the methanol solution.

将硝酸钴、邻菲罗啉和3，4-二羧基吡啶按1∶2∶1物质的量比计量，在pH=5和50-60℃加热搅拌的条件下，在甲醇溶液中合成了钴的三元配合物，用元素分析、红外光谱、紫外光谱、热重分析和摩尔电导率对配合物进行表征，结果表明该配合物为1∶1型电解质，其组成为[CoⅢ2]NO3.H2O，其中Pydc=

By the analysis of HPLC,the amount of ganoderic acids in the fermentation broth was more abundant when cultured in Coix lachryma-jobi substrate than cultured in synthenic liquor substrate.

分析了主要活性物质在灵芝发酵前后的变化，结果表明：以薏苡仁为基质进行灵芝发酵后的发酵产物，其粗脂肪的总量有所下降，但亚油酸的含量升高；经 HPLC 分析，与以清液进行的灵芝发酵相比，以薏苡仁为基质进行的灵芝发酵在粗灵芝酸组成上是有差异的，合成的种类也更为丰富。

Avene THERMAL SPRING WATER,CYCLOMETHICONE,DECYL OLEATE,OCTYL SILYLATED TITANIUM DIOXIDE,GLYCERIN,C12-15 ALKYL BENZOATE,ZINC OXIDE,SODIUM CHLORIDE,DIMETHICONE COPOLYOL,GLYCERYL STEARATE,PETROLATUM,BUTYLPARABEN,CAPRYLIC/CAPRIC TRIGLYCERIDE,DISODIUM EDTA,ETHYLPARABEN,IRON OXIDES（CI 77491/CI 77492）,METHYLPARABEN,MINERAL OIL,OCTYLDODECANOL o-CYMEN-5-OL,ORANGE OIL,OZODERITE,PEG-30 DIPOLYHYDROXYSTEARATE,PHENOXYETHANOL,PPG-3 MYRISTYL ETHER,PROPYLPARABEN,QUATERNIUM-18 HECTORITE,ROSEMARY OIL,SILICA DIMETHYL SILYLATE,SODIUM MYRISTOYL GLUTAMATE,TITANIUM DIOXIDE（CI 77891）,TOCOPHERYL ACETATE,XANTHAN GUM

成分虽然复杂，但活性物质并不是很多，纯物理防晒，UVA/UVB都有比较完全的防护；其他多为合成酯、硬脂酸、矿物油乳化剂类成分，最后有一点植物精油；诉求就是温和防护，整体比较厚重，而且有物理防晒的通病泛白；针对敏感类皮肤成分多了点，除了防晒无其他功效，保湿性一般。

The Nazarov cyclization, a powerful tool for the construction of five-membered carbocycles from divinyl ketones and related compounds, has attracted increasing attention in recent years due to its wide applications in the synthesis of complex natural and unnatural products.

Nazarov环合反应是通过二烯酮类物质和类似化合物构建五元碳环的有效方法。由于该方法广泛地应用于复杂天然和非天然产物的合成，近年来引起人们的广泛关注。

It showed that the ammonium ferric sulfate dodecahydrate was an excellent catalyst,the yield of the n-butyl lactate could reach over 95.0% under molar ratio of n-butyl alcohol and lactic acid 2.25∶1,the reaction temperature of 110～125℃,reaction time of 1.5 h and amount of the ammonium ferric sulfate dodecahydrate catalyst of 2.5%.

实验表明：NH4Fe(SO4)212H2O是合成乳酸正丁酯的良好催化剂。最佳反应条件为：醇酸物质的量比2.25∶1，催化剂的用量为反应物料总量的2.5％，酯化反应时间为1.5 h，反应温度110～125℃，酯化率可达95.0％。

In this paper, synthetic process of PTT and cationic dyeable PTT was studied, including molar ratio, catalyst concentration, reaction time and temperature, types of antioxidants in the esterification reaction and the condensation reaction.

研究了聚对苯二甲酸丙二醇酯、阳离子染料可染PTT的合成工艺条件中各因素对酯化及缩聚反应的影响，包括单体物质的量比、催化剂浓度、反应时间和温度、抗氧剂种类等。

In this paper,authors introduces advances in organic electrosynthesis both in research methods and research contents which have important theoretical and practical significance.

近年来有机电合成在中国有许多新的发展，无论是研究方法，还是研究内容都有了新的进展，为今后的发展打下了牢固的理论基础和物质基

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失