合成体

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为M〓（n=0或2），配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

Benzaldehyde nitrogen mustard isonicotinoyl hydrazone was synthesized according to literature method. The copper , cobalt , nickel , chromium , iron , zinc and cadmium complexes of it were prepared and characterized by elemental analysis, IR, UV-vis, NMR and EPR spectra. The cytotoxicity effect of the complexes was examined on SMMC-7721 cell line. Results show that the complexes have definite antitumor activity and the synergic effect between chromium and the ligand.

依照文献合成了异烟肼苯甲醛氮芥腙及其铜、钴、铬、镍、铁、锌和镉配合物并用元素分析、红外、电子光谱、核磁共振及电子顺磁共振光谱，对这些配合物进行表征，确认了它们可能的立体结构，并研究它们对SMMC-7721人肝癌细胞的作用，结果表明它们均有一定的抗肿瘤作用，发现铬与配体存在有协同作用。

Bromoethyl benzene was synthesized by anti-Markovnikov addition of hydrogen bromide to styrene under ultraviolet light irradiation.

在紫外线的照射下，苯乙烯与溴化氢气体发生反马氏规则自由基加成反应，可合成β-溴乙苯。

Bromoethyl benzene was synthesized by anti-Markovnikov addition of hydrogen bromide to styrene.

通过苯乙烯与溴化氢气体发生反马氏规则自由基加成反应，合成了β-溴乙苯。

High yield,well-defined gold nanocrystals with shape of icosahedron were synthesized by the rapid reduction of gold precursors with ethylene glycolin presence of polyunder hydrothermal condition for 1 h.Au icosahedron is one of multiple twinned particleswhich has 20 faces,each were enclosed by {111} facet.

采用水热法在乙二醇体系中成功的制备出了形状规则、尺寸为200-300nm的二十面体金纳米粒子，研究结果表明，所合成的纳米颗粒是面心立方晶型，每个晶面都是{111}面。

TBO was an incongruent compound and its melting point was 1110℃.

此外我们还合成了Sr〓Ba〓Be〓B〓O〓(0≤x≤1)一系列固溶体化合物。

The former, intracranially complements patients some factors, most frequently with TH gene to compensate scanty of intrastriatal DA and improve the symptoms of the patients, while have little resistance to the progressive degeneration of dopaminergic neurons; The latter provide variety of neurotrophic factors, most specific being the glial cell-line derived neurotrophic factor , to protect the residual DA neurons in the nigrostriatal system from further pathogenic injuries, while have little benefit to those DA neurons with irreversible damage, and them cannot offset the already-existing symptoms.

前者是给宿主脑内补充某些因子，主要是DA合成过程中的限速酶TH基因，以补充纹状体内DA含量的不足，减轻患者的症状，但对DA能神经元的进行性退变没有治疗效果；后者则是提供各种神经营养因子其中最具特异性的为GDNF，以保护黑质一纹状体系统内剩余的DA能经元免受病因的继续损害但对已发生不可逆性损害的DA能神经元并无拯救作用，无法消除已出现的症状。

Triton-X100 has little effect on fermentation, but span-20 and β-ionone could enhance the productivity of lycopene significantly.

研究了不同小分子效应物对三孢布拉氏霉菌合成番茄红素的影响，结果表明：trinton-X100对菌体中番茄红素含量影响较小，span-20、β－紫罗酮和异烟肼可以提高番茄红素的产量，其中添加span-20可使番茄红素产量提高3倍。

A series of L-histidine Schiff bases that include Sal-His (H2L^1), Br-Sal-His(H2L^2), NO2-Sal-His (H2L^3) and their Cu complexes were synthesized, and the catalytic behavior of Schiff-base-Cu for the oxidation of β-ionone to 4-oxo-β-ionone as well as the effects of substitutents on these properties were examined.

合成了芳环上含不同取代基的Schiff碱配体（水杨醛缩组氨酸(H2L^1)、5-溴水杨醛缩组氨酸(H2L^2)、5-硝基水杨醛缩组氨酸(H2L^3)及其铜配合物，研究了其作为催化剂应用于催化分子氧氧化β-紫罗兰酮制备4-氧代－β-紫罗兰酮中的行为。

The modulator could make different effect on fermentation, kerosene and triton-XlOO has little effect on fermentation, but span-20 and J3 -ionone could enhance the productivity of J3 -carotene, significantly. The content of 3 -carotene in the medium reach 2~3 times of the control experiments by adding Ig/L span-20.The effect of the mycelial morphology on producing 3 -carotene of Blakeslea tripora was also investigated.

在研究前体物和促进剂对p一胡萝卜素生产影响时发现：复合前体物添加可以提高产率到2.4倍；研究了不同小分子效应物对三抱布拉氏霉菌合成p一胡萝卜素的影响，结果表明：煤油、trinton一X 100对菌体中p一胡萝卜素含量影响较小，sPan一20可以提高卜胡萝卜素的产量，其中添加sPan一20可使p一胡萝卜素产量提高到2一3倍。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失