合成物

Although many researchers have studied the synthesis of allyl phenyl ether by phase-transfer catalysis, no studies have used it in membrane reactor up to now. The purpose of this paper is to combine the studies of membrane reactor and phase-transfer catalysis. The membrane was used to stabilize the aqueous/organic interface at a fixed position, also the quaternary ammonium ion in the membrane was used as the catalyst to partake in the reaction system directly, and so it can also separate the product and reactants at the same time. A theoretical model is also presented.

中文摘要对於利用相间转移触媒催化技术来合成丙烯基苯基醚的反应，已有不少专家学者研究过，而至今还无在薄膜反应器中进行此反应之研究，本研究则是要结合薄膜反应器与相间转移触媒两者之特性，固定水油两相之界面，并且利用薄膜上的四级铵离子为触媒，直接在反应系统中参与反应，并同时分离产物及反应物，进而推导出相关之理论模型。

The present paper reports three new europium complexes,EuL3(H2O) 6,EuL3Phen(H2O)4 and EuL3(H2O)5,synthesized with Eu(NO3) 3·6H2O,2-(4-fluorobenzoyl) benzoic acid,Phen and TPPOL=2-(4-fluorobenzoyl benzoic acid,Phen=1,10-phenanthroline,TPPO=triphenyl phosphine oxide.

以硝酸铕、2-(4-氟代苯甲酰基)苯甲酸、1，10-菲咯啉和三苯基氧膦合成了EuL 3(H2O)6，EuL3Phen(H2O) 4和EuL3(H2O)5三种固态配合物。

Dynamic laser light-scattering experiment indicated that PEO-PAn and PAn-PEO-PAn aggregated in DMF, and their aggregation radiuses were about 40-60nm.

所合成的嵌段共聚物PAn-PEO，PAn-PEO-PAn通过动态激光散射测量表明：在选择性溶剂DMF中形成了胶束，它们的胶束半径在40-60nm之间。

Synthesis of such compounds from nonchiral materials results in equal numbers of the enantiomers, racemates.

使用非手性物料合成此类化合物导致等量的对映异构体和外消旋物。

Phycobiliproteins are brilliantly coloured,intensely fluorescent chromoproteins,which consist of apoproteins and covalently bound linear tetra pyrroles as prosthetic groups.

藻胆蛋白是藻类光合作用捕光复和物的功能组分，所以研究藻胆蛋白生物合成对认识光合作用的形成和机理非常重要。

However, before it can do so, primers must present on the DNA.

但在它开始合成前，必须有引物出现在DNA上。

Polys with amino endgroups have been prepared and used asmacromolecular initiators for the polymerization of SLGNCA.

这一研究结果为含聚肽共聚物的合成提供了一种新的有效途径。

The effects of such parameters as temperature, pH, feeding rate,concentration, [NH_3]_T/_T molar ratio, surfactants and agitation, on the morphology and size of the particles, were studied and conclusions obtained are as follows:(1) The morphology and size of the particles are mainly decided by the species of nickel oxalates present.(2) Speeding up dissolution-recrystallization process benefits the preparation of the particles of being composed of a single species with uniform morphology and high aspect ratio.(3) The variations of nucleation and growth supersaturation under different conditions have definite effects on the morphology and size of the particles.(4) Adding PVP25 at a proper amount is beneficial to the preparation of fibrous nickel oxalate particles with high aspect ratio. 3 The formation mechanism as well as the morphology and size control of fibrous cobalt oxalate particlesThe cobalt oxalate particles with fibre morphology were prepared using CoCl_2 solution and mixed(NH_4)_2C_2O_4, NH_3·H_2O solution by a double jet process.

研究了温度、pH值、加料速度、浓度、[NH_3]_T/_T摩尔比、表面活性剂及其添加量、搅拌等对颗粒形貌与粒度的影响，主要结论为：(1)草酸镍化合物种类是决定颗粒形貌与粒度的最主要因素；(2)提高陈化中溶解—再结晶速度，有利于得到物相单一，形貌规整，轴向比大的粉末；(3)不同条件下，颗粒形核与生长过饱和度改变，也会对粉末形貌与粒度产生一定影响；(4)适量添加PVP25有利于大轴向比纤维状草酸镍的制备。3纤维状草酸钴的形成机理及其形貌与粒度控制采用CoCl_2溶液与(NH_4)_2C_2O_4和NH_3·H_2O混合溶液并流加料合成的方法，研究了纤维状草酸钴的制备。

The catalytic behavior of these complexes in the hydrosilylation ofα-olefins with triethoxysilane has been investigated systematically.

二、富勒烯过渡金属配合物的合成及其催化性能的研究以富勒烯为基的衍生物一般具有独特的催化性能。

Chapter two is concerned with the syntheses and characterization of some chiral ligands and consists of relevant mechanism of reaction( for example, N anion acts as nucleophilic reagent and different nitriles act as reacting substance).

第二章讨论了若干手性配体的合成与结构，并包含了相关反应的机理探讨(例如N~-做为亲核试剂、不同的腈作为反应底物)。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失