合成体

This part we introduce complexes synthesized by hydrothermal method containing inorganic polyacid, bipyrindine, organic polyacid, pyridine-carboyxlate, and mixed polyacid and polybase ligands.

我们分类介绍了，水热条件下合成的含无机的同多或杂多酸配体、联吡啶、有机多酸、吡啶羧酸和混合酸碱配体的配位化合物。

Three chiral mono-quaterized bis-cinchona alkaloid ligands 8, 9, 10 were designed and synthesized. Treatment of 1, 4-dichlorophthalazine with quinine or quinidine provided 〓PHAL and 〓PHAL.

根据金鸡纳生物碱衍生物配体的构效关系，设计并合成了三种手性双金鸡纳生物碱单季铵盐配体8、9和10。

Six Co complexes have been synthesized and their structures were confirmed by IR, UV spectroscope.

3以L~2、L~3、L~4、L~5、L~7、L~8、L~9为配体分别合成了它们的Co配合物，并测定配体及其配合物的红外光谱及紫外光谱，对它们的物理性质进行了初步的研究。

A new free thiol ligand M-C1ABZM based on C1- ABZM was synthesized and characterized 〓 and MS analysis.

以C1-ABZM为原生配体首次合成了含有巯基的单齿配体M-C1ABZM，其结构通过各种图谱方法得到指认。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

The effects of reactive route and temperature on forming control of four isomers were examined in the processes of synthesizing the thymine dimer.

考察了环丁烷嘧啶二聚体合成中反应途径和温度对四种异构体生成的影响和控制。

Tortile octagonal Zn_4O_4 building of μ2-O is edge-bridged by four carboxylates to give a novel topology structure. Viewed along the c zxis, there are channels(10.8A×8.15A)in the structure filled by L1 ligands.

同时，以L1为第一配体，均苯四酸为第二配体与Zn合成了另一个具有新颖结构的三维配位聚合物 [Zn_2(L1)_(0.5)_2]2。

The oligomerization of isoprene with titanium tetrachloride as catalyst and alkylaluminium chlorides as promotor was studied, and especially the effects of the reaction conditions on the synthetic activity and selectivity of dimer and trimer were investigated in detail.

研究了以四氯化钛为主催化剂，以烷基铝为助催化剂催化异戊二烯的低聚反应，详细考察了各种反应条件对催化合成二聚体及三聚体的活性和选择性的影响。

Some experimental techniques such as the dilution rate of flux and sample,preparation of sample with melting,the correction methods of the loss on ignition and the effects of enhancement and absorpt.

采用国家标准物质和以标准物质为基体添加纯试剂合成标样制作工作曲线；研究讨论了熔剂体系及样品的稀释比例、样品的熔融制备、烧失量和基体增强吸收效应的校正。

The reaction of monoporphyrins having different functional groups with dibromopropane gave metalloporphyrin potassium trimer with two alkoxyl linkages(C144H104N12O8K16)and square array tetramer with the property to quench fluorescence.

利用合成带有混合取代基团的卟啉单体和二溴丙烷反应得到了具有荧光淬灭性质的线状卟啉三聚体C144H104N12O8K16和方阵式四聚体。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失