合成地

Whereafter,we achieved a highly enantioselective approach towards the synthesis ofβ-substituted chiral ketones utilizing Oppolzer\'s sultam as chiral auxiliary.The-and-enantiomer of target chiral ketones were obtained with up to 99%ee.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，高对映选择性地合成了一系列β-芳基取代手性酮，其ee值高达99%，可用于药物及其它精细化工中间体的不对称合成。3。

Starting from the hydroxylamine (dimethyl amino ethanol, triethanolamine) and 1, 3-propane sultone, a series of hydroxyl and sulfonyl dual-functionalized zwitterionic salts were synthesized. Then dual-functionalized ionic liquids containing both hydroxyl and sulfonyl functional groups were produced successfully by zwitterionic salts and three kinds of strong acids (p-toluene sulfonic acid, trifluoromethanesulfonic acid, methanesulfonic acid) respectively. The structure of zwitterionic salts and dual-functional ionic liquids were confirmed by the 1H NMR and IR.

以羟基有机胺(N，N-二甲基乙醇胺，三乙醇胺)为原料与1，3-磺酸内酯反应合成了一系列含有羟基和磺酸基双官能团的内盐，并将所得到的内盐分别与三种强酸(对甲苯磺酸，三氟磺酸，甲磺酸)反应，成功地合成了双功能化室温离子液体，并通过红外光谱、核磁氢谱测定，证实了内盐和双功能化离子液体的结构。

In low-temperature superalkaline condition,the nuclei of zirconia were synthesized simply by stirring and milling the solid mixture of sodium hydroxide and zirconium oxychloride.

摘 要：以分析纯氢氧化钠和氯氧化锆为原料，通过低温强碱合成法简单、方便地合成了二氧化锆晶核。

In low-temperature superalkaline condition,the nuclei of zirconia were synthesized simply by stirring and milling the solid mixture of sodium hydroxide and zirconium oxychloride.

以分析纯氢氧化钠和氯氧化锆为原料，通过低温强碱合成法简单、方便地合成了二氧化锆晶核。

This paper first stated the hydrolysis law of organochlorosilane and the effect of various R/Si and ph/R on the properties of propolymer,there showed the mathematical calcu- lation method and computer progrom of the every monomer amount to synthetize propolymer, and provided the necessary theortical basis and quantitive calculation equation for the syn- thetise,In addition,the co-existing structure model of linear and trapezoid was put forward on the analysis of prepolymer micro-structure,which laid a found...

本文阐述了有机氯硅烷单体的水解规律及不同R/Si和ph/R值对预聚体性能的影响，在此基础上，提出了合成预聚体所需各单体用量的数学计算方法和计算机计算的程序，为合成提供了必要的理论依据和定量的计算公式。此外，文章在剖析预聚体微观结构的基础上，提出了线型与梯型结构并存的结构模型，为进一步更深入地认识预聚体的性能奠定了理论基础。

This dissertation successfully fabricated cross-linked polysiloxanes under base catalysts such as potassium hydroxide siloxanolate or tetramethylammonium hydroxide (Me_4NOH) siloxanolate by anionic ring-opening copolymerization of cyclosiloxanes and Polyhedral Oligomeric Silsesquioxanes as multifunctional monomers.

本论文首次通过阴离子开环共聚，成功地将POSS大分子作为多官能团单体，与环硅氧烷在KOH硅醇盐或Me_4NOH硅醇盐等碱性催化剂的作用下，直接合成交联聚硅氧烷：通过调节POSS大分子和环硅氧烷单体的种类以及化学计量比，可合成出一系列不同种类和不同交联密度的交联聚硅氧烷；并对其阴离子开环共聚机理以及极性调节剂DMAc对凝胶时间的影响进行了详细讨论；同时借以凝胶含量和溶胀比、GPC、FT-IR、固体~(13)C和~(29)Si NMR、WAXD、DSC以及TG等手段对所得聚合物的微观结构以及热性能进行了详细考察。

Total synthesis of CET was accomplished by two routes through a conceptually novel strategy featuring a transannular reductive rearrangement as the key transformation for the construction of the core pentacyclic ring skeleton of CET.

