合成体

Beta-thalassemia major is a serious hereditary hemolytic anemia which does great harm to human being.It is a monogenic disease characterised by a reduced synthesis of beta-globin chains,which dues to the Doint mutation or deletion of beta-globin gene and its control region.It not only decreases the hemoglobin level,but breaks the balance of alpha/beta synthesis ratio.The major cellular pathogenetic mechanisms in beta thalassemia are based primarily on the deleterious effects produced by the accumulation of the excess alpha globin chain.These excess alpha-globin chains cannot form stable tetrameric structure and deposit in erythroid cells.They cause large ineffective erythropoiesis on their own,accelerate red cells destruction,and lead to hemolysis.

地中海贫血是一种对人类健康危害严重的遗传性溶血性贫血病，是因β-珠蛋白基因及其调控序列的点突变或缺失致使β-珠蛋白肽链合成减少或完全停止，这不仅使患者血红蛋白水平降低，而且使原来在数量上与之持平的α-珠蛋白肽链相对过剩，这些相对过剩的游离α-珠蛋白肽链并不能形成稳定的四聚体，它们沉积在红细胞中导致了大量无效红细胞生成和红细胞寿命缩短，引起了严重的溶血性贫血。

MgO nanowires were synthesized at a lower temperature (600℃) by pulsed liquid injection MOCVD with β–diketonate Mg2 magnesium bis (2,2,6,6–tetramethyl- 3,5-heptanedionate, with formula Mg(C11H19O2)2 as precursor.

使用脉冲液滴注入式MOCVD，将Mg2（即：双（2，2，6，6，-四甲基-3，5-庚二酮酸）镁，其分子式是Mg(C11H19O2)2 ）作为反应前驱体，在较低温度下（600℃）合成MgO纳米线。

Synthesis, molecular structure and magnetic properties of tetranuclear copper complexes with pendant-arm macrocyclic ligands.

主研方向：金属离子导向的分子自组装研究，新型大环配体的设计与合成及其离子和分子识别研究，新药开发与铂药物筛选。

Finally, two tetranuclear Cu~(2+) complexes were constructed from a new salen ligand with alkoxo groups. The two complexes were obtained by the reaction of the same ligand with Cu~(2+) in different solvents, i.e., a stage tetranuclear complex and a pseudo-cubane tetranuclear complex in MeOH and THF, respectively.

最后，本文以Schiff碱类过渡金属配合物发展应用为研究背景，设计并合成了一种新型Schiff碱及其两种构型的Cu金属配合物，发现所设计的具有和三个Schiff碱配体，与Cu_2在不同的反应溶剂中进行配位反应时，可以得到不同结构的配合物。

Six new ligands and 2 mononuclear,5 binuclear,8 tetranuclear complexes all of which are new havebeen synthesised and characterized by elementalanalysis,electric conductance and IR,UV-Vis spactr-oscopic methods.

本文主要研究多核配合物中的磁交换相互作用。共合成了6个新配体，2个单核。5个双核和8个四核配合物，并用元素分析，红外，紫外一可见。

Using titanyl sulfate as the TiO_2 source,the experiments for synthesizing TiO_2 nanoparticles were carried out by detonating the mixed explosives composed of the TiO_2 precursor,ammonium nitrate(NH_4NO_3)and cyclortrimethylenetrinitramine,the structures and properties of the as-prepared TiO_2 nanoparticles were also characterized, meanwhile in combination with detonation theory and experimental measurement,detonation parameters,such as detonation heat,detonation temperature were calculated,and detonation velocity was also measured.

以硫酸氧钛为钛源，引爆由氧化钛前驱体、硝酸铵和黑索金组成的混合炸药，进行爆轰合成氧化钛纳米粉的实验研究，对纳米氧化钛的结构和性质进行表征；结合爆轰理论计算和实验测量得到爆热、爆温和爆速等爆轰参数。

A series of modified polyurethane elastomer materials with different amino siloxane content were synthesized,which were based on polyoxypropylene glycol,aminoethyl aminopropyl poly,toluene diisocyanate and the curing agent dimethylsulfide toluylenediamine.

以聚氧化丙烯二醇或聚氧化丙烯三醇、氨乙基氨丙基聚二甲基硅氧烷、甲苯二异氰酸酯为原料在无溶剂条件下制备预聚体，利用二甲基硫甲苯二胺为固化剂合成一系列氨基硅油改性聚氨酯弹性体材料，并对材料的力学性能、耐热性、表面水接触角等性能进行了测试。

Syntheses of Grignard precursor, N - tert -butyl-4-chloro-piperidine, were accomplished via transamination with a quaternary ammonium piperidone or via addition of methylmagnesium chloride to an iminium ion.

氏体合成， N-叔丁基-4-氯哌啶、出自同一个经转氨酶哌季铵盐或透过增设methylmagnesium亚胺离子的氯化物。

With good stability and high reactivity, pyridine-based tridentate N-ligands have been widely used in the fields of coordination chemistry, organic synthesis and homogeneous catalysis.

吡啶基含氮三齿配体具有良好的稳定性和反应活性，在配位化学，有机合成和均相催化中均得到了广泛的应用。

A new unsymmetrical ONO tridentate chain ligand N-(2′-hydroxyl) benzyl-ethanolamine has been synthesized and characterized by elemental analysis, IR and 1NMR.

宗汉兴 ，林瑞森，寇福平，解永树合成了不对称氮氧杂链型配体N-（2′-羟基苄基乙醇胺，通过元素分析、IR和1H NMR等手段进行了表征。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失