合成体

Design and synthesis of chiral phosphorus ligands and the applications of them in catalytic asymmetric reactions has been a hot topic. Researchers betake themselves to develop novel chiral phosphorus ligands to solve problems that the existing ones cannot do.

中文摘要手性膦配体的设计与合成及其在不对称催化中的应用一直是研究的热点领域，研究人员一直致力于开发新型的手性膦配体来解决已有配体不能解决的问题。

It is showed that in the X-ray diffraction patterns of the interlayer solid solution Ti3Si0.9Al0.3C1.93 and Ti3Si0.8Al0.4C1.93 bulk samples,which were in-situ reactively synthesized by hot-pressing the elemental Ti,Si,Al and C mixed powders,the diffraction peaks of [00L] crystal planes are very weak,there is only a small diffraction peak belonging to the [008],and the diffraction peaks belonging...

结果发现，用热压Ti、Si、Al和C混合粉末原位反应合成的Ti3Si0.9Al0.3C1.93和Ti3Si0.8Al0.4C1.93层间固溶体块体样品的X射线衍射谱中[00L]晶面的衍射峰极其微弱，只有[008]面有一个小的衍射峰，[002]、[004]和[006]面几乎没有衍射峰存在，而该块体样品的粉末的X射线衍射谱中所有[00L]晶面的衍射峰均存在。

We attached for the first time -NOBIN to Frechet-type dendron units. The syntheses of 16 kinds of dendrimer-based NOBIN Schiff-base ligands were achieved in a straightforward manner by simple condensation of -NOBIN with the corresponding salicylicaldehyde derivatives, of which 12 belong to the dendritic Schiff-base ligands and 4 belong to the non-dendritic Schiff-base ligands.

通过手性拆分获得了光学纯化合物NOBIN，首次将NOBIN手性单元连接到树枝状大分子中去，设计合成了四个系列16种新的NOBIN衍生的希夫碱三齿手性配体，其中4种为非树枝状手性希夫碱配体，12种为树枝状手性希夫碱配体。

It was indicated by UV-Vis spectra characterization that the precursor always contains the tetrahedral Ti species and the octahedral Ti species regardless of the Ti content. Calcination of the precursor resulted in a partial condensation of the octahedral Ti species to form the anatase phase.

UV-Vis 光谱表明，Ti-MWW 合成原粉中含有四面体的钛和八面体的钛，而八面体的钛属于一种骨架外钛，未经酸处理而煅烧会使部分八面体钛缩合形成锐钛矿，而经过酸处理和煅烧后的分子筛则几乎不含有锐钛矿。

First, we extract the boundaries between two different materials by weighting with gray-level gradient,and only voxels on these boundaries participate in the generation of each image, so it drastically reduces the rendering time. Second. We think the voxels on boundaries as the mixture of different materials,so in every voxel there is a surface. We use the oriented cube-interpolation technique to get the intersection point of viewing orientation and the surface in the voxel, then compute the surface normal of the intersection point. We use the normal to shade the voxel in order to improve the image quality.

首先，采用灰度梯度加权提取出三维数据场中不同物质间的边界，根据显示的需要只对这些边界上的体元赋予相应的阻光度并进行光亮度合成计算，因而可大大减少计算量，提高显示的速度；将边界上的体元作为不同物质的混合体，采用与方向有关的三线性插值来计算视线方向与体素内等值面的交点，根据交点的法向量进行光照效应计算以提高显示图像的质量；最后用投影成像法显示最终的图像。

Part 7 is the conclusion of this paper.The main research in this paper includes:1 The 22 mixed ligand complexes were synthesized in which bipyridine-, phenanthroline 5-nitrophenanthroline , phenanthroline- 5,6-dikentone and biquinoline are the first ligand and chlorine ion phenylalanine, tyosine asparagic radical 2.6-diaminocaproic radical tryptophan , histidine malonate(mal2-) benzyl malonate (bmal2-) phenethtyl malonate (pmal2-) are the second ligand.

