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The basic structure of chromogen in PFBs remains the same, so PFBs have fluorescent properties of traditional FBs. Covalent bonds between chromogen and macromolecule chains enhance their photochemical stability, increase their whitening performance and fluorescence quantum yield.

聚合型荧光增白剂中基本发色团的结构不变,具有传统荧光增白剂的光学性能;发色团与高分子链间的共价键使其光化学稳定性大大增强,增白性能和荧光量子产率显著提高。

It consists of a chromophore and an apoprotein, and the former has the activity to attack DNA, whereas the latter plays the role in protecting chromophore.

其分子由一个酸性的辅基蛋白和一个发色团结合而成,发色团是LDM的主要活性部分,起着直接断裂DNA的作用,而辅基蛋白的主要作用是保护发色团。

In this thesis,rare earth and transition metals complexes providing second-ordernonlinear properties and their LB films were studied.

本文主要研究含有机发色团的稀土及过渡金属配合物LB膜及其二阶非线性光学性质。

The thermo-optic coefficients of polymer solution by using Abbé refractometer were demonstrated at natural light and a series of single wavelength lights, respectively.

合成了侧链含染料发色团的聚氨酯-酰亚胺,采用红外光谱、示差量热扫描、热失重分析等手段对合成的PUI进行了表征。

Copolymers with the naphthoyimine chromophores were firstly obtained through Pd-catalyzed Heck reaction. The copolymers had good solubility in common solvents due to the presence of alkoxyl substituents in the molecular chains.

在钯催化下利用Heck耦合反应制备了以萘酰亚胺为发色团的共聚物,通过侧链上引入丁氧基醚链,使得聚合物具有很好的溶解度,能溶解在常用有机溶剂中。

A number of monoaza-15-crown-5 ether derivatives linking naphthyl or anthrylchromophores have been designed and synthesized, and their photophysical propertiesand self-assembly behavior in different media have been investigated.

本文设计合成了几个含有萘和蒽发色团的单氮杂15-冠-5化合物和用柔性链连接的双单氮杂15-冠-5化合物,研究了它们的光物理性质和自组装行为以及在溶液和气/液界面上的离子识别能力。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intramolecular singlet-singlet energy transfer .

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中噁二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与噁二唑、三苯胺功能团之间发生了分子内单线态—单线态能量转移。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intermolecular singlet-singlet energy transfer.

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中恶二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与恶二唑、三苯胺功能团之间发生了分子内单线态-单线态能量转移。

To improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide attached with azo chromophore side-chain is synthesized by diazo coupling reaction of 4-nitrohenzediazonium tetrafloroborate.

为了提高材料的非线性光学性能和偶氮染料发色团的稳定性能,通过对-稍基苯基重氮氟硼酸盐的重氮偶合反应,合成了侧链含偶氮非线性光学活性基团的聚酰亚胺材料,幷用红外光谱对其进行了结构表徵。

The results reveal that two energy transfer paths (i. e.β-PEB→α/β-PCB and β-PEB→α/βPCB′) with time constants of 50ps and 200ps, respectively, exist in R-PC monomers, and that α/β-PCB′chromophores are the terminal emitting acceptors with fluorescence lifetimes of 1150 ps. The experimental results of time-resolved fluorescence spectroscopy in case of R-PC trimers exhibit that the corresponding energy transfer processes are faster in R-PC trimers than in R-PC monomers, with time constants being 45ps, 165 ps and 920ps.

结果显示:在R-PC单体中存在2条能量传递途径,即β-PEB→α/β-PCB和β-PEB→α/β-PCB′能量传递过程,其时间常数分别为50ps和200ps;作为终端发色团的α/β-PCB′的荧光发射时间常数为1150ps.R-PC三聚体的时间分辨荧光光谱实验结果显示对应的能量传递过程速率加快,其时间常数分别为45ps,165ps和920ps。

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