合成体

Two compounds, [Cu4SO4]n (1) and [Cu(H2O)2SO4]n (2)(im = imidazole, bpy = 2,2'-bipyridine), were synthesized under solvothermal condition in 67% and 82% yields, respectively.

溶剂热体系下采用咪唑、2，2'-联吡啶为配体与硫酸铜合成了2种蓝矾衍生物：[Cu4SO4]n (1)和[Cu(H2O)2SO4]n (2)，产率分别为67%和82%。

In this thesis, we synthesize eight new compounds 5, 11, 12, 16, 5-Zn, 11-Zn, 12-Zn, 16-Zn, which can be absorbed on the surface of nanometer size semiconductors (TiO_2) with four ester groups on the bipyridyl ligands.

本文合成了八个新化合物5，11，12和16以及它们的金属锌的络合物5-Zn，11-Zn，12-Zn和16-Zn。这些化合物可以通过联吡啶配体的酯基吸附在纳米二氧化钛表面。

In this paper, two novel Organic- Inorganic Hybrid Compounds Containing POMs were achieved by selecting POMs with unique structure and properties and organic ligands with bipyridyl groups as building blocks and transition mental cation as templating through hydrothermal reaction.

本课题选择结构和性能独特的多金属氧酸根和多齿有机配体作为构件，以金属离子作为模板合成出新型多金属氧酸盐无机－有机杂化化合物。

They are derived from the condensation of salicylaldehyde with naphthalidine, 2-cyano-4-chloroaniline, o-Toluidine, N-aminoethylmorpholine, benylamine, butylamine, cyclopentylamine and 3-carboxysalicylidene with N-aminoethylmorpholine, benylamine, 2-hydroxyaminoethylamine, ethylenediamine, respectively.

得到了HL1、HL2和HL3配体的单晶；培养出了HL3～HL6、H2L11的Cu配合物，HL7～H2L11的Co配合物和H2L11的Ni配合物的单晶。此外，以5-溴水杨酸(5-bsa)、2-氨基苯甲酸(2-aba)、六次甲基四胺等为原料，合成了3种过渡金属Ag配合物，并培养出了其单晶。

In this paper, the main work has been focused on the rare reported arsenomolybdates, and nine novel compounds have been synthesized. Sandwich arsenomolybdates:(NH_4)_(12)[Cr_2AsMo_7O_(27_2]·11H_2O (1)(NH_4)_(14)[Cu_2AsMo_7O_(27_2]·13H_2O (2) Double sandwich arsenomolybdates:(NH_4)_(12)Cu(H_2O)_4[As_2Fe_6Mo_(22)O_(85)(H_2O)]·19H_2O (3)(NH_4)_(15)[As_2CoFe_5Mo_(22)O_(85)(H_2O)]·16H_2O(4)(NH_4)_(14)Mn_(0.5)[As_2Fe_5MnMo_(22)O_(85)(H_2O)]·22H_2O(5) Cagelike arsenomolybdate:(NH_4)_(11)[AgAs_2Mo_(16)O_(54)]·9H_2O (6) Organic-inorganic molybdenum arsenate complexes:CuAs_6Mo_6O_(30{[Cu_4]_3[CuAs_6Mo_6O_(30)]}_2·6H_2O (7),[Cu_2]_3[As_3Mo_3O_(15)]_2·2H_2O (8)(NH_4)_(10){Cu(H_2O)_4}[AsMo_6O_(21)(O_2CCH_3)_3]_2·12H_2O (9)All of the above polyoxomolybdates were characterized by IR spectroscopy, TG-DSC, elemental analysis, and single-crystal X-ray analysis to identify their structures and chemical compositions.

本文选择目前报道尚少的砷钼杂多化合物为研究重点，合成了不同结构类型的九个新的杂多化合物：单夹心化合物：(NH_4)_(12)[Cr_2AsMo_7O_(27_2]·11H_2O(1)(NH_4)_(14)[Cu_2AsMo-7O_(27_2]·13H_2O(2)双夹心化合物：(NH_4)_(12)Cu(H_2O)_4[As_2Fe_6Mo_(22)O_(85)(H_2O)]·19H_2O(3)(NH_4)_(15)[As_2CoFe_5Mo_(22)O_(85)(H_2O)]·16H_2O(4)(NH_4)_(14)Mn_(0.5)[As_2Fe_5MnMo_22_O_(85(来源：AbcccBC论文网www.abclunwen.comH_2O]·22H_2O(5)笼状结构化合物：(NH_4)_(11)[AgAs_2Mo_(15)O_(54)]·9H_2O(6)有机配体修饰的化合物：CuAs_6Mo_6O_(30{[Cu_4]_3[CuAs_6Mo_6O_(30)]}_2·6H_2O(7) [Cu_2]_3[As_3Mo_3O_(15)]_2·2H_2O(8)(NH_4)_(10){Cu(H_2O)_4}[AsMo_6O_(21)(O_2CCH_3)_3]_2·12H_2O(9)对上述新化合物进行了瓜光谱分析、元素分析、热分析和X-射线单晶衍射测试，确定了它们的组成和结构，对部分化合物还进行了UV-vis及荧光光谱分析和循环伏安表征。

The precursor object was made from the cobalt nitrate,cerous nitrate,carbamide by the methods of hydro-thermal synthesis.It was calcined at the high temperature and the cobalt-cerous oxide powder was obtained.

以硝酸铈和硝酸钴、尿素等为基本原料，采用水热合成法制备出前驱体，经高温锻烧获得铈钴复合氧化物粉体，经TG-DTA，XRD，SEM等检测手段进行表征。

The census encompasses an alphabet soup of projects, including ChEss (Biogeography of Deep-Water Chemosynthetic Ecosystems) and TOPP.

普查报告中含有一系列有关各项目的字母缩写体，包括ChEss（生物地理学之深水化能合成生态系统）和TOPP。

So the key of asymmetric reaction is design and synthesis of the chiral ligands.

因此，手性催化反应的关键是手性配体的设计与合成。

UV-Vis spectrum showed that some monomer or oligomer were existed in this film. The results demonstrated that the PPy chains were served as both the reductant of chloroauric acid and the ligands to stabilize gold-NPs.

接着利用吡咯单体及寡聚体具有的还原性，将新合成的聚吡咯膜浸泡在氯金酸水溶液中搅拌反应，通过扫描电镜观察发现，在膜中还原生成了大量的金纳米粒子，同时在膜的表面也观察到了金纳米粒子的存在。

The effects of cholic acid concentration and pH of the buffer on separation were studied, and the influences of organic additives such as methanol, acetonitrile, isopropyl alcohol were also examined.

该实验表明电化学检测同样可用于手性物质的分离，从而扩宽了电化学检测的应用范围，并为对映体的定量合成和纯度测定找到了灵敏的检测方法。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失