合成物

Introduced the synthetic principle and method,the performance and application of polyurethane acrylate prepolymer are also discussed.

简述了一种重要的紫外光固化用基础材料——聚氨酯丙烯酸酯预聚物的合成原理及合成方法，并讨论了其性能特点和应用。

The optimal conditions were found as follows: reaction temperature 90℃, reaction time 50 min, the molar ratio of catalyst to diethyl adipate 1.1:1, providing 99.5% yield.

结果表明，各试验因素的影响效能为反应温度（反应时间（催化剂用量；最佳合成条件为反应温度90℃，反应时间50 min，催化剂与原料的摩尔比为1.1：1，在此条件下，常压合成目标物的产率可以达到99.5%。

So the effect of different solvents, such as methanol, ethanol, butanol, tertiary butanol, isoamyl alcohol, tertiary amyl alcohol, diethyl ether and cyclohexane, on the reaction was explored.

在文献所报道的应用K〓CO〓作催化剂、CH〓I既作促进剂又作部分反应物的由原料甲醇与二氧化碳直接合成碳酸二甲酯工作的基础上，在体系中加入离子液体emimBr后，研究了emimBr对合成反应的影响。

In terms of the contents and compositions of macromolecules in an Anabaena cell in the literature, the requirements of monomeric building blocks and precursor metabolites for cell synthesis were calculated, and an appropriate metabolic stoichiometry on cell biosynthesis was derived.

根据文献中鱼腥藻细胞大分子的含量和组成情况，计算了细胞合成所需要的小分子单体和前体代谢物的量，得到代谢意义上的细胞生物合成计量关系。

Herein, a self-assembly system with polymer pattern of lower molecular weight polyaerylie acid have been built up, in which some nanosized complex was synthesized, including nanosphere of Pb-PAA, one-dimensional nanorod of CuS-PAA and PbS-PAA, one-dimensional helix nanochain of PbSO4-PAA, and one-dimensional reticulate nanofibres of PbCr2O7-PAA. The mechanism was discussed preliminarily, the important action of the bone angle torsion as well as the ""contact bridge"" served by ion in the course of self-assembly was proposed for the first time.

本文以低分子量聚丙烯酸为高分子模板构建自组装体系，首先合成了几种特殊形态的纳米配合物，包括纳米微球Pb-PAA、一维纳米棒CuS-PAA和PbS-PAA、一维螺旋纳米链PbSO_4-PAA及一维有序纳米纤维网络PbCr_2O_7-PAA，初步讨论了该自组装体系的合成机理，首次提出了键角张力和分子的"搭桥"作用在自组装过程中的作用。

The results show different factors in this process such as reactant ratio, atmosphere pressure etc.

结果表明，反应物投料比例，合成气氛压力等因素对合成产物化学计量配比有显著的影响。

The concrete steps are: the lactic acid and small-molecule dicarboxylic acid react under the condition with the presence of the catalyst to directly polymerize the carboxyl-terminated lactic acid prepolymer; then the aliphatic polycarbonate diol and the catalyst are added; with the presence of the N2, the reaction is kept for 1 to 10 hours at the temperature of 150 to 200 Celsius system to get the poly lactic acid and polycarbonate copolymer of the low molecular weight; then the reaction is done in the twin-screw extruder at the temperature of 150 to 190 Celsius system to screw out the extension chain; finally the polylactic copolymer of the high molecular weight, toughness and heat resistance is made.

具体步骤是：乳酸和小分子二元酸在催化剂条件下反应直接缩聚合成羧基封端的乳酸预聚物，然后加入脂肪族的聚碳酸酯二元醇和催化剂，在N 2 气氛下，抽真空，在150～200℃温度下，反应1～10小时，得到低分子量聚乳酸/聚碳酸酯共聚物，然后在双螺杆挤出机中在140～190℃下，进行反应挤出扩链，最终得到高分子量的、韧性与耐热性较好的聚乳酸共聚物。

Effect of TP on DNA primase-polymerase α complex activity was examined using Liquid Scintillation counter. Results:It showed that IC50 value of TP inhibiting DNA primase-polymerase α complex activity was 20.28 (15.17～ 27.13)μ g/ml. TP could promote DNA primer synthesis but inhibit DNA primer extension.

结果：茶多酚对小鼠肿瘤L2细胞DNA引物酶多聚酶α复合体活性有抑制作用，半数抑制浓度（IC50）值为20.28(15.17～27.13)μg/ml；对DNA引物合成有促进作用；对引物延长亦有明显抑制作用，其IC50值为36.43μg/ml。

The esterification reaction was carried out in isooctane solvent at 50℃, with 0.15mol/L of substrate and 1:1.4 of acid-alcohol molar ratio.

研究了反应温度、溶剂、底物浓度、底物摩尔比、吸水剂用量等因素对酯化反应的影响，确定了正戊酸异戊酯的最佳合成条件为：反应温度为50℃，异辛烷为反应介质，底物浓度为0.15mol/L，酸醇摩尔比为1：1.4。

These complexes showed modest catalytic activity, and the PDIs of the polymers obtained were relatively broad.6. Reaction of CpjLn with MBMPHa in THF in 1 :1 molar ratio, isopropanol was added to the system in 1 equiv., after workup, a new kind of neutral lanthanide complexes [LnCw-OiPrXTHF2]2 Ln = La (14, Nd (15),Yb (16) were gained.

配合物cp3Ln与MBMPH：按卜1的摩尔比在THF中反应1小时，然后再原位按卜1的摩尔比加入异丙醇，合成了中性的桥联双芳氧基稀土烷氧基配合物 [L城犷0，P以THF2]2Ln=La(14，Nd(15)，Yb(16)，产物经红外光谱，元素分析和核磁共振氢谱(配合物14)等表征。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失