取代物

In chapter three,we investigated a new Baylis-Hillman-type reaction,organozinc speciesCF_3COOZnEt can react withα,β-acetylenic ketones and N-tosylated imines providing Baylis-Hillman adducts in good yield in the absence of any catalysts.

有机锌试剂CF_3COOZnEt可以与各种类型的α，β-炔酮及亚胺发生偶联反应，高产率的得到β-取代的Morita-Baylis-Hillman反应加合物，这类反应不需要任何的催化剂，产物具有立体单一型，完全是Z式结构。

Third, Polymerization behaviors of alkenyl substituted Cp Lanthanide complexes as Methyl Methacrylate polymerization catalysts were also studied.

最后，本文还分别考察了烯丁基和烯丙基取代茂的稀土络合物对甲基丙烯酸甲酯的催化聚合反应。

By using this methodology, alkenyl silanes which have useful applications from a synthetic point of view could be easily obtained.

藉由改变起始物硫缩醛的取代基，或是使用不同的格林那试剂，我们能利用此烯化反应得到在有机合成上有许多应用的有机矽化合物。

The effects of alkoxy chains, metal ions of complexes and molecular space structure on liquid properties have been investigated.

考察了取代基、金属离子和配合物的空间结构对液晶性能的影响。

Second, the polymerization behaviors of alkoxyl substituted Cp titanocene for styrene syndiotactic polymerization were investigated.

其次，本文研究了烷氧基取代的茂钛络合物对苯乙烯间规聚合的催化作用。

On this basis, three soluble poly derivatives with asymmetric alkoxyl substituents copolymers were synthesized by copolymerization with different PPV derivatives. The luminescence characteristic and thermal performance of three copolymers were improved by copolymerization.

在此基础上，采用共聚的方法，将具有不同结构的PPV衍生物分子进行共聚，合成了三种可溶性不对称烷氧基取代聚对苯乙炔共聚物，从而改善了材料的热性能和光致发光特性。

It was found that the binaphthyl backbone of S configuration was matched to the S, S pyrrolidino group. In this case, the asymmetric allylation product could be obtained in 85. 6% ee.

轴手性是S构型时，和中心手性S，S构型相匹配，它和钯形成的络合物在催化烯丙基取代反应时，取得了比不含中心手性因素的吡咯烷基氮膦配体高得多的对映选择性，可以得到85.6％ee值的产物。

In order to develop an useful synthestic process, we have synthesized amides with various substitutents. The isoquinoline skeleton was constructed through Bischler-Napieralski reaction, followed by asymmetric reduction of the imine intermediates with a Ru complex to form the only chiral center. Finally, we connected the two phenyl groups by Heck reaction and effectively obtained optically active aporphine alkaloids.

为了发展一套实用的合成方法，我们首先制备於苯环上具有不同种取代基的苯乙醯胺，接著透过Bischler-Napieralski反应进行分子内合环，并利用钌金属对亚胺中间体进行不对称的还原反应，建立出产物中唯一的光学活性中心，最后再利用Heck反应连结两个苯环，就可以顺利得到具有光学选择性的阿朴吩类天然物。

In the presence of ethanol- HCl solution, arylamine-HCl and w=37% aqueous formaldehyde solution or the condensation product of arylamine and formaldehyde are directly reacted with ethyl 3-oxo-2-phenylmethylenebutyrate to form l-aryl-2-phenyl-3-carbethoxy-4-piperidone.

2－苯亚甲基－3－丁酮酸乙酯与芳香胺和w＝37％甲醛水溶液或芳胺和甲醛的缩合物在氯化氢－无水乙醇存在下可直接发生的Mannich反应，得到1－对位取代芳基－2－苯基－3－羰乙氧基－哌啶－4－酮。

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论；能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性；掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。