合成体

The nanoTiO2-CNT-PtNi complex catalysts were prepared by the direct hydrolysis of electrosynthetic precursor Ti4 and electrochemical scan electrodepositing method.

采用电合成前驱体Ti4直接水解法和电化学扫描电沉积法制备纳米TiO2-CNT-PtNi复合纳米催化剂。

Firstly,two novel rare earth complexes(CH_2=CHO)Ln~Ⅲ[2,6-_2PhNSiMe _3]_2Li_3Ln=Y(2,Yb(3)containing arylamido and enolate mixed ligands have been synthesized by treatment of 2 equiv of of 2,6-~iPr_2PhNHSiMe_3 with exces n-BuLi at -78℃in THF for 12h,followed by reaction with 1 equiv of LnCl_3at 80℃for 24h in one-pot.All the two compounds were characterized by spectroscopic methods,elemental analyses,and a single-crystal X-ray diffraction study.

首先，-78℃下，在两当量的2，6-~iPr_2PhNHSiMe_3(1)THF溶液中加入过量的n-BuLi，反应12小时，再加入一当量的LnCl_380℃下，反应24小时，一锅法合成了含胺基、乙烯醇基混合配体的新型稀土金属配合物(CH_2=CHO)Ln~Ⅲ[2，6-_2PhNSiMe_3]_2Li_3Ln=Y(2、Yb(3)，上述化合物结构经单晶X-ray衍射、光谱和元素分析表征，表明我们得到的是一类新型的三价稀土配合物。

Ergothioneine is a kind of precious amino acid, and it is also a natural antioxidant. It plays an important role to prevent the oxidative damage in organism. Ergothioneine cannot be biosynthesized in humans, only can be absorbed from the diet. In recently the research discovered the high content of ergothioneine in the mushroom. Content of ergothioneine of Pleurotus eryngii is the highest from 28 kinds of mushrooms, therefore the research untilized P. eryngii to make the products of P. eryngii-fermented adlay and P. eryngii-fermented buckwheat which content high ergothioneine. Also, we analyzed their proximate composition, nutritional components, taste and physiologically active components, antioxidant properties and evaluation of anti-imflammatory effect.

中文摘要麦角硫因为一种稀有的胺基酸，也是天然的抗氧化剂，其在生物体内对氧化压力伤害之预防扮演著重要角色，麦角硫因不能在动物体内合成，仅能由食物中摄取，近年来发现在菇类中含有高含量的麦角硫因，从28种食药用菇类中筛选出麦角硫因含量较高的菌种，以杏鲍菇子实体最高(1521.6 mg/g dw)，因此本论文以杏鲍菇为媒介，利用固态发酵方式，制备出高麦角硫因之杏鲍菇薏仁和杏鲍菇荞麦，并针对薏仁、杏鲍菇薏仁、荞麦、杏鲍菇荞麦和杏鲍菇菌丝体，进行一般成分、营养、物性、呈味、生理活性物质、抗氧化性质之分析及抗发炎反应之评估。

The results showed that various morphologies of barite particles, such as flowerlike aggregates, spheres, rod-like superstructures etc. could be synthesized by changing the concentration of PSMA, pH value of solution, and molar ratio of Ba~(2+) to SO_4~(2-).

结果显示，通过改变PSMA的浓度、溶液的pH值、溶液中钡离子与硫酸根离子的相对比例R等实验条件能够合成各种形貌的硫酸钡颗粒诸如花形片状团聚体、球形、棒状超结构等。

And 〓 are the first of the ligands appended fluorenyl.

合成含芴的配体这是第一个。

We have synthesized fourdioxotetraamine ligand appended with fluorenyl group and their transition metal complexes.The crystal structures of the complexes were determined by x-ray diffraction. Stability,electrochemistry and switch properties in aqueous solution was studied by pH-potentiometricand fluorimetric titration as well as cyclic voltammetry.

合成了带侧链荧光基团—芴的二氧四胺配体及其过渡金属配合物，测定了过渡金属配合物的晶体结构，研究了他们在水溶液中的稳定性、电化学性质和荧光开关性质。

Synthetic fluid inclusions were studied in order to discuss formational mechanisms of homogeneous fluid and boiling fluid in detail.

为详细了解流体的形成机制，对系统的流体包裹体合成实验进行研究。

In this dissertation,we chose some simple ligands as raw materials.A series of metal-organic complex were synthesized under room temperature.Their molecule structures were determined and some relative physical and chemical properties were studied in the purpose of discovering some new phenomena between the structure and NLO properties.It will settle foundation studies for developing this work frothily.

本论文主要以有机磷配体三苯基氧化磷作为起始原料，在温和条件下，设计、合成了一系列金属-有机配合物，测定其晶体结构，并积极开展了一些相关的物理化学性质的研究，努力揭示晶体结构与其二阶非线性光学效应之间的新现象，新问题，为进一步拓展和深化该工作奠定基础。

Totally 17 new type of fulvene ligands have been synthesized by the reaction of substituted-benzoyl chloride with Cp and substituted Cp anions. All the new compounds are fully characterized by infrared spectroscopy,!

我们利用含芳香取代基的环戊二烯丛负离子与含-CN、-I、-CO_2CH_3等配位有机基团的芳酰氯反应成功地合成了17个既含芳香基团又含杂原子配位基团的刚性共轭富烯类配体。

A novel supramolecular complex, [Cu2]CH3OHH2O (fum=fumarate dianion, dpphen=4, 7-diphenyl-1, 10-phenanthroline), has been prepared from the reaction of bidentate ligand, fumarate with CuCl2, and were characterized by element analysis, IR, thermal analysis and X-ray diffraction technique.

利用螯合配体4，7-二苯基－1，10-邻菲罗啉与反丁烯二酸钠及铜盐反应合成了一种新型超分子配合物[Cu2]CH3OHH2O（fum=反丁烯二酸根，dpphen=4，7-二苯基－1，10-邻菲罗啉）。通过元素分析、红外光谱、热分析和X射线单晶衍射等技术对其进行了表征。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失