合成地

From the ester n, the intermediate Ⅲwas produced by the Sonogashira coupling reaction with terminal alkynes under the co-catalysts of Pd2 and Cul. These final products of alkynyl benzamide derivatives IV were obtained by the cleavage of support with primary or second amines.

液相合成兼容了固相合成可快速简便地对产物进行分离纯化以及溶液相合成可在均相条件下进行反应和用常规手段对反应中间体进行分析检测的优点，用聚乙二醇4000作为可溶性聚合物支持体，通过醚键将[1，3，5]氯三嗪连接在PEG上制备成PEG支持的新型的可溶性聚合物试剂I。

The known titanoheterocyclic compound〓 was synthesized in high yield by a new route involving an oxidative addition reaction of "titanocene"with benzil, and its structure was first confirmed by a single crystal X-ray diffraction method.

首次由&二茂钛&与二苯乙二酮的氧化加成反应，高产率地合成了一个已知的高价钛杂环化合物〓，并首次用X-射线衍射法测得该化合物的单晶分子结构。

Therelative rates of the Rh-mediated carbenoid insertion into the benzylic C - H bonds of aseries of para-substituted phenyl substrates: methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-propylhexanoate 47a - g, have been measured by an indirect intramolecular competitionmethod under the condition in which the possible steric and conformational effects have beenminimized.

为了将立体因素和构象因素最大程度减小，以便较为准确地评价电子效应对该反应的影响，设计并合成了不同对位取代基的化合物4-丙基-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯47a-g，并研究了它们在不同Rh催化剂作用下的分子内C-H插入反应。

Results Two bicyclic azasugars and a thiosugar were produced from L-sorbose in several steps.

结果 经几步反应成功地从L-山梨糖合成了三种双环氮杂糖和硫杂糖。

By using different bidentate auxiliary ligands, a number of one- and two-dimensional azido-bridged coordination polymers and molecular magnets were synthesized, including some with novel structures, and the influences of the ligands on the structure and the magneto-structural correlations in some systems were analyzed.

以不同二齿配体为辅助配体合成了多种一维及二维叠氮桥配位聚合物和分子磁体，较系统地分析了辅助配体对结构的影响及部分体系的磁构关系，并获得几种新的叠氮桥联结构类型。

A new series of Ni complexes [NiBr2] bearing bidentate amino-oxazoline ligands have been synthesized and applied for polymerization of styrene.

系列新的胺基-恶唑啉双牙配位基及其镍金属错合物，[NiBr2] 4，已被成功地合成出来，并且可应用在苯乙烯的聚合反应上。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2，2'-二取代的联萘衍生物在手性构型上高度稳定的特点，分别从光学活性的-和-2，2'-二乙炔基-1，1'-联萘结构模板出发，通过Sonogashira偶连反应导入苄基碸，然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子－对映异构体-3和-3。

Under the catalysis of rare earth composite solid superacid SO42-/ZrO2-La2O3,reaction of a-pinene and anhydrous oxalic acid afforded bornyl oxalate smoothly. Followed by saponification reaction, borneol was obtained selectively.

在稀土复合固体超强酸SO42-/ZrO2-La2O3的催化下， a -蒎烯与无水草酸的反应能顺利生成草酸龙脑酯，经皂化反应后，能选择性地合成正龙脑。

BAReO (boronic acid adducts of rhenium dioxime) complexes were synthesized and characterized with IR and UV/Vis spectra and elemental analysis. This analogous work was very helpful in under-standing the BATOs chemistry.

了为更好地了解BATO的络合物化学，又尝试合成和表征了两种类似BATO的BAReO络合物，〓和〓给出了它们的IR、UV/Vis光谱及元素分析结果。

Based on this, the technological process of purification after the bromination was reasonably simplified and the yiel...

据此在合成CLT酸中合理地简化了溴化反应后提纯的工艺步骤，产率提高2％，且对最终产品的质量和使用性能没有不良影响。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失