本文具体研究内容包括四部分：一、合成了以联吡啶、邻菲啰啉、5—硝基邻菲啰啉、邻菲啰啉-5，6-二酮、联喹啉为第一配体，以Cl~-、苯丙氨酸根、酪氨酸根、天冬氨酸根asp~(2-、赖氨酸根、色氨酸根、组氨酸根、丙二酸根mal~(2-、苄基丙二酸根bmal~(2-和苯乙基丙二酸根pmal~(2-为第二配体的共22个混配配合物，制备了其中6个混配配合物和1个单配体配合物单晶，用X-射线单晶衍射法测定了晶体结构。

By using different bidentate auxiliary ligands, a number of one- and two-dimensional azido-bridged coordination polymers and molecular magnets were synthesized, including some with novel structures, and the influences of the ligands on the structure and the magneto-structural correlations in some systems were analyzed.

以不同二齿配体为辅助配体合成了多种一维及二维叠氮桥配位聚合物和分子磁体，较系统地分析了辅助配体对结构的影响及部分体系的磁构关系，并获得几种新的叠氮桥联结构类型。

In order to mimic this repair process of apoenzyme, we synthesized two model compounds, in which tryptophan and/or tyrosine was covalently linked to cyclobutane thymine dimer, and measured the splitting quantum yield of dimer under 295 nm light. By investigating the photosensitized splitting properties of the dimer, some new insights into the intramolecular electron-transfer process were gained.

为了模拟酶蛋白的这一修复过程，合成了色氨酸和/或酪氨酸与胸腺嘧啶二聚体共价连接的化合物，作为酶-底物复合物的模型，研究了它们在295 nm光照射下氨基酸残基光敏化二聚体裂解的性质，测定了二聚体裂解量子产率，获得一些新的结果并对其进行了分析。

The third part of this thesis is reactive simulating calculation In this section, some well-known auxiliaries are selected to compute in density functional theory B3LYP on Gaussian 03, from which the relationship between reaction active energies of transition states and enantiomeric excess of chiral products homoallylic alcohols isobtained based on relative reactive ratio theory. Using this relationship, calculations on the reaction of more than eight auxiliaries with four other aldehydes are carried out in AMI and MNDO, proving that N,N\'-dibenzyl tartamide has higher enantioselectivity than others in this reaction.

第三部分为计算化学部分，运用密度泛函理论B3LYP方法在Gaussian03软件上对已经报道的几种手性配体参与的醛不对称烯丙基化反应过程进行模拟计算，基于相对反应速率理论找出两种构型过渡态间活化能的差异与产物光学收率之间的关系；并以此为基础，用AM1和MNDO方法对上述合成的几种配体控制的反应过程进行量化计算，从而在理论上证实了N-苄基酒石酸二酰胺配体在醛的不对称烯丙基化反应中具有较高的立体选择性。

The performace of material was tested by DSC,XRD,SEM,EIS and charge-discharge cycles . The influences of various synthesized condition , sintering time and the amount of F were studied and correlative technics parameter to improve performance of material were optimized. DSC shows that three endotherimc peaks and one large exothermic peak are observed in the temperature range 150-400℃, which is because of the removal of water,the decomposition of the organic constituents and the formation of spinel. Only the citrate precursor is sintered at least 450℃, the crystallinity of spinel phase could be formed intactly.

通过DSC、XRD、SEM、EIS和充放电循环等手段对材料进行性能测试，比较了不同合成温度、烧结时间和不同掺杂元素量等条件对材料性能的影响，优选出提高材料性能的相关工艺参数， DSC表明，采用溶胶-凝胶-络合法制备的前驱体在150-400℃中有三个小的吸热峰和一个大的放热峰，这是前驱体中的水分、柠酸酸及其盐和醋酸及其盐在蒸发及分解，柠檬酸前驱体至少需在450℃以上才可能形成完整的尖晶石材料。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失