合成

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下，经4，5-二溴甲基-1，3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1，ω-二巯基衍生物的缩合反应，方便地合成了4，5-位带二硫杂冠醚残基的2-硫代-1，3-二硫杂环戊烯的衍生物8a~8d，中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下，经4，5-二溴甲基-1，3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1，ω-二巰基衍生物的缩合反应，方便地合成了4，5-位带二硫杂冠醚残基的2-硫代-1，3-二硫杂环戊烯的衍生物8a~8d，中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

He thyrotropin-releasing hormone is a bioactive peptides Synthesized and excreted from hypoghaiamus. It is the mainphysiological action that stimulates the Synthesis of antehypophysis, release of thyroid-stimulating hormone and excretion of prolactin.

RH是由下丘脑合成和分泌的活性肽之一，主要生理作用是促进垂体前叶合成和释放促甲状腺素，并能促进催乳素的分泌，它又是一种中枢神经谏U激剂，可以细8精神抑郁症。

Spraying with chitosan of different concentration significantly increased the content of chlorophyll ,anthoxanthin ,chlorogentic acid, polyphenal ,soluble protein and total soluble sugar of Broccoli flowers. 40 mg L-l chitosan showed the most remarkable effet,compared to control, the content of chlorophyll ,anthoxanthin ,chlorogentic acid, total soluble sugar and soluble protein of treated Broccoli flowers increased by 64.4%,282.5%,35.6%,16.2% 22.7% respectively.PAL and PPO are key enzymes in synthesize of phenolics.No relation was found between phenolics synthesize and PAL activity in Broccoli flowers,but it showed positive relation between phenolics synthesize and PPO activity.

研究表明，本研究中，不同浓度几丁聚糖喷施对青花菜花球的叶绿素、类黄酮、绿原酸、多酚总量、可溶性蛋白及可溶性总糖的含浙江大学硕卜学位论文(2004)量有显著增加，其中以浓度为40mgL一'影响最为显著，花球中的叶绿素、类黄酮、绿原酸、可溶性总糖、可溶性蛋白分别较对照提高64.4%、282.5%、35.6%、 16.2%、22.7%，苯丙氨酸解氨酶、多酚氧化酶是酚类物质合成中关键酶，花球内酚类物质合成与苯丙氨酸解氨酶的活性没有一定的相关性，而与多酚氧化酶的活性呈正相关。

A new synthesis method for 15NL-tryptophan by yeast fermentation using glucose as carbon source, ammonium sulphate as nitrogen source, and 15N anthranilic acid as a precursor is described.

以葡萄糖为碳源，硫酸铵为氮源，15N邻氨基苯甲酸为前体物，利用酵母发酵合成15NL-色氨酸，是合成15NL-色氨酸的一种新方法。

Terminated DFA-PEG-PPG tripolymer polyester,which was synthesis by adding long chain fatty acid or fatty alkanol into the reactionsystem, contained not only chain lipophilic group but also polyester-polyether group,and had the building effection of alkanol antifoaming reagent and polyether one. Thenovel design theory for structure of antifoaming reagent was put forward by studyingperformance of product.

这种新型结构聚酯的合成，为消泡剂分子结构的设计提出了一种的思路；采用嵌段聚合方法所合成的_m-_n嵌段聚酯型高分子表面活性剂，其分子量比DFA-PEG和DFA-PEG-PPG三元共聚酯的分子量更大，所表现出的乳化性能更为优秀。

OK, so far this perfect anabolic causes massive protein synthesis like the synthetics, but doesn't shut down your natural testosterone production, in fact, increases it, plus it doesn't "aromatize" and convert to estrogen.

好， 这完善的促合成起因巨型的蛋白质综合到目前为止喜欢合成物质，但不关闭您的自然睾甾酮生产，实际上，增量它，加上它&不芳香化&和不转换成女性荷尔蒙。

Bifluoro nitrobenzene was the raw material of synthesis of asymmetry chromotropic acid bisazo fluoroarsen reagent, By way of ammonia substitution, arsonation, reduction and coupled reactions, bisazo fluoroarsen was synthesized.

以2，4—二氟硝基苯为起始原料，经过氨取代、胂酸化、还原、偶联反应合成了偶氮氟胂Ⅰ，然后分别选择不同的取代苯胺与偶氮氟胂Ⅰ偶联，合成了一系列的不对称变色酸偶氮氟胂。

In this dissertation, we also reported a facile stereoselectivesynthesis of (2E, 4E)-2,4-dienals via arsonium salt.

二在合成研究中，我们还发现利用砷盐由醛一步高度立体选择性合成(2E，4E)-2，4烯醛的简便方法。

Making use of this reaction, thirteen methyl 2-arylamino-2-deoxy 3-keto glucopyranosides (5～17) with different substituted arylamino groups and two

选择不同类型的芳胺利用该反应合成了一系列共十三种2-脱氧2-芳胺基3-位氧化α-甲基D-葡萄糖苷（5～17），该类化合物为重要的手性合成子。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失