合成体

The results showed that the addition leading to -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 7 could proceed with good diastereoselectivity and excellent yield (95%).(3) The selective N-deprotection of -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 2 without affecting the vinyl group in the substrate were untaken.(4) The Zip reaction for the transformation of -1-(3-aminopropyl)-3-methylazecan-2-one 8 to -7-Methyl-1, Sdiaza-cyclotetradecan-6-one 9 were undertaken. The results showed that, under controlled conditions, acceptable yields (43%) could be achieved and racemization can be minimized during the ring expansion reaction.

该合成路线与文献方法相比，反应条件较温和，也缩短了反应时间；(2)哌啶衍生物2与乙烯基格氏试剂进行加成反应的条件和立体选择性，取得了较好的结果（差向异构体比为80：20，产率95％左右）；(3)不饱和哌啶衍生物7在不影响碳碳双键的情况下去除苯基甘氨醇手性辅助基的条件；(4)具有羰基α位手性的氨基酰胺8在不同条件下经Zip重排反应转变为9的反应，控制反应条件，可使反应中消旋化减小到最小的程度。

R-4-Methyl-δ-valerolactone was transformed into-methyl 5-bromo-4-methylpentanoate (5) which is a stable and easily reserved reagent.

首次利用甾体皂甙元氧化降解废弃物-4-甲基－δ-戊内酯合成了松叶蜂性信息素(25，3S，7S)-3，7-二甲基－2-十五醇乙酸酯(2)和丙酸酯(3)。

n thes paper, the oligomers with different molecular weight of monohydroxylpolyethersulfones were synthesized in solution and the optimum condition ofpolymerization was obtained; With phase transfer catalyst method,the oligomerswas obtained and transformed to monovinylpolyethersulfones macromer. Its structure was characterized with IR and 1H-NMR.

本文采用溶液法以单酚（4－氯－4'－羟基二苯砜）为原料合成了不同聚合度的单酚低聚体，得到了控制聚合度的最佳聚合条件；用相转移催化剂法成功地将单酚转化为单烯大分子单体，并用IR、1H—NMR对其结构进行了表征；测定了双键官能度均在1.90以上。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明：Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应，同时溶剂极性和薄膜含水量对负载量也影响相当大；本课题首次使用硫代乙酰胺代替传统无机硫源（H2S、Na2S）合成CdS纳晶，研究了各种硫源的组装机理，克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点，得到了有利于光催化传质需要的体相均匀分布CdS/Nafion；研究了多种Nafion膜内纳米粒子晶化途径，找到了简单可靠的水热晶化法，TiO2纳晶最高负载量达43％；初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性，在本实验条件下最高降解率达86％。

Antagonism of MR ablates the normal synthesis of progesterone in response to hCG although the mechanism remains unclear.;It was also concluded that even though mural granulosa cells are less likely to proliferate in response to exogenous stimulus in the form of epidermal growth factor after hCG, proliferation can be enforced in even luteinizing granulosa cells using insulin.

拮抗作用议员ablates的正常合成的孕激素反应机制，虽然目前还不清楚。；也有人得出结论认为，即使壁画颗粒细胞不太可能扩散针对外来刺激的形式，表皮生长因子后绒毛膜促性腺激素，扩散可以强制执行，甚至促黄体颗粒细胞使用胰岛素。

The title compound used as an amino acetylating reagent was further reacted to yield Cefepime hydrochloric acid, the crystals obtained has white pale color and is stable to temperature, and has no E-isomer too.

用其作为氨基酰基化试剂进一步合成盐酸头孢吡肟，也得到基本上白色的对温度稳定的不含E-异构体的晶态化合物。

The formation mechanism of spherical agglomerates of xonotlite in dynamic hydrothermal synthesis has been systematically studies.

系统研究了动态水热合成硬硅钙石球形团聚体的形成机理。

The design and synthesis of effective chiral ligands play important roles in transition-metal catalyzed asymmetric reactions.

在金属介入的不对称催化反应中，手性配体的设计合成扮演着极重要的角色。

The present invention discloses nanometer composite polyester material prepared through polymerizing monomer 1, monomer 2 and nanometer particle.

本发明公开的聚酯纳米复合材料是将合成聚酯的单体1和单体2以及纳米粒子的前驱体一起聚合反应而成。

They have intense absorption bands in the red region so that they can collect more energy available in the solar spectrum.

本文设计合成了一些包括电子给体和受体的简单模型，研究它们在光激发下的相互作用，分子间和分子内激基复合物形成与衰变过程的动力学，分子内三元激基复合物形成的结构条件，取得十分有趣的结果。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失