变构

Meanwhile, the isomer with a larger change of dipole moment has larger value of the first hyperpolarizability during the charge-transfer process.

5， 6， 7顶点双取代碳硼烷桥连分子受推拉电子基的影响，5， 6， 7顶点碳硼烷的构型发生一定变化，碳硼烷中两个C原子间的距离变长；同时碳硼烷中两个C原子取代位置的不同，影响了分子的稳定性和极化率，取代基团与碳硼烷中成键数较低的C原子相连的异构体，稳定性较好且具有大的极化率； 5，6，7顶点双取代碳硼烷桥连分子形成一维结构有利于分子内电荷转移，在电荷转移过程中偶极矩变化较大的体系，其二阶NLO系数也较大。

A new cyclic constitutive model for sands which can describe the deformation behavior of sands under combined variation of principal stress axes and magnitudes was developed based on the above physical fundamentals. And its effectiveness under the complex stress paths including cyclic rotation of principal stress axes is verified by a good comparison of model simulation with test results for sands.

2基于对应力主轴循环旋转条件下砂土的基本变形规律的认识，吸收和借鉴已有弹塑性本构模型研究成果中的合理概念和建模方法，建立了一个可合理描述应力主轴循环旋转效应及主应力幅值大小与应力主轴方向循环耦变效应的砂土弹塑性本构模型，并对该模型在包含应力主轴旋转的复杂循环应力路径下的有效性进行了验证。

In this topic, the dynamic analysis methods for piezoelectric vibrator are studied systematically based on the theoretical model, FEM numerical experimentation and FEM governing equation for given compound-mode vibrator, and some valuable conclusions are obtained. The main work accomplished is summarized as follows: 1.Elaborate the main modeling methods for piezoelectric vibrator and the significance and necessity to study the dynamic characteristics of piezoelectric vibrator which emphasize the urgency of this paper. 2.Take the bending deformation induced by piezoelectric ceramic as example, the energy transfer mechanism of electric energy to mechanical energy are analyzed; the motion and force transfer mechanism are analyzed for the longitudinal-bending vibrator. 3.Based on mode assumption and Hamilton principle, the coupling model of piezoelectric vibrator of linear USM is built; moreover, the equivalent circuit model is obtained and a coupling equation represents the relation between electric parameters and mechanical parameters is derived which provides foundation to match the vibrator and driving circuit. 4.Combine the constitutive equation of piezoelectric ceramic with elastic-dynamical equation, geometric equation in force field and the Maxwell equation in electric field and the corresponding boundary condition equation, the FEM control equation for piezoelectric vibrator of USM to solve dynamic electro-mechanical coupling field is established by employing the principle of virtual displacement. The equation lays the foundation to study the non-linear constitutive equation of piezoelectric ceramic driven by high-power. 5.Define the dynamic indexes of characteristic of vibrator and carry out variable parameters simulation by calculating the model parameters and the electric characteristics of vibrator are simulated according to the equivalent circuit model. By numerical experimentation, the working mode of vibration of vibrator and the shock excitation results of the working frequency band which provides the mode frequency to realize bimodal are analyzed. Detailed calculation of the electro-mechanical coupling field parameters is made by programming the FEM control equation.

本课题从理论模型、有限元数值试验、有限元控制模型等方面以复合振动模式振子为例对超声电机压电振子的动力学特性及其分析方法进行了全面系统地研究，得出了许多有价值的结论，主要概括如下： 1、阐述了目前针对超声电机压电振子的主要建模方法，对压电振子动态特性的研究意义和必要性进行了论述，突出了本文研究内容的迫切性； 2、以压电陶瓷诱发弹性体发生弯曲变形为例，分析了压电陶瓷通过诱发应变来实现机电能量转换的机理；对基于纵弯模式的压电振子的运动及动力传递机理进行了分析； 3、基于模态假定，利用分析动力学的Hamilton原理，建立了面向直线超声电机压电振子的机电耦合动力学模型，并据此建立了压电振子的等效电路模型，导出了电参量与动力学特性参量的耦合方程，为压电振子与驱动电路的匹配提供了依据； 4、从压电陶瓷的本构方程出发，综合力场的弹性动力学方程、几何方程、电场的麦克斯韦方程以及相应的边界条件方程，采用虚位移原理，建立了压电振子动态问题机电耦合场求解的有限元控制方程，为研究其大功率驱动下的非线性本构模型奠定了基础； 5、界定压电振子的动力学特性指标，对压电振子的机电耦合动力学模型参数进行计算及变参数仿真；依据等效电路模型，对压电振子的电学特性进行了仿真分析；通过有限元数值实验，对压电振子工作模态附近的模态振型及工作频率附近的频段进行了激振效果分析，找出了实现模态简并的激振频率；利用有限元控制方程，通过编程计算，对压电振子的力电耦合场参数进行了详细计算，得出了一些有价值的结论。

