合成体

Rare earth organometallic chemistry is closely interrelated with materials science, organic synthesis, life science. Rare earth organometallic complexes containing Ln-C σ bond and involving silylene-bridged fluorenyl are of important significance in macromolecular and asymmetry organic synthesis.

稀土金属有机化学与材料科学、有机合成、生命科学等学科密切相关，含Ln-Co键稀土金属有机配合物和含硅桥配体稀土金属有机配合物在高分子和有机合成不对称催化领域具有重要意义。

In the thesis, we wish to report the synthesis and structures of a series of new type rigid conjugated nanometer-sized fulvene ligands, and coordination polymeric compounds based on both metal-carbon and metal-heteroatom interactions and also H-bonded supramolecular architectures generated from this new type of fulvene ligands.

基于此，我们合成了一系列刚性共轭的纳米级富烯类配体，并以之与过渡金属离子反应合成了同时基于金属-碳和金属-杂原子两种键合作用的有机-无机配位高聚物及以氢键作用为驱动力的超分子聚集体。

It is worthy pointing out that there are two types of Ag-C bonding models found in 19 including /7\'-C6H6-Ag and /72-Cp-Ag.Three new H-bonded one-dimensional supramolecular compounds, namely M(C3oH2iN2O2)2(C2H5OH)2 M - Cu(II (20), Co (21) and Mn (22), were also synthesized by the reactions of metal (Cu2+, Co2+, Mn2+) acetate with this new type of fulvene ligand.

用所合成刚性多齿有机配体与过渡金属Cu~(2+)(来源：AB4dC论文网www.abclunwen.com)、Co~(2+)、Mn~(2+)的醋酸盐反应，分别合成了含七员金属环的配合物(20—22)，在固态下，20—22为分子间氢键驱动的一维链状超分子聚集体。

A process approaching 3 and 4 chlorophthalic anhydride in high purity via chloriation of o xylene , oxidation of monochloro o xylene by air in gas phase,and separation of 3 and 4 chlorophthalic anhydride afterwards by distillation is described.

介绍由邻二甲苯氯代，再经空气氧化及异构体分离合成氯代苯酐中试规模的合成路线。

Based on these techniques, one-dimensional rare earth orthovanadate nanorods doping with Eu~(3+) ions were synthesized by adding 2～5% mol Eu(NO_3)_3 respectively.

在合成一维LaVO_4、CeVO_4和YVO_4纳米棒的最佳工艺参数的基础上，在前驱体中添加2～5％mol的Eu(NO_3)_3水热合成了具有较好一维形貌的掺Eu的LaVO_4、CeVO_4和YVO_4纳米棒。

These results suggest that the activate spleen-energy method can achieve appetitive purpose by not only affecting the gastrointestinal tract function in periphery, but also regulating the process of ingestion in brain. The basic research about ingestion indicate: one hand, after food enters the gastro-intestinal tract, the endocrine cell of the intestinal tract is activated and secrete many kinds of brains intestines peptide, the level of the brain intestines peptide in blood as the periphery signal spreads to the central nervous system regions that control digest and feeding behavior. On the other hand, it has been shown that dorsal parabranchial neurons, containing CCK-8S, extend fibers to the VMH and are involved in the inhibition of feeding .

关于摄食控制的基础研究表明，一方面食物进入胃肠道后，激活肠道的内分泌细胞，分泌多种脑肠肽如CCK-8S，这些脑肠肽在血中的水平作为外周信号可通过&肠—脑轴&传入中枢神经系统介导消化和摄食行为的部位，影响摄食中枢神经元的活动调节动物的摄食行为；另一方面中枢神经元可合成释放内源性的神经肽直接作用于摄食中枢神经元调节摄食，如中枢鳃旁体神经元的神经纤维就可延伸到达VMH，并且合成释放内源性的CCK-8S。

The total synthese three natural compounds to explore enantioselective synthesis of flavanol: We use phloroglucin and 2, 4, 6-trihydroxyacetophone as starting materials to synthesis distenin in two ways; Resorcin was used to synthsis 2, 5-dimethoxymethoxyacetophone though 3 steps.

对黄烷醇化合物的立体选择性全合成进行了探索：以间苯三酚和2，4，6-三羟基苯乙酮为原料，尝试用两条路线对Distenin化合物进行了全合成研究；以对苯二酚为原料，经三步制得2，5-二甲氧甲氧基苯乙酮，与2，4，6-三甲氧甲氧基苯甲醛反应，经四步反应得到天然产物3，5，7，2′，5′-二五羟基黄烷关键中间体1-（2′，6′-二甲氧甲氧基苯）-3-（2&，4&，6-三甲氧甲氧基苯）丙烷-1R，2R-二醇83及其对映体84；简要介绍了EGCg类化合物的生物活性和研究概况。

Expanding pinacol reductive coupling reaction into asymmetric one with both diastereoselectivity and enantioselectivity may lead to its application in synthesising medicaments and biologic active compounds with structure of vicinal diol. Asymmetric pinacol coupling reaction is also the most compact and effecient method in synthesizing chiral ligands or chiral auxiliary with C〓 symmetry.

将这一反应发展成为既有高度的非对映选择性，又有高度对映选择性的不对称偶联反应在合成许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用，同时不对称Piancol偶联反应也是合成C〓对称性的邻二醇多用途手性配体或手性助剂的最为简捷有效的方法。

The content of intermediates such as protochlorophyll,Mg protoporphyrinand protoporphyrin IXwere reduced and δ aminolevulinc acid and porphohilinogenwere markedly accumulated in albino seedlings of W1,which proved that there was a blockage in the formation of uroporphyrinogen or coproporphyrinogen during Chl biosynthesis under lower temperature.

白化苗中Chl生物合成的中间产物原叶绿素、镁原卟啉、原卟啉IX含量减少，而δ氨基酮戊酸和胆色素原大量积累，证明突变体W1低温下Chl生物合成卟啉原形成部位受阻

This dissertation involves the syntheses, reactivities and structures ofGroup 6 metal carbonyl complexes containing the pyrazole ligands.

本论文开展了对含吡唑类配体的VIB金属羰基配合物的合成、反应及结构的研究，合成了70余个新化合物，并取得了如下研究成果。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失