合成物

The pinacol coupling of carbonyl compounds affording pinacols is an important method for the formation of 1, 2-diols and one of the most powerful methods for constructing carbon-carbon bond.

醛酮的片呐醇偶联是合成片呐醇的经典而有效的方法之一，也是形成C-C键的有效途径，一般通过醛酮与金属试剂或金属络合物作用来实现。

Methods The α-factor prepro peptide from Saccharomyces cerevisiae was used as a signal peptide to secret HBsAg in Hansenula polymorpha. Both MFα and HBsAg genes were designed based on Hansenula polymorpha-preferred condons and synthesized by overlap PCR respectively, then fused together by PCR using a pair of primers.

在HBsAg基因前加酿酒酵母α前导肽基因序列作为信号肽，将整个序列优化为汉逊酵母优选密码子，采用搭桥PCR方法分别合成后，通过1对引物PCR法融合在一起。

The solution behavior of the complex has been studied by potentiometric titration, UV and cyclic voltammetry.

第六章合成了三核铜配合物Cu〓-L，用紫外、pH滴定以及电化学的方法详细研究了其溶液行为。

A range of oligoaryls having alternating para- or meta-benzene-furan rings is synthesized by rapid convergent/divergent method from the annlation of a propargylic dithioacetal and an aldehyde having a propargylic dithioacetal moiety as the substituent.

中文摘要结合分流法/汇集法，利用炔丙基硫缩酮单体和另一具有醛基的单体进行环化反应，可以迅速合成对位及间位取代苯环呋喃交错寡聚物。

This thesis mainly focuses on overcoming the substrates limition of the present catalytic systems,low catalytic efficiency,and application in total synthesis.1.Conveniently synthesized sulfonamide alcohol titanium complex has been used to catalyze the asymmetric addtition of methyl propiolate to various aromatic and aliphatic aldehydes with high enantioselectivity.

本论文即针对现有催化体系的底物局限性、催化效率低、应用研究少等展开研究：1、我们将简便合成的磺酰胺基醇配体-钛催化体系应用于催化丙炔酸甲酯对各类芳香醛及脂肪醛的不对称加成取得了理想的结果。

Diethanol amine and 2,2-bis(methylene-2-bromoisobutyrate) propionyl chloride were used as divergent reagents respectively before preparations of the second and the third generations. The resultant polymers were characterized by GPC and ~1H NMR.

为了利用含有可降解链段的树枝状聚合物(dendrimer-like polymer)制备纳米空心球，我们结合ATRP和开环反应合成了两种苯乙烯和L-丙交酯的三代树枝状共聚物CPSt(PLLA_2_2_3和CPSt(PLLA_2_2_4。

Pyrazole; pyrazolyl carboxylic acid; synthesis; complexes; crystal structure

吡唑； 羧酸；合成；配合物；晶体结构

A new corrosion inhibitor and Universal antibacterial reagent, namely, the copolymer of N-isopro-pylacrylamide and N-allyl-1-benzoyl-3-phenyl-4,5-dihydro-4-formamido pyrazole was prepared.

合成了一种新的腐蚀抑制及广谱抑菌剂：N-异丙基丙烯酰胺与N-烯丙基-1-苯甲酰基-3-苯基-4，5-2H-4甲酰胺基吡唑的共聚物PNIPAM-Co-PBPCP。

For the above purposes, using a tailored cyanometalate precursor,(1) Tp=hydrotris (pyrazolyl borate; Bu〓N〓=tetrabutylammonium cation , two trinulear complexes,〓(2),〓(3; cyclam: 1, 4, 8, 11-tetraazacyclotetradecane), two one-dimensional polymers,〓(4; dien: diethylenetriamine),〓(5), and a cluster 〓(6) have been synthesized and characterized structurally and magnetically.

基于上述研究热点，我们以修饰的氰基金属化合物(1)为构筑基元（Tp：三吡唑基氢硼烷，Bu〓N〓：四丁基铵离子），合成了两个杂三核化合物，〓(2)，〓（3；cyclam：1，4，8，11-四氮环十四烷），两个一维聚合物，〓（4；dien：二乙烯三胺），〓(5)，和一个十四核簇合物〓(6)。

A novel mixed ligands sandwich copper complex with hydrotris borate and bihydrobis borate ligands Tp: hydrotris (pyrazolyl borate; Bp: bihydrobis borate was synthesized.

合成了一种新型Ⅱ三吡唑硼酸根和二吡唑硼酸根混合配体的&三明治&型铜配合物（Tp：三吡唑硼酸根，hydrotris borate；Bp：二吡唑硼酸根，bihydrobis borate）。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失