In addition nC〓, nC〓, two isomers of C〓 sterene and three isomers of C〓 isoprenoid hydrocarbons were also identified from aliphatic fraction of pyrolyzed product at 200℃. After pyrolyzed at 300℃, the main aliphatic hydrocarbons were normal alkanes ranged from C〓 to C〓, with C〓 as the main peak and C〓 as the second main peak. Meanwhile, pristane, phytane and C〓 sterane were also detected. In the pyrolysates at 400℃ and 500℃, the content of saturated hydrocarbons decreased, the range of normal alkanes distribution became narrow and the main peak was nC〓. Low concentration of C〓-C〓 steranes was detected and the content of C〓-C〓 increased more.

在200℃热模拟产物饱和烃馏分中除检测出两种长链烯烃外，还检测到正十九碳单烯烃、正三十五碳双烯烃、两个碳二十八甾烯的同分异构体和三个C〓类异戊二烯烷烃化合物同分异构体。300℃模拟产物饱和烃主要为正烷烃，正烷烃的碳数分布范围为C〓-C〓，以C〓为主峰、C〓为次主峰；另外，样品中还检出姥鲛烷、植烷和C〓甾烷等化合物。400和500℃热模拟产物中的饱和烃含量下降，正烷烃系列碳数分布范围变窄，主峰碳后移至C〓，检测到低浓度的C〓-C〓甾烷系列化合物，另外，C〓-C〓藿烷系列化合物含量进一步增加。

Changes of silver carp muscle protein s during chilled storage;2. The changes of rheology,texture and color of minced pork after the cooking respectively in water bath,retort and microwave were tested,based on which the effects of muscle protein and transglutaminase contents on the gel properties of minced pork were then investigated.

结果表明：3种热处理方法下，一定量的转谷氨酰胺酶及肌肉蛋白使猪肉糜表现出不同的颜色和质构特性；与其他两种方法相比，水浴加热使猪肉糜更具有弹性；加入MTGase后，样品的储能模量G′增大，表明MTGase的加入影响了猪肉糜的流变特性、颜色以及质构，其效力取决于猪肉糜的热处理方法。

A one-dimension divided linear model is established on the simplified calculation and the transformation characteristic of SMA in superelastic state.

在形状记忆合金常用的本构关系模型的基础上，结合SMA处于超弹性状态的相变特点，通过适当的简化，建立了分段线形的本构模型，并通过国产NiTi形状记忆合金丝材的拉伸试验对模型进行了验证。

Through the helminthes examination, according to the numerical Analysis, we get the detail parameters of the four-asphalt-mixed viscous elasticity. Through the mixed asphalt"s temperature-time effect, we get four materials" viscous elasticity in different temperature.

通过室内蠕变试验，运用数值分析手段得到了四种沥青混合料的一维粘弹性本构模型的具体参数，利用沥青混合料的温度时间效应的得出了不同温度四种材料的粘弹性本构模型参数。

The study on the constitutive relation of solid materials with special microstructures and behavior, one of which is martensitic transform...

具有特殊细微观结构和响应行为的固体材料本构关系研究是固体力学和材料科学关注的热点，马氏体相变材料的本构关系研究就是其中之一。

The total energy, standard enthalpy, standard entropy and standard free energy were obtained. The calculations show that 5-fluorouracil and 5-chlorouracil existing as the dione forms are the predominant isomers in the gas and aqueous phases. The entropy effect on the Gibbs free energy of 5-fluorouracil and 5-chlorouracil is very small and there is little significance for the tautomeric equilibria.

Onsager反应场溶剂模型用于水相的计算计算结果表明，5-氟尿嘧啶和5-氯尿嘧啶在气相中和水相中主要以双酮形式存在5-氟尿嘧啶和5-氯尿嘧啶的熵效应小，对互变异构平衡没有显著的影响，而焓变对互变异构产生了主要的影响。

And we also research the impact of methylating on hydrogen bond and stacked bond in base pairs under considering water molecules.

研究结果表明，烷基化之所以能造成碱基错配是它可使碱基的质子迁移或烯醇互变现象容易发生，改变原有原子的电荷分布或配对模式，同时碱基自身的互变异构体会跟烷基作用，致使互变异构体能够稳定存在，影响正常碱基配对，引起碱基诱变，造成生理疾病的发生。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！