合成体

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

It has been proved that the pressure and temperature of the synthetic room are fluetuant, that is to say the diamond synthesizing point is excursive, when the diamond is synthesized at high temperature and high pressure.

理论分析和生产实践都证明，在高温高压合成金刚石过程中合成腔体的压力和温度随着合成时间的延长而不断变化，即金刚石生长的工作点是漂移的。

It has been proved that the pressure and temperature of the synthetic room are fluctuant, that is to say that the diamond synthesizing point is excursive, when the diamond was synthesized at high temperature and high pressure.

理论分析和生产实践都证明，在高温高压合成金刚石过程中合成腔体的压力和温度随着合成时间的延长而不断变化，即金刚石生长的工作点是漂移的。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构；得到了一个在空间上存在位阻作用的配体与金属离子2：1结构的晶体；解析了具有特色的一个配体（LA4）和三个配合物（4、7和10）的晶体结构，其中的配体与金属离子的配位作用显示出细微的差异，表明在同一金属配合物的晶胞中，可以同时存在着多个稳定的构象。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

Four bidentate NS ester ligands, two bidentate NS amide ligands, tridentate MBPA and tetradentate BMBPA ligands have been synthesized.

合成了四种含有酯基的NS二齿配体-CYE系列物，两种含有酰胺基的NS二齿配体，三齿配体MBPA和四齿配体BMBPA。

In order to investigate the relationship between the open-chain ligands and metal ions, and the possibility of the metal complexes used as electroluminescent materials, a new naphthol schiff base ligand which is a open-chain crown and its four transition metal complexes, a new amide type tripodal ligand containing heterocyclic ring, two tripodal ligands (H〓L〓 and H〓L〓) containing phenol schiff bases and their rare earth complexes were synthesized and characterized.

为了进一步研究和探讨开链配体与金属离子的配位作用，以及金属配合物作为电致发光材料的可能性，我们设计合成了含萘酚环的Schiff碱开链冠醚H〓L〓及四种过渡金属(Zn、Ni、Co、Cu)配合物，两个含酚羟基的Schiff碱三足配体H〓L〓和H〓L〓及稀土配合物，一个含杂环的酰胺型三足配体L〓，培养了配体L〓的单晶，确定了其晶体结构。

Biloba was mainly synthesized in ER and plastids. More or less, mitochondria, Golgi body and ground cytoplasm also took part in the synthesis and transportation of secretory products.

银杏分泌腔内分泌物的合成主要在分泌细胞的质体和内质网中进行，但线粒体、高尔基体和细胞质也似乎参与分泌物的合成和转输。

In this study, Cryptomeria japonica was liquefied in phenol with H2SO4 and HCl as a catalyst. The epoxy resin was synthesized from epichlorohydrin and bisphenol A with the molar ratio of 5/1. Blending resins were prepared by mixing the liquefied Japanese cedar and epoxy resin with weight ratios of 30/100, 50/100 and 70/100, and the triethylene tetramine was added as a cross-linking hardener. The effect of mixing ratios of liquefied Japanese cedar to epoxy resin and amount of hardener added on the reactivity of blending resins and the properties of cured resins were investigated. Furthermore, polysiloxane and rice husk were added as foaming agent and filler, respectively, to the epoxy resin and blending resins. The foaming process, the bubbles shape, the mechanical properties, and the thermal stability of the epoxy foams were investigated.

中文摘要本研究将柳杉(Cryptomeria japonica； Japanese cedar)木材以酚为溶剂，H2SO4及HCl为催化剂进行液化处理，另以莫耳比5/1之环氧氯丙烷与双酚A反应合成环氧树脂，并将液化柳杉与环氧树脂以重量比30/100、50/100及70/100混合制备掺合树脂，并以三乙基四胺(Triethylene tetramine； TETA)为架桥硬化剂，探讨液化柳杉与环氧树脂混合比及硬化剂添加量对其掺合树脂之反应性，及其硬化树脂性质之影响；进一步於环氧树脂与掺合树脂中添加聚矽氧烷为发泡剂，稻壳粉为填料制备发泡体，探讨其发泡体之发泡过程、泡体形态、发泡体机械性质与热稳定性。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失