合成

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点，但是目前国内外大量报道的PILM制备大多采用离子交换法，生产周期很长，影响因素很多，并且产物热稳定性不够高，特别是水热稳定性较差，这是其不能在实际中大规模生产和应用的主要障碍，因此制备一种高稳定性的PILM意义非常；文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物，传统的离子交换法必须将钙基蒙脱石钠化改型，其成本相当高，而自然界中大量存在的却是钙基蒙脱石，直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义，但目前这方面的报道却很少见；另外，迄今为止，PILM作为催化剂的研究领域主要在石油的炼制中应用，而在煤炭的液化中却鲜有报道，如果能在煤炭转化领域应用这一成果，其影响也将是相当大的。

The approach identifies all possible focal elements from the incomplete decision matrix, then constructs the DS-AHPs hierarchical structure model, calculates the basic probability assignment of each focal element and the belief interval of each decision alternative.

该方法首先对决策矩阵中属性值进行识别，生成DS-AHP方法的焦元集合；然后构造DS-AHP的判断矩阵，并运用Dempster合成法则对判断值进行合成，从而确定方案排序。

A commercial and practical synthesis rout with-2-(3-acetoxy-l-me-thyl-l~propenyl)-5,5-dimethyl-l,3-dioxane as starting material by couple,oxidation, Ramberg-Backlund and deprotection is chosen and studied in this paper.

本文选择了以2-(3-氯-1-甲基-1-丙烯)-5，5-二甲基-1，3-二噁烷为原料，经偶连、氧化、Ramberg-Bcklund反应及脱保护基四步反应的合成路线，对该中间体进行合成研究。

Short chain fatty acid, propyl alcohol, methionine and dimethylamide are the possible precursors for spiramycin formation. Addition of 0.6% propyl alcohol into fermentation medium increases the spiramycin productivity by 24%, while addition of short chain fatty acids, methionine, or dimethylamide has a repression effect on spiramycin production.

合成螺旋霉素的前体物质可能有短链脂肪酸、丙醇、蛋氨酸和二甲胺等，在发酵培养基中加入0.6％的丙醇可以使螺旋霉素的发酵单位提高24％，而短链脂肪酸、蛋氨酸和二甲胺对菌体生长和螺旋霉素的生物合成有不同程度的抑制作用。

The item will establish a set of producing propyl- aldehyde 20 thousand t/y and its backwards' process using the advanced technology above. The main productions are propyl- aldehyde, propyl- alcohol propyl-ache, and etc..

本项目拟建设一套2万吨/年丙醛生产装置及其下游产品加工装置，采用国内研制开发的以催化稀乙烯和合成气为原料的羰基合成工艺，主要产品有：丙醛、丙醇、丙酸、丙酸钙、丙酸钠和丙酸胺等。

D-lactic acid is considered to be a very important chemical compound as a chiral material or intermediate in organic synthesis. D-LA is a prosoma of many chiral compounds with applications not only in the pharmaceutical and cosmetic industry but also in highly efficient and lowly toxic pesticide and herbicide.

D-乳酸是重要的手性中间体与有机合成原料，是多种手性物质的前体，广泛应用于制药、化妆品和高效低毒农药及除草剂等领域的手性合成。

The thesis was designed to optimize the cultures of producing D-LA bySporolactobacillus sp. and analyze the effects on fermentation in order to produceD-LA effectively.D-lactic acid is considered to be a very important chemical compoundas a chiral material or intermediate in organic synthesis. D-LA is a prosoma of manychiral compounds with applications not only in the pharmaceutical and cosmetic industry but alsoin highly efficient and lowly toxic pesticide and herbicide.

本研究的目的是通过对芽孢乳杆菌发酵工艺的研究，建立一条产物光学纯度高、工艺简单，成本较低的D-乳酸生产路线。D-乳酸是重要的手性中间体与有机合成原料，是多种手性物质的前体，广泛应用于制药、化妆品和高效低毒农药及除草剂等领域的手性合成。

In this thesis, some chemical approaches in liquid phase have been employed to prepared Prussian Blue analogue.

在本论文中，我们通过几种液相法合成技术制备纳米普鲁士蓝衍生物材料，旨在寻找有效控制合成各种结构纳米普鲁士蓝衍生物的方法。

On the other hand, 3(2)-fluoro-4-methoxyl methyl benzyl alcohol and 3(2)-fluoro-4-methyl benzyl alcohol are mixture and components of pyrethrum esters. Both of them have "mixture fluorine effect " and higher activity, lower drug resistance. As we know, the mixture benzyl alcohol containing fluorine is more easy to be synthesized than the single, so the cost of preparation is lower. We hope to apply it to molecule design of the new agriculture chemical. On the base of molecule design and structure-activity relationship research of pyrethric acid II and mixture of alcohol containing fluorine, we intend to get new pyrethrum ester that have higher activity and lower resistance.

另一方面，混合含氟对甲氧甲基苄醇和混合含氟对甲苄醇都是具有"混合氟效应"的高活性、低抗性的拟除虫菊酯醇组分，由于混合含氟醇的合成要比单一异构体的合成容易，成本较低，本文希望将其应用到新农药的分子设计中，用第二菊酸和一些含氟醇进行分子设计及进一步的构效关系的研究，筛选出一些高活性低抗性的拟除虫菊酯换代新品种。

In the second chapter, a series of pyridine derivatives are synthesized.

第二章，吡啶类衍生物的合成和表征，共合成了25种化合物，其中目标产物15种。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失