发现物

But in the + moiety, the three benzimidazole rings shared the whole space equally, the dihedral angel among them is about 120°, just like three fan blades of an airscrew, the molecular structure appear gear-like shape.

X-射线单晶衍射测试、红外、紫外等方法确定了三(2-苯并咪唑亚甲基)胺的Fe和Co配合物的结构，由晶体结构发现金属配位情况不同、配合物在结构上存在着差异，Fe为八面体构型，而Co为三角双锥构型；其次，两配合物中的苯并咪唑环间夹角不同，配合物中包含N2和N4的两个苯并咪唑环间夹角仅为9.41(0.11)，几乎构成一个平面，呈蝴蝶形；后者Co三个苯并咪唑环几乎平分了整个空间，它们之间的夹角约为120，呈三扇叶螺旋桨式构型，为齿轮形。

Its bonding characterization and stability are discussed. The results show that these complexes are covalence complexes and that both the in-plane σ-bond and the in-plane π-bond in these complexes play an important role. The ESR spectra of VO -Ser system, VO -Ser-Phen system and VO -Ser-Bipy system in binary solvent glycol/water (V/V=1: 1) solution at various acidities (pH=1～14) have been observed at low temperature. It is found that in different pH ranges different structural complexes are formed.

测定了五种氨基酸席夫碱铜配合物的室温多晶粉末ESR谱、在不同溶剂中的室温及低温溶液ESR谱，确定配合物的配位环境；对室温溶液谱中观察到的二级效应和驰豫效应给予了理论解释、计算了驰豫参数；根据低温ESR波谱，计算了配合物的成键特性及稳定性，发现此类配合物为共价型配合物，平面内σ配键和平面内π配键均起重要作用。

Based on investigation of the moraine and outwash deposits in above regions, the authors find that they are very complicated Quaternary deposits with special composition, structure and properties. Their engineering properties are mainly related with the composition of the gravel and the filled material.

通过对上述地区大量冰碛物和冰水沉积物的现场调查发现，冰碛物和冰水沉积物是一类成分、结构和性质都十分复杂的第四纪堆积物，其工程性质主要与母岩成分和充填胶结物的矿物成分密切相关。

The above method can be used as a general method of determining molecular weight distribution of