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Linear alkyl benzenes and linear alkyl dimethyl benzenes, prepared by the alkylate reaction of linear alpha olefin with benzene or dimethyl benzene which were sulfonated by chlorosulfonic acid and then neutralized to produce linear alkyl benzene sulfonates and linear alkyl dimethyl benzene sulfonates.

本文以一定链长的直链α-烯烃分别与苯和混合二甲苯为原料制备了直链烷基苯和烷基二甲苯,经氯磺酸磺化,中和可得到具有一定链长的直链烷基苯磺酸盐和直链烷基二甲苯磺酸盐。

The results showed that new-type solid ferric potassium alum was a good catalyst for the synthesis of ethyl decanoate and the optimum conditions were as follows: molar ratio of acid to alcohol was 1∶2, the use level of catalyst was 0.6 g/0.05 mol capric acid, water-taking reagent benzene was...

结果表明,新型固体酸铁钾矾是合成癸酸乙酯的良好催化剂,在酸醇物质的量比为1∶2,催化剂用量为0.6g(0.05mol癸酸),带水剂苯为15mL,反应时间为2.5h的条件下,癸酸乙酯的酯化率可达98%。

The results showed that new-type solid ferric potassium alum was a good catalyst for the synthesis of ethyl decanoate and the optimum conditions were as follows: molar ratio of acid to alcohol was 1:2, the use level of catalyst was 0.6g/0.05 mol capric acid, water-taking reagent benzene was 15 mL, reaction time was 2.5 h and the yield of ethyl decanoate could reach 98%.

结果表明,新型固体酸铁钾矾是合成葵酸乙酯的良好催化剂,在酸醇物质的量比为1:2,催化剂用量为0.69(0.05 mol癸酸),带水剂苯为15mL,反应时间为2.5h的条件下,癸酸乙酯的酯化率可达98%。

This paper gives some commensurable researches utilizing experiment combining theory. The whole paper consists of the theoretical and experimental researches. The first part consists of the fundamental study of foamed acid, the flowage of foamed acid as a Non-Newton fluid in the pipe and annular pipe, and the technology of acidification using foamed acid; and the experimental study includes the formula experiment of foamed acid, the Rheological behavior of foamed acid, the seepage and divided flow in the corn of foam, and appraisal experiment of foamed acid.

本论文采用实验和理论结合的方法,开展了相应的研究工作,主要包括两大部分内容:一是理论研究,包括泡沫酸的基本性质、泡沫酸流体作为可压缩非牛顿流体在井筒和环空中的流动规律、以及泡沫酸酸化工艺等方面的理论研究;二是实验研究,包括泡沫酸的稳定性配方、泡沫酸的流变特性、泡沫流体渗流规律和暂堵分流特性、泡沫酸室内评价等室内实验。

L-Amino-2-bromo-4-hydroxy- anthraquinone could be obtained by coordinated hydroxylation of l-amino-2- bromo- anthraquinone, boric acid and the initiator potassium iodide or bromide with 97.5%yield and 99% purity.

在用HPLC跟踪溴氨酸的合成过程研究中发现,1-氨基蒽醌-2,4二磺酸在溴化过程中可转化为产物溴氨酸。

It is pointed out that under the condition of the temperature of 1120℃, the reaction time of 16 mm and the carbon content of 27%, the metal transformation rate of sponge iron used for general metallurgy is up to 90%. But the optimal carbon content is 29% for iron sponge to treat DSD acid oxidation wastewater. Under condition of the wastewater's pH value of 3 to 5 and the reaction time of 40min, the removal rates of COD and color are 68% and 90%, respectively. The BOD/COD ratio is up to 0.425 when DSD oxidation acid water is treated with sponge iron.

研究表明:在配碳量27%、反应温度1160℃、反应时间16min的情况下,以铁泥为原料制备的常规海绵铁的金属化率可达90%以上;用于处理DSD酸氧化废水的海绵铁适宜配碳量为29%,用制备出的海绵铁处理DSD酸氧化废水,在pH值3~5、反应时间40min时,出水的COD去除率可达68%、色度的去除率达90%、可生化性指标BOD/COD提高到0.425。

It was found that ARA was composed of esterification products of (2-HEA)-ester with pimaric acid, dehydroabietic acid, abietic acid and two isomers of acrylpimaric acid. ARA is a good crosslinking agent which can copolymerize with most vinyl monomers. The properties of solvent-resistance and heat resistance of the copolymer were improved considerably by the use of ARA.

实验结果表明:ARA主要由海松酸、脱氢枞酸、枞酸和丙烯海松酸的二种异构体的丙烯酸-2-羟基乙基酯的酯化产物组成,ARA是一种良好的交联剂,可与大多数乙烯基单体共聚合,其与MMA的共聚物的耐溶剂性和耐热性均得到了较大幅度的提高。

Studies also indicated that genistein exsists not only in soybeans but also in many kinds of plants such as vegetables and fruits.As a potential anticancer agent, the actional mechanisms of genistein mainly includes as follows:First, genistein can depress the activity of protein tyrosine kinase and transduction pathways for the phosphorylation of receptors and mitosis signal. So genistein can lead to cells' proliferation depressed. Second, genistein has minimal effects of phytoestrogens. It can be combined with estrogen receptor and improve the synthesis of cellular sex hormone binding glulobin, and improve the activity of UDP-glucuronyl transferase. Through these pathways, it can inhibit the cell activity of breast cancer and prostate cancer.

作为一个很有潜力的抗肿瘤物质,三羟异黄酮的作用机制主要包括:①抑制蛋白酪氨酸激酶活性,可阻抑PTK引起的受体磷酸化和有丝分裂的信号传递,导致癌细胞增殖受抑;②弱雌激素作用:可通过与体内雌激素受体结合,并可增加细胞内性激素结合球蛋白的合成,增加UDP-葡糖醛酸转移酶的活性等途径抑制乳腺癌和前列腺癌细胞活性;③拓扑酶Ⅰ和Ⅱ抑制剂,抑制细胞活性;④上调细胞周期性负性调节因子P21WAF1/CIP1的表达,使之负性调节因子作用增强;⑤可阻止胰岛素样生长因子-Ⅰ、肝细胞生长因子和神经生长因子的作用而抑制肿瘤生长;⑥其他:抗氧化作用、抑制热休克蛋白、诱导细胞凋亡、抑制新生血管生成和抑制多种耐药相关蛋白等。

Discussion Diphenylacetic acid can be prepared by the reduction of benzilic acid with hydriodic acid and red phosphorus,1 by carbonation of the reaction product of phenylsodium and diphenylmethane,2 and by hydrolysis of 1,1-dichloro-2,2-diphenylethylene.3

讨论 Diphenylacetic酸可编写的减少benzilic酸hydriodic酸和红磷, 1碳化反应产物phenylsodium和二苯基甲烷,第2和水解1,1 -二氯- 2 ,2 - diphenylethylene 0.3

Phospho-tungstic heteropoly(H3PW12O40) was prepared and its catalytic performance for synthesizing of ethyl hexanoate from hexanoic acid and ethyl alcohol were studied.

结果表明:磷钨杂多酸是合成己酸乙酯的良好催化剂,当酸醇物质的量比为1∶2.0,催化剂用量为0.5 g/0.1 mol己酸,甲苯为8 mL,反应时间为150 min时,酯化率可达97.2

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