合成

In this paper, through a series of experiments, two series of quaternary-ammounium Gemini surfactants were synthesized, namely the pair alkylene double quaternary ammonium salt surfactant m-s-m·2Br and the pair the alkylene double quaternary ammonium salt surfactant -s-·2Br. We has carried on the attribute with the infrared spectrum to its structure, and to affected the factor which the synthesis pair the alkylene double quaternary ammonium salt surfactant responded to carry on the discussion. We has discovered the synthesis pair the ethylene double quaternary ammonium salt surfactant m-2-m·2Br optimum condition: The bromo alkane and a tetramethyl ethylene diamine mole of ratio is 3.0: 1.0, makes the solvent by the ethyl alcohol, 80℃ under responds for 48 hours in the backflow temperature; Synthesis pair alkylene double quaternary ammonium salt surfactant 12-S-12 ·2Br optimum condition: 12 tertiary amine and 1, 3- propylene dibromide (1, 4- two bromines butane) a mole of ratio is 2.2: 1.0, makes the solvent by the ethyl alcohol, responds for 48 hours in the constant temperature 80 ℃ under backflow.

本文通过一系列的实验，合成了两个系列的Gemini型表面活性剂，即双烷撑双季铵盐表面活性剂m-s-m·2Br和双烷撑双季铵盐表面活性剂-s-·2Br，用红外光谱对其结构进行了表征，并且对影响合成双烷撑双季铵盐表面活性剂反应的因素进行了讨论，找出了合成双乙撑双季铵盐表面活性剂m-2-m·2Br的最佳条件：溴代烷与四甲基乙二胺的摩尔比为3.0：1.0，以乙醇作溶剂，在回流温度80℃下反应48小时；合成双烷撑双季铵盐表面活性剂12-s-12·2Br的最佳条件：十二叔胺与1，3-二溴丙烷(1，4-二溴丁烷)摩尔比为2.2：1.0，以乙醇作溶剂，在恒温80℃下回流反应48小时。

A novel endocyclic enamine cyclopentenone annulation was discovered and rationalized as an unusual Nazarov-type electrocyclization, which would have broad applications in the synthesis of natural alkaloids and other heterocycles.

我们在合成路线一、路线二中用的6-6元环系到7-5元环系的还原重排反应，在温和的酸性还原条件下即能发生，这说明在三尖杉碱的生物合成中6-6元环到7-5元环的还原重排步骤是非常有可能发生的；因此，我们的合成路线二中可认为是生物合成过程。

In this paper, various synthetic methods of coenzyme Q10 appeared in about half a century were reviewed with emphasis on the semi-chemosynthetic methods using natural solanesol extracted from tobacco as starting material. The key factors and development direction of coenzyme Q10 chemosynthesis were illustrated in this paper as well.

笔者根据半个世纪以来有关辅酶Q10化学合成的各种文献报道，对辅酶Q10现有的各种化学合成路线及其工艺优劣进行了介绍和比较，重点介绍了从烟草中提取天然茄尼醇为原料的半化学合成辅酶Q10方法，并阐明了化学合成辅酶Q10的关键因素和发展方向。

To regulate policy composition and guarantee its correctness, an algebraic model called APoCA (attribute-based access control policy composition algebra) is proposed for composing access control policy. In APoCA, an authorization relation between entities is described at the attribute level. APoCA fertilizes the existing formal frameworks by taking into account the computation of attribute values.

为了规范策略合成和保障策略合成正确性，基于属性刻画了实体间的授权关系，通过属性值的计算结构扩展了现有的策略合成形式化框架，建立了新的基于属性的策略合成代数模型APoCA(attribute-base access control policy composition algebra)。

The article includes three parts. The first, a steroselective and regioselective synthesis of digitoxin with glycosyl ortho-alkynylbenzoates as doners. The second, synthesis of different length chain of L-fucose with a SO3Na group in the position of C-2 hydroxy.

本文工作主要包括三部分内容，分别为采用全新发展的一种邻炔基苯甲酸酯的糖基供体进行地高辛的全合成并与常规的Schimidt供体及三氟亚胺酯供体进行结果比较；合成不同长度的2位硫酸化的岩藻糖糖链；对现有的合成伏格列波糖的一条合成路线进行工艺优化。

Pinacol reductive coupling reaction of aldehyde and ketone is one of the most important methods in forming C-C bond, which may also produce vicinal diol as valuable intermediate compound applied in the synthesise of natrual products.

醛酮的Pinacol还原偶联反应是合成C—C键的重要方法之一，同时合成的邻二醇类化合物是重要的有机合成中间体，已被应用于许多含有邻二醇结构的复杂天然化合物总合成中。

On the way, By giving the example as the names of the thing (such as silk silks etc.) with color and the basic colorific phrase associated with it, this text demonstrated a fact that the basic colorific phrases were evolved from the names of the thing that include the color, under the function of the come from the method that is borrowing the thing assumes the color, and expatiated the condition of the basic colorific phrase in Chinese language. Take the synthesize colorific phrase implied compliment or dispraiser as an example, explained the imagism of Chinese thought method how to influence the synthesize the colorific phrase, and do it by taking the food, metals and nature scenery makes the ratio at other Chinese thought method that is take shape to analogy as too. It expatiated the influence that the Han ethnologic culture result in the acceptation of the colorific phrase, pass on analyze the diverse the diverse metaphor meanings of colorific phrase and the opposite phenomenon of acceptation among them of, and the colorific etyma metaphor of "yellow","vermilion","purple","blue","green" and "white", under the premise that distinct the different between themetaphor meanings of colorific phrase and colorific etyma metaphor.

由此本文通过例举有色彩含义的事物专有名称及相应的基本色彩词，分析了基本色彩词是在"借物呈色"思维方式的影响下，由有色彩含义的事物专有名称演变而来的事实，并阐述了汉语基本色彩词的状况；以含有褒扬、贬抑语义的合成色彩词为例说明了汉民族"意向性"思维方式对合成色彩词的影响，以取食物、金属、自然界景物作比的合成色彩词为例说明了汉民族"取象类比"思维方式对合成色彩词的影响；在区分色彩词隐喻意义与色彩语素隐喻意义的基础上，通过分析色彩词的多元隐喻意义及其中的语义对立现象，并分析"黄"、"朱"、"紫"、"青"、"绿"、"白"等色彩语素的隐喻意义，阐述了汉民族文化对色彩词语义的影响。

Detonation method is cheap, governable and handy. It can product manifold kinds of compound. It is supplementary method of general synthesis method, may substitute general synthesis method inmany ways.

爆轰方法是一种廉价、可控、简便合成方法，适于多种化合物的合成，可以作为常规合成纳米材料的补充方法，在许多方面有替代常规合成方法的潜能。

By the algorithm, the surfaces are first divided into a series of mapping areas and synthesis areas using the constraints of the triangles' normal and texture attributes. Then the mapping areas are textured by harmonic mapping from the 2D mapping sample, by a patch-based synthesis method. Finally, the synthesis areas are textured by a triangle-based synthesis method.

首先以三角形法向量、切向矢量与纹理尺度为约束，将三角网格曲面分割为一系列映射区与合成区；然后用基于块的平面纹理合成方法生成大面积样图，用调和映射方法对映射区进行纹理映射；最后采用基于三角块的合成方法生成合成区纹理。

There are three main synthesis routes:direct synthesis of imines;one-pot synthesis of imine with oxidation;one-pot synthesis of imine with reduction.

主要有三种合成路线：直接合成亚胺；一锅法氧化合成亚胺；一锅法还原合成亚胺。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！