合成地

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用，在机理研究的基础上，本论文选择五种不同结构的甲基丙烯酸酯类单体：lauryl methacrylate，(N，N-dimethylamino)ethyl methacrylate，polymethyl ether methacrylate，4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate，用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物，详细而深入地研究了它们的均聚、共聚动力学，发现了双硫酯并非在聚合反应初期就全部转化，而是随着反应进行逐步消耗，这与理想的活性聚合体系有很大差别。

In chapter four, the preperation of ytterbium diiodide was examined. The reductive cleavage of Se-Se bond and S-S bond induced by ytterbium diiodide was investigated. The reaction of diselenides and disulfides with allylic bromide promoted by ytterbium diiodide was also examined. The intermolecular Barbier-type reaction induced by ytterbium diiodide was studied. In the last section of this chapter, the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide was investigated.

第四章，研究了二碘化镱的制备方法，以及二碘化镱作为一种优良的单电子转移试剂在有机合成中的应用：二硒醚的Se--Se键和二硫醚S-S键的还原断裂，及其在合成烯丙基硒醚，硒代酯和烯丙基硫醚，硫代酯中的应用，实验结果表明二碘化镱也能促进分子间的Barbier反应，而文献认为二碘化镱不能促进分子间的Barbier反应；最后研究了二碘化钐促进的叠氮化合物与腈的交叉还原偶联反应，一步高收率地制备脒的方法。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

Some stable imino -acetoxyphosphoranes were successfully synthesized.

建立了一套合成稳定磷烷的新方法，并成功地合成了稳定的氨基酸磷烷。

The invention adopts the technical proposal that the nucleation and process of growth of the molecular sieve are controlled properly in the synthetic process of the ZSM-5 molecular sieve material for producing the Magadiite/ZSM-5 intergrowth material, wherein the proportion of intergrown phases is adjustable, and the synthesized Magadiite/ZSM-5 intergrowth material adopts the compositions including the following mole relation: nSiO2:Al2O3, where n is between 50 and 1000 in the formula, and the method is characterized in that the Magadiite/ZSM-5 intergrowth material has two intergrown phases and an XRD diffraction pattern thereof has the d-space maximum value at the lengths of 15.73+-0.1, 11.14+-0.1, 9.97+-0.1, 7.74+-0.1, 5.14+-0.1, 3.86+-0.05, 3.66+-0.05, 3.45+-0.05, 3.30+-0.05 and 3.14+-0.1 angstroms, thereby solving the problems properly.

本发明通过采用在ZSM-5分子筛材料合成过程中，控制好分子筛的成核和生长过程，制备出了一种Magadiite/ZSM-5共生材料，其中共生物相比例可调，合成的Magadiite/ZSM-5共生材料采用包括以下摩尔关系的组成：nSiO2∶Al2O3，式中n＝50～1000，其特征在于所述Magadiite/ZSM-5共生材料具有两种共生物相，其XRD衍射图谱在15.73±0.1，11.14±0.1，9.97±0.1，7.74±0.1，5.14±0.1，3.86±0.05，3.66±0.05，3.45±0.05，3.30±0.05，3.14±0.1埃处有d-间距最大值的技术方案，较好地解决了上述问题。

The analysis result shows that the rutting depth is smaller when the thickness of paved temporary road is thinner. Therefore, the geosynthetic only owned the isolative function, the rutting depth will be larger than 100mm if the subgrade without the geosynthetic material. To use the geosynthetic material is very important for the base and subbase of road.

研究结果显示；临时性道路在路基较薄时因车辙较小，地工合成材料仅具有隔离之功能，但在路基较厚时若无加劲材料则车辙可能大於100mm，因此使用地工合成材料显得相当重要。

This thesis sets up a new method to synthesize stereoselectively ?ra玸--2,5-disubstituted tetrahydrofurans by introducing two alkyl groups in 3-C and 5-C of lactol, flash decomposition and hydrogenation.

本文独创新的合成方法：以-乳醇，即-4，10-二氧杂三环[5.2.1.0~(2，6)]-癸-8-烯-3-醇为原料，在其3-位和5-位先反向引入两个取代基，再经过热分解和催化加氢反应，高立体选择性地合成反式-2，5-二取代四氢呋喃。

The key problem is to synthesize high stereoselectively trans- 2,5- disubstituted tetrahydrofurans. This thesis sets up a new method to synthesize stereoselectively ?ra玸--2,5-disubstituted tetrahydrofurans by introducing two alkyl groups in 3-C and 5-C of lactol, flash decomposition and hydrogenation.

本文独创新的合成方法：以-乳醇，即-4，10-二氧杂三环[5.2.1.0~(2，6)]-癸-8-烯-3-醇为原料，在其3-位和5-位先反向引入两个取代基，再经过热分解和催化加氢反应，高立体选择性地合成反式-2，5-二取代四氢呋喃。

In present paper, the progress of quinoline derivatives in synthesis and application are summarized first, then according to a lot of literature, designed the synthetic route for 8 derivatives of 6-AQ. They are 4-chloro-6-AQ, 5- chloro -6-AQ, 5-methoxyl-6-AQ, 7- chloro -6-AQ, 8- chloro -6-AQ, 8-bromo-6-AQ, 8-methyl-6-AQ and 8- methoxyl -6-AQ. All the products were obtained by reduction of its corresponding 6-nitroquinoline.

在对过往文献大量查阅的基础上，本文首先综述了喹啉及其衍生物的性质、合成方法及应用研究进展，并通过对文献报道方法的优化和改进成功地设计合成了4-氯-6-AQ、5-氯-6-AQ、5-甲氧基-6-AQ、7-氯-6-AQ、8-氯-6-AQ、8-溴-6-AQ、8-甲基-6-AQ和8-甲氧基-6-AQ等8种6-AQ的衍生物作为研究新型抗疟疾药物的中间体。

But ferrous sulfate the by-product of TiO2 cannot be effectively used enough in our country over a long period. In order to solve above questions, the dissertation has done some works as follows:Firstly, the process of purifying by-product of TiO2-ferrous sulfate is studied. The craft and condition of the synthesis of micaceous iron oxide with by-product of TiO2-ferrous sulfate was studied through experiments.

它们都可以通过钛白副产硫酸亚铁为原料制备，但是长期以来，我国硫酸法生产钛白的副产物硫酸亚铁得不到充分有效地利用，针对以上情况，本论文主要作了以下几个方面的工作：首先，研究了钛白副产硫酸亚铁的净化工艺路线，讨论了钛白副产硫酸亚铁水热法合成云母氧化铁的工艺路线和条件，讨论了影响云母氧化铁生成的因素，得出了红、棕、灰云母氧化铁合成的控制条件。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！