合成

The results show that the synthetic compounds conform to the target compounds and the primary bioassay for anti-vibrio activity displays that the pyrrole alkaloids have a weak inhibition against Vibrio parahaemolyticus and Vibrio alginolyticus compared with the positive control of chloromycetin.

结果表明，所合成的化合物与目标化合物结构相一致。初步的抗溶藻弧菌和副溶血弧菌活性筛选表明，合成的吡咯生物碱具有一定的抗弧菌活性，但相对于阳性对照药氯霉素来说，合成的绝大部分吡咯生物碱抗弧菌活性较弱。

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

In the first chapter, the class of modern frequency composing techniques and the recent development situations have been introduced. Then the advantages and disadvantages of the techniques have been described. At last, based on the techniques mentioned above, a scheme to realize the X-band low phase noise frequency source has been proposed.

在第一章引言部分，主要介绍了现代频率合成技术的分类及技术发展近况，并就每一种合成技术的优缺点做了简要的陈述，最后以上述不同合成技术的优缺点为基本指导思想，提出了一种实现X波段低相噪频率源的方案。

Although many synthetic routes to spiro[4,5]decane have been reported, few reports have been focused on the asymmetric synthesis of the title compounds.

虽然有关旋环状[4，5]癸坑的合成途径已经被报导，但其中仅有少数几篇是利用不对称合成方法来合成具有光学活性的此类化合物。

Compared to other alternatives, the approach is in favor of the consistency with Dempster's rule in form as well as flexible process of combination.

这种预处理一方面解决了合成过程中可能导致悖论的标准化问题，符合人类的日常思维习惯，并且在形式上和Dempster合成规则保持一致，同时在证据合成方面也更为灵活。

According to concerned papers ,we have chosen the way in which diquat dibromide is synthesized from 2,2-bipyridyls and ethylene dibromide. This paper makes further research into its technology, thus obtaining better synthesizing conditions.

本文在查阅大量文献的基础上，采用以2，2'-联吡啶和1，2-二溴乙烷为原料合成敌草快二溴盐的合成路线，并对其合成工艺进行了深入的研究，筛选出较佳的工艺条件。

Hydrolysis of 2,3-epoxy-butanol-p-methylbenzensulfonate (12) in acidic aqueous media gave chiral vicinal diol (2) in high enantioselectivity (95% ee).2. The chiral vicinal diol s play an important role in organic .

手性邻二醇在有机合成中具有重要的用途，它们是理想的手性合成砌块，可用于合成多种手性药物，许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用。

In this thesis, for the first time, we attempted at preparing a library of 20×20 dipeptide aldehydes based on 20 natural amino acids by parallel solution phase method.

本论文以20个天然氨基酸为原料，利用液相平行合成技术进行了一个20×20的二肽醛化合物库的系统合成的尝试，并进一步合成了3，6-二取代-5，6-不饱和-2-哌嗪酮化合物库。

The reaction of polyfluoroalkyl iodides with 4-pentenoic acids initiated by sodium dithionite was realized to give polyfluoroalkyl substituted lactones.

我们研究了多氟烷基碘代烷与4-戊烯酸类化合物等在连二亚硫酸钠引发下的反应，得到了氟烷基取代的内酯化合物，我们将该反应称为氟烷基化内酯化反应；并建立了一个利用该反应合成含氟内酯的新方法，首次利用氟烷基化内酯化反应进行高立体选择性双环含氟内酯及手性含氟内酯等的合成，已合成含氟内酯新化合物50余种。

The expression of cogging torque is deduced on dual-stator permanent magnet synchronous machine, and the influence rules of the resulting cogging torque are analyzed with the change of relative angle between dual stators. The relation between cogging torque amplitude and the relative angle between dual stators is investigated. Finally, simulation verification is conducted based on finite element method.

针对双定子永磁同步电机，推导了内外定子及其合成齿槽转矩的解析表达式，分析了内外定子相对位置变化对合成齿槽转矩的影响规律，着重研究了合成齿槽转矩幅值与内外定子相对位置的关系，最后用有限元方法进行了仿真验证。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失