合成体

Aluminosilicate mesoporous molecular sieves are synthesized with natural ore and microcline as main raw materials,and the precursors of 13X zeolite as crystal source,by integrating the synthetic procedures of mesoporous MCM-41 and microporous 13X zeolite.

以天然矿物微斜长石为主要原料，13X沸石前驱体为晶核剂，结合介孔分子筛MCM-41与13X沸石合成工艺，合成了孔壁中含有13X沸石基本结构单元的铝硅酸盐介孔分子筛。

Aluminosilicate mesoporous sieve s with 13X zeolite units in the pore wall were synthesized with a natural ore,microcline,as the main raw material,and the precursors of 13X zeolite as the crystal source,by integrating the procedures for MCM-41 and 13X zeolite synthesis.

以天然矿物微斜长石为主要原料，以13X沸石前驱体为晶核剂，结合介孔分子筛 MCM-41与13X沸石合成工艺，合成了孔壁中含有13X沸石基本结构单元的铝硅酸盐介孔分子筛。

Aluminosilicate mesoporous sieves with 13X zeolite units in the pore wall were synthesized with a natural ore, microcline ,as the main raw material,and the precursors of 13X zeolite as the crystal source,by integrating the procedures for MCM-41 and 13X zeolite synthesis.

以天然矿物微斜长石为主要原料，以13X沸石前驱体为晶核剂，结合介孔分子筛MCM-41与13X沸石合成工艺，合成了孔壁中含有13X沸石基本结构单元的铝硅酸盐介孔分子筛。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

Two ligands L~Ⅵand L~Ⅶhave been designedand synthesized containing different terminal groups and using benzo-12-crown-4 as theskeleton, and their 18 rare earth nitrate and picrate complexes also have been synthesizedand characterized.

第二章：以五种不同种类水杨酰胺为功能末端基设计合成出以苯并-15-冠-5为骨架的配体L~Ⅰ～L~Ⅴ，并合成了其稀土硝酸盐和苦味酸盐的10个系列共51个稀土配合物。

Short chain fatty acid, propyl alcohol, methionine and dimethylamide are the possible precursors for spiramycin formation. Addition of 0.6% propyl alcohol into fermentation medium increases the spiramycin productivity by 24%, while addition of short chain fatty acids, methionine, or dimethylamide has a repression effect on spiramycin production.

合成螺旋霉素的前体物质可能有短链脂肪酸、丙醇、蛋氨酸和二甲胺等，在发酵培养基中加入0.6％的丙醇可以使螺旋霉素的发酵单位提高24％，而短链脂肪酸、蛋氨酸和二甲胺对菌体生长和螺旋霉素的生物合成有不同程度的抑制作用。

On the other hand, 3(2)-fluoro-4-methoxyl methyl benzyl alcohol and 3(2)-fluoro-4-methyl benzyl alcohol are mixture and components of pyrethrum esters. Both of them have "mixture fluorine effect " and higher activity, lower drug resistance. As we know, the mixture benzyl alcohol containing fluorine is more easy to be synthesized than the single, so the cost of preparation is lower. We hope to apply it to molecule design of the new agriculture chemical. On the base of molecule design and structure-activity relationship research of pyrethric acid II and mixture of alcohol containing fluorine, we intend to get new pyrethrum ester that have higher activity and lower resistance.

另一方面，混合含氟对甲氧甲基苄醇和混合含氟对甲苄醇都是具有"混合氟效应"的高活性、低抗性的拟除虫菊酯醇组分，由于混合含氟醇的合成要比单一异构体的合成容易，成本较低，本文希望将其应用到新农药的分子设计中，用第二菊酸和一些含氟醇进行分子设计及进一步的构效关系的研究，筛选出一些高活性低抗性的拟除虫菊酯换代新品种。

Chiral aminoalcohol is an important kind of chiral substance in the asymmetric synthesis, meanwhile, it is widely used in the field of medicine synthesis and the resolution of raceme.

手性氨基醇在不对称合成领域中是一类重要的手性源，同时，手性氨基醇在药物合成、外消旋体拆分等领域也具有广泛的用途。

The test with the gravity anomalies and gravity gradiometry data of the synthesized Y-type dyke and multiple rectangular prism models shows that the method can image the spatial extension states and the distribution of equivalent excess masses of anomalous geological bodies with high resolution both longitudinally and transversely.

通过合成Y型岩脉模型和合成多个直立长方体组合模型的重力异常和重力梯度数据试验分析，验证了本文三维相关成像方法可显示出异常地质体的空间赋存状态和等效剩余质量分布，具有良好的纵向和横向分辨率。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失