合成

In THF solution, the four compounds show intensive photoluminescence and have large two-photon absorption cross section, and the TPA cross section gradually increases with increasing phenothiazine units.

3通过优化卟啉的合成方法，合成了两个以吩噻嗪齐聚物为臂的卟啉的分子，这类卟啉分子在溶液和薄膜中都具备高的荧光量子产率，有望在光子学器件中得到应用。

The major goal for our research is to use simple synthesized method for various fluorescence dye derivatives containing Phenothiazine core via Heck reaction and Suzuki coupling reaction that unprotected at 10N-H.

中文摘要本实验的研究目的为利用简单的合成步骤：在Phenothiazine 的3，7-位置上，藉由Heck reaction和Suzuki coupling reaction直接合成出 10NH没有保护基的萤光染料。

B yusing UV, MI, TGA and DSC techniques, the effects of phenoxide groups andits relative concentration on the structure and propenies of PEEK during Synthsisand processing have been studied.

本文用稍过量4、4'－二氯苯酮合成的聚醚醚酮样品，利用UV、MI、DSC和TGA等研究本氧阴离子及其相对浓度在树脂合成和加工过程中对PEEK分子结构和性能的影响。

This article through the belt hydroxyl aldehyde class material and the chloroacetic acid response, the synthesis intermediate, then with the neighbouring phenylene diamine responded again synthesized 6 kind of benziminazole class compound, including 4 kinds not to report.

本文通过带羟基的醛类物质和氯乙酸的反应，合成中间体，然后再与邻苯二胺反应合成了6种苯并咪唑类化合物，其中有4种还未被报道。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

A series of convenient and efficient reactions have been developed. Especially, instead of using toxic phosgene, the triphosgene was employed in the synthetic process of some receptors, which provides a convenient. safe and efficient method for the preparation of chiral unsymmetrical urea.

深入研究了它们的合成方法，实现了多种简便有效的选择性合成，特别是以三光气代替剧毒的光气，实现了一条简便、安全、有效的制备手性不对称脲的方法。

Phosgene has been used in many organic syntheses, notably of isocyanates; but its commercial use has been largely discontinued because of its toxicity.

光气被广泛应用于有机合成，尤其是异氰酸盐的合成，但由于光气毒性巨大，限制了它在商业上的应用。

The identified proteins were divided into two following categories: one is regulatory proteins, for example, caffeic acid 3-O-methyltransferas, HSP70, glyoxalase I , actin, and so on. They are involved in protein biosynthesis and processing, cellular structural organization and stress responses. The other is function proteins, for instance, ascorbate peroxidase, cytoplasmic malate dehydrogenase, cytosolic phosphoglycerate kinase, S-adenosyl methionine synthetase, ATP synthase, and so on. They are involved in photosynthesis, photorespiration, redox homeostasis, and metabolisms.

通过分析可以将这些差异蛋白分为两大类：第一类是调节性蛋白，如咖啡酸三氧转甲基酶，热激蛋白70，醛酮变位酶I，肌动蛋白等，它们主要参与蛋白质的合成和加工、胁迫响应、细胞骨架稳定等过程；第二类是功能性蛋白，如抗坏血酸过氧化物酶，细胞质苹果酸脱氢酶，细胞质磷酸甘油酸激酶，S-腺苷蛋氨酸合成酶，ATP合酶等，它们则参与氧化还原平衡、光合作用、光呼吸和各种代谢等过程。

The purpose of this paper is to synthesize some phosphonium salts with PPh3 and some chiral quaternary ammonium salts with L-Valine. And we also use L-Valine and L-Phe-OMe to synthesize a new type catalyst —2,5-diketopiperazine , the simplest compound of cyclo-peptide.

本文利用廉价易得的三苯基磷和手性L-缬氨酸作为起始原料，合成了几种普通季鏻盐和手性季铵盐，并且利用L-缬氨酸与L-苯丙氨酸甲酯反应，合成了一种新型的相转移催化剂——2，5-二酮哌嗪环类的化合物。

Several synthesis of phosphoric acid monoester was introduced,and their strong suit and defect were compared.

介绍了磷酸单酯的各种合成工艺路线，并比较了它们的优缺点，提出了聚磷酸法是合成高纯度磷酸单酯的最佳路线。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失