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合成气

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Experiments on purification technologies for the conversion of cornstalk biomass into the industrial product were made to produce cornstalk gas in the down-flow fixed by the gasifier. The experiment focused on the technical procedures for deoxygenation. catalytic cracking of tar, hydrogenation, etc. Quality straw syngas was produced for methanol synthesis. The catalysis of methanol synthesis for the production of cornstalk syngas was earned out in a tubular-flow integral and isothermal reactor under the pressure of 5MPa over Cu-based catalyst C301 (particle size: 0.833mm×0.351mm), a catalyst made in China. Thirty-three sets of test data were obtained.

为了实现秸秆类生物质合成燃料甲醇的工业转化,有效利用生物质能,对下吸式固定床气化炉产生的低热值玉米秸秆燃气进行除氧、分解焦油和配氢等纯化试验,制备出合成甲醇的优质秸秆合成气,在直流流动等温积分反应器中,使用国产C301铜基催化剂,催化剂粒度为20~40目(0.833mm×0.351mm),在5MPa反应压力下,对玉米秸秆合成气进行催化合成甲醇试验研究,获得33套试验数据。

In this paper, the catalyst and process of dimethyl ether from syngas were studied.

合成气一步法制二甲醚是近年来开发的一种新技术,相对于传统的两步法合成工艺,即先合成甲醇再脱水制二甲醚,合成气一步法合成二甲醚因其热力学上的有利性和经济上的合理性,成为C1化学研究的一个热点。

It is revealed that a certain amount of excessive formamide is favorable for preparation of the aerogel with high porosity, while more excessive glycol can deteriorate the formation of nano-porous SiO2 aerogel network. Additionally, the pH value of the reaction system has a strong impact on the microstructure and properties of prepared SiO2 aerogel.

研究发现:微过量的甲酰胺,有利于高孔隙率气凝胶的合成;过量的乙二醇的引入不利于低密度气凝胶的形成;pH值对合成气凝胶的性质也有较大的影响。

This process utilizes the packaged technology--- Slurry Bed Fischer-Tropsch Synthesis independently developed by Institute of Coal Chemistry, Chinese Academy of Sciences to convert syngas ( H2+CO2) into high-quality synthetic diesel oil, naphtha, liquefied petroleum gas and chemicals.

中科合成油煤制油技术,利用自主创新的浆态床费托合成成套技术,将合成气( H2+CO2)转化成优质合成柴油、石脑油、液化石油气及相关的化学品。

The influence of each strategy on heat economy and safety operation of gas turbine simple cycle was discuss...

结果表明:对于焦炉煤气,方案1的热经济性最高,方案4的热经济性最低,各方案对燃气轮机的安全运行几乎没有影响;对于煤基合成气,方案5的热经济性最高,方案4的热经济性最低,方案1的安全性最差;综合考虑热经济性、安全性和可操作性,对于焦炉煤气,方案1是最佳方案,对于煤基合成气,方案2是最佳方案。

The influences of conditions, such as the different elements in A site, reaction temperature and the reoxidation time etc.on partial catalytic oxidation of AFeO 3 catalyst are reviewed. The results show that the lattice oxygen from AFeO 3 pervoskite catalyst in A site occupied ...

结果表明,稀土金属(La ,Nd ,Sm ,Eu)占据A位的AFeO3钙钛矿型催化剂中的晶格氧适于甲烷选择性氧化制合成气,在完全氧化的LaFeO3催化剂上存在少量的强氧化性氧物种,通过控制再氧化条件,可使CH4 在LaFeO3催化剂的作用下,高转化率(~ 92 %)、高选择性(96 %)地生成合成气

High-pressure liquefaction of a sawdust in syngas and hydrogen with tetralin as solvent was performed in an autoclave,and the effects of temperature,reaction time and initial reaction pressure on the sawdust high-pressure liquefaction were studied by testing the distribution and characteristic of liquefaction products.

在小型高压反应釜中以四氢萘为溶剂,氢气和合成气为液化反应气,通过对不同液化条件下所得液化产物的收率及性质分析,考察了不同液化条件(反应温度、反应时间、反应气压力)对锯屑高压液化行为的影响;同时在相同液化条件下,通过液化产物收率和性质的分析,考察了气氛对锯屑高压液化行为的影响,探讨了用合成气代替氢气进行液化的可行性。

On the basis of the thermodynamic analysis, the equilibrated concentration of the components, the conversion of CO and the selectivity of DME in the different pressure and temperature have been studied. The feed gas is come from coal and natural gas.

在此基础上,研究了以煤或渣油为原料制得的合成气、以天然气为原料制得的合成气在不同压力、温度下的平衡组成、CO的平衡转化率及该操作条件下的二甲醚与甲醇的平衡选择性。

The synthetic gas and ash composition heat transfer and flow in vertical pipe of coal gasifier are simulated and analyzed by the theory and program presented. The temperature、velocity and concentration variations of synthetic gas and ash composition are accomplished. The influences of coal gasifier working condition and vertical pipe parameters on the gas and ash cooling process are discussed. The law of solid-gas two phase turbulent flow and heat transfer is further revealed.

本文还应用上述理论和程序,在国内首次对气化炉激冷室下降管内合成气和灰份的流动和传热过程进行了数值计算和分析,得到下降管内合成气和灰份的温度、速度和浓度等参数的变化,还讨论了气化炉运行参数和下降管结构参数如气化温度、下降管尺寸、灰份性质等参数变化对合成气降温过程的影响,进一步揭示了下降管内气固两相的流动和传热规律。

Processes using composite materials in accordance with the invention are, for example, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen which synthesis gas is, advantageously, free of deleterious and/or inert gaseous diluents such as nitrogen.

应用按照本发明的复合材料的工艺是,例如,生产包括一氧化碳和分子态氢的合成气,其中合成气的优点是没有有害和/或惰性气体如氮气的稀释。

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