合成

The pure isomers 3-(1-hydroxyethyl)-8-vinyldeuteroporphyrin Ⅸ and 3-vinyl-8-(1-hydroxyethyl)deuteroporphyrin Ⅸ were obtained from protoporphyrin Ⅸ dimethyl ester.Starting from these two acetylating compounds,eight new porphyrin derivatives were synthesized through an alkyloxy fission reaction.

以原卟啉Ⅸ二甲酯为起始原料，合成并分离得到3-(1-羟乙基)-8-乙烯基次卟啉Ⅸ（Ⅱ1）和3-乙烯基-8-(1-羟乙基)次卟啉Ⅸ（Ⅱ2）二个异构体，两者分别经酰化后与醇进行烷氧裂解反应合成了8个全新的卟啉衍生物。

Allene oxide synthase is a key enzyme for JA biosynthesis.

丙二烯氧化物合成酶是茉莉酸生物合成的关键酶。

During the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)CH=CH2, several stable osmacycles with novel structure, such as osmabenzenes, osmafurans, osmacycles containing intramolecular-coordinated allene, intramolecular-coordination osmacycles containing osmacarbene, an osmacyclopentadiene, were isolated during the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2-CH=C(PPh_3C(=CH_2)CH=CH_2.In addition, some convenient and efficient methods to prepare these osmacycles were developed.

首先，合成出两种具有反应活性的金属杂五元环IC配合物OsCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2和OsCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)-CH=CH_2，并对它们进行了系统表征；进而，研究了这些活性五元配合物的反应性，合成出多种稳定的锇杂环配合物，其中包括锇苯、锇呋喃、含配位联烯的锇杂IC环化合化物、含锇卡宾的IC环化物、首例锇杂环戊二烯化合物等多元化的产物。

The results show that the quality of AlN thin films are improved with the increase of N2 flow rate.

摘 要：介绍了一种应用电子浴辅助阴极电弧源法合成AlN薄膜的新方法，研究了N2流量、阴极偏压、工作气压等工艺参数对合成AlN薄膜质量的影响规律。

Al〓O〓-TiC and Al〓O〓-TiB〓 ceramic composites were synthesized using TiO〓, Al and graphite and TiO〓, Al, and amorphous B〓O〓 powders via aluminothermic reactions, respectively.

采用TiO〓、Al和石墨原料合成了Al〓O〓-TiC复相陶瓷，研究了压坯压力、试样直径、原料中铝粉和石墨颗粒、TiO〓的晶型、过量铝和Al〓O〓稀释剂等对燃烧合成过程及产物微观结构的影响。

When additive sulfur is mixed with powdered catalyst, the surface integrity of diamond will be destroyed with different degree, especially (100) surface, the more additive sulfur is added, the more cavities appear on surface. The cavities almost show irregular and alveolate shape.

有添加剂硫参与合成时，两种粉末触媒合成的晶体表面的完整性具有不同程度的破坏，尤其是（100）晶面，随着添加剂硫含量的增加，晶体的表面出现孔洞缺陷，孔洞的形状多为不规则的&蜂窝状&。

Peptide synthesis. PMAP-23 peptide was synthesized by the solid phase method using Fmoc(9-fluorenyl-methoxycarbonyl)-chemistry.Rink Amide 4-methyl benz hydrylamine resin (0.55mmol/g) was used as the support to obtain a C-terminal amidate peptide.

多肽合成。萨夫- 23肽合成固相法芴-化学 try.rink 酰胺4 -甲基奔驰hydrylamine树脂( 0.55mmol /克)，被用来作为支持以获得一个c端酰胺肽。

Add up to content to synthesize a lot of inadequacy in the method in view of amidine apperception, introduced a few kinds of new methods that synthesize amidine, enlarged the limits of raw material, raised yield.

鉴于脒类化合物合成方法中的诸多不足，介绍了几种新的合成脒的方法，扩大了原料的范围，提高了产率。

The general formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

The genera formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失