合成体

In this dissertation, polyethylene glycol monomethyl ether of 2000 molecular weight as soluble support, an array of soluble polymer-supported tartrate esters were designed, synthesized, and applied in asymmetric epoxidation of allylic alcohols.

本论文以平均分子量为2000的聚乙二醇单甲醚为可溶性支载体设计和合成了一系列可溶性聚合物支载的酒石酸酯配体，并将它们用于烯丙基醇的不对称环氧化反应。

Firstly, a series of organic molecules which use phthalimido group as electron acceptor, N as electron donor, COO~- as eletrofugal group were synthesized based on SET-promoted photocyclization processes. These compounds were irradiated by 500 W ultraviolet under nitrogen atmosphere in room temperature. After filtration of the photochemical character of these molecules, substrate S1 and S2 were selected as appropriate model reactants. Secondly, the monosubstituted derivatives at the 6-position ofβ-cyclodextrin were synthesized as chiral template of photocyclization.

首先，以单电子转移机理为指导，设计了一系列以邻苯二甲酰亚胺基为电子受体、N为电子给体、羧基为离去基团的光环合反应底物，这些化合物在氮气保护下以500瓦紫外光室温下进行光照反应，对这一系列的分子的反应情况进行了研究与筛选，最终选择底物S1和S2作为研究光环合反应中立体控制方法的模型底物；其次，又合成了一系列6-位单取代β-环糊精，以此作为光环合反应的手性模板。

In this study, 0.94(Bi0.5Na0.5)TiO3-0.06BaTiO3 is a composition within morphotropic phase boundary. It was prepared by solid state reaction method. The dense ceramics with various grain size distributions were prepared by adjusting process. And grain size effect on crystal structure, dielectric, ferroelectric and piezoelectric properties were studied in detail.

故本研究将以固态反应法合成(Bi0.5Na0.5)TiO3-BaTiO3系统中之MPB 组成之0.94(Bi0.5Na0.5)TiO3-0.06 BaTiO3，并利用制程的调整以制备具有不同晶粒大小之致密陶瓷体，再来探讨晶粒大小变化对晶体结构、介电性质、铁电性质以及压电性质之影响。

Considering the functions of metal-organic frameworks and the synthesis conditions, we designed and synthesized six metal-organic frameworks based on rare earths by choosing multidentate organic carboxylate ligand, H3CTC, and using mild solvent vapor conditions.

在第二章中，我们利用半刚性的多齿有机羧酸配体——1，3，5-环己三酸与稀土金属元素合成了七个三维具有开放骨架结构的金属有机骨架晶体材料，由于稀土元素在光学和磁学方面的特殊性能，所获得的金属有机骨架材料不仅具有较好的吸附和储存性质，而且拥有金属中心赋予的独特的光学和磁学性能。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

Using pyridine-2, 6-dicarboxylic acid as starting material, a novel ligand N2,N6-bis(3-methyl- pyridine-2-yl)-pyridine-2, 6-dicarboxamide was synthesized,which contained multidentate and large conjugative system.

摘 要：以吡啶-2， 6-二甲酸为原料，合成含有多个共轭体系多齿配体N2，N6-二(3-甲基吡啶)-2-取代吡啶-2， 6-二甲酰胺；同时制备它与稀土离子Tb和Eu的配合物，并培养出单晶。

In this project, a series of novel polypyridine ligands and their ruthenium complexes were synthesized. The scope of this work is focused on the construction of multinuclear complexes, the controlling of electron and energy transfer in polynuclear complexes, NLO materials and molecular recognition, The results should be of value in further understanding the properties of the Ru complex, as well as laying the foundation for the rational design of Molecular devices based on Ru complexes.

本课题的主要目的是应用化学手段，设计合成出一系列结构新颖的多吡啶配体及其钌配合物，在多核配合物的构筑、电子和能量转移调控、非线性光学材料和分子识别等方面进行重点研究，旨在进一步丰富和发展钌多吡啶配合物化学。

On the other hand, N-acylsalicylhydrazidate which contains several donor atoms is a strong chelating agent and is particularly well suited for the preparation of multinuclear complexes, In this paper, two N-acylsalicylhydrazidate ligands and six relevant complexes were synthesized.

本学位论文中，作者以水杨酰肼为原料合成了两个N-取代水杨酰肼配体和六个金属配合物。

Nucleoli are the domains in which transcription and processing of rRNA and assembly of ribosomes take place.

摘要核仁是真核生物细胞的rRNA合成加工和核糖体装配的场所。

N -(4-vinyl)benzylimidazole and its copolymer with octyl methacrylatewere synthesized and characterized,and oxygen—binding properties of cabaltporphyrincomplexes with imdazole ligands were studied.

研究了 N -(4-乙烯基)苄基咪唑单体及其与甲基丙烯酸辛酯共聚物的合成与表征，以及咪唑基有机或聚合物配位体与钴卟啉络合物的氧结合性能。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失