取代物

It was found that copolymerization of selected acetylenes with different polarity by using palladium acetylide complex catalysts is an effective method for improving solubility of polymers, especially doped polymers, which makes the above mentioned polymers and doped ones a new type of π-conjugated sensing material for preparation of thin film humidity sensor.

研究发现，以新型过渡金属钯-炔配合物为催化剂，通过选择具有不同极性的取代乙炔单体进行共聚，可有效地提高聚合物的溶解性，尤其掺杂聚合物的溶解性，实现可溶酸掺杂，继而开发出上述系列新的π-共轭型聚炔湿敏材料，用以制备薄膜型湿敏元件。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1，4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

X-ray single crystal diffraction study reveals that the Zn atom is five-coordinated, Furthermore, a 2D superamolecular network is constructed via the tetracarboxylate bridged binuclear of Zinc SBU ,and the amino substituent results in the formation of hydrophilic 2D structure of the title complex.

该配合物中，锌离子为5配位，2个Zn原子和4个羧基形成的双核锌结构单元，进而形成二维方格式平面结构，氨基取代基导致配合物具有亲水性。

The optimum reaction condition for preparation of CoPcY is as follows: a , using CoCl2 as the exchanged salt ; b , complexation temperature of 180 ; c . complexation catalyst of NH4C1 and A1C13 .2, The unsymmetrically substituted cobalt phthalocyanine complexes were synthesized by statistical condensation of phthalic anhydride and tetrabromophthalic anhydride, and further immobilized in MCM-41 molecular sieves by zeolite synthesis method, as well as characterized by XRD,FT-IR,DRS, 1HNMRetc. The catalytic property of CoPcBrx/MCM-41was tested by cyclohexane oxidation using H2O2 or t-BOOH as oxidant.

2采用本路线制备CoPcY的最佳条件为：a、采用氯化钴作为待交换的金属盐；b、络合温度以180℃为宜；c、起始反应物为苯酐、尿素、氯化铵、氯化铝、CoY时，制备出的CoPcY的催化性能最好； 2、首次采用苯酐和四溴苯酐均相浓缩统计合成法制得了不对称取代的金属钴酞菁络合物，并采用~1HNMR、FTIR、DRS等对其进行了结构表征；此外，采用沸石合成法将其固定于MCM-41中孔分子筛，并对其催化性能进行了考察。

Bartering of goods and services has replaced money.

以物易物的商品和服务已取代金钱。

The enthalpies of some compounds were measured. And decomposition temperatures of some compounds were determined by thermogravimetric analyzer.

在合成实验中，研究了反应物分子结构，反应物配比对钯催化偶联反应速率及反应产率的影响，首次发现钯催化偶联反应中的取代反应，对观察到的实验现象给出了理论上的分析和解释。

The system of barter was superseded by the use of money.

以物易物的制度被金钱的使用取代了。

In chapter two,six isoeuxanthone derivatives (HL~1-HL~6) and metal complexeshave been synthesized and characterized by elementary analyses,molar conductivity,infrared spectra,~1H NMR and mass spectra.

第二章：以异优呫吨酮为母体合成了六个取代基团各异的吨酮衍生物(HL~1-HL~6)及其金属配合物，并通过元素分析、摩尔电导、红外光谱、~1H NMR以及质谱表征了配合物的结构。

The regularities of the substitution effects of the electron-pushing group and the electron- withdrawing group on the electronic structures and the related properties of the complexes, e.g. the energies and the compositions of some frontier molecular orbitals, the spectroscopy properties, the atomic net charge populations on main ligands, the coordination-bond lengths and the coordination-bond angles of the complexes, etc. have been investigated.

探讨供电子基团和拉电子基团在主配体上的取代对配合物的电子结构及相关性质，如配合物前沿分子轨道的能量、组成、光谱性质、原子的净电荷布居及配位键长键角等的影响规律。

The effect of molecular weight, ethylene group and mixing of polyketone on the photodegradability were investigated. The mechanism of the photodegradation of ESTCO, STCO, STCO-PS and ESTCO-PS were reviewed. In addition, the block polymerization of methyl methacrylate initiated by STCO under UV irradiations was also studied.

研究了乙基取代基、分子量及共混物对聚酮光降解性能的影响，探索了STCO、ESTCO及其分别与聚苯乙烯共混物STCO-PS、ESTCO-PS的光降解行为和光降解机理，初步探讨了聚酮ESTCO光降解所产生的大分子自由基引发的甲基丙烯酸甲酯的聚合。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。