我们采用了全新的合成策略，以氮原子参与的跨环还原重排为关键反应，通过两条路线分别成功地合成了三尖杉碱。

In this paper, the preparations, analytical methods, physical characteristics of ferrates and the application of ferrates in the fields of synthesis of organic compounds, treatment of waste water and the usage as cathode material in alkaline batteries are summarized. The electrochemical preparation of sodium ferrate is described and the relationships between the main parameters in the process are deeply investigated. One method of in-situ electrosynthesizing potassium ferrate of high purity with both high efficiency and low energy consumption is invented. The cyclic voltammogram and feature characterization of iron anode in alkaline solutions is studied. One preparation method of ex-situ electrosynthesizing tripotassium sodium ferrate of high purity is created.

本文概述了高铁化合物的制备方法、分析方法、物理化学性质及其在氧化合成有机物、水处理和用作碱性电池正极材料等领域的应用；深入系统地研究了高铁酸钠的电化学制备及其影响参数之间的关系；研发了一种高效率低能耗直接电合成高纯度高铁酸钾的工艺方法；探讨了铁电极在浓的苛性碱溶液中的循环伏安特征及其极化特征；研发了一种电化学制备高铁酸三钾钠的工艺方法并用多种现代分析测试技术对K_3Na(FeO_4，)_2进行了表征。

A one-step method for the synthesis of aromatic indolizine derivatives byintramolecular 1,5-dipolar cyclization reaction of 2-(2-arylethenyl)pyridinium N-ylidesin the presence of an oxidant has been studied for the first time. In the presence ofelectron-deficient olefins, however, 2-(2-phenylethenyl)pyridinium N-ylides underwent1,3-dipolar cycloadditions and then aromatized in situ by TPCD to produce indolizinederivatives, indicating 1,3-dipolar cycloaddition proceed more readily than 1 ,5-dipolarcyclization in these conditions. Pyridinium disubstituted N-ylides, readily obtainedfrom corresponding pridinium and β-chlorovinyl ketone, underwent thermalintramolecular 1,5-dipolar cyclization to give indolizine derivatives easily.Indolizinecarbaldehyde derivatives were synthesized starting from 2-pyridinecarbaldehyde in four-steps involving 1,3-dipolar cycloaddition reaction.

本文首次研究了2-(2-芳基乙烯基)吡啶N-叶立德在氧化剂存在下的分子内1，5-偶极环化反应，采用一锅法合成了中氮茚衍生物；研究了这些N-叶立德的1，5-偶极环化和1，3-偶极环加成反应的选择性，发现当有缺电子烯烃存在时，优先进行1，3-偶极环加成反应，而不再发生分子内1，5-偶极环化反应；由β-氯乙烯酮方便地得到了烯丙基N-叶立德，他们在加热时进行分子内1，5-偶极环化反应而得到中氮茚衍生物；由2-吡啶甲醛为起始原料，通过1，3-偶极环加成反应等四步反应，得到了重要的中氮茚甲醛衍生物，这些反应都具有条件温和和操作简便的特点，是合成中氮茚衍生物的新方法。

DEM is necessary in the geometrical correction of non-flat area. SAR simulation is helpful to the selection of GCPs in hilled area. For high accuracy of less than one pixel, auto-registration technique was adopted. Multi-channel filtering can be carried out in an optimal way, which minimizes speckle while preserving the radiometry and spatial resolution of the individual channels.

研究表明在非平坦地区必须经过DEM 正射校正，正射校正时利用DEM 模拟雷达影像有助于山区控制点的选择；利用多参数雷达合成影像时，影像间的配准十分重要，利用自动配准技术不仅配准精度高，而且自动化程度高；文中采用多通道滤波方法对多时相合成的ASAR影像进行斑点噪声的去除，很好地保持了图像的辐射特性和空间分辨率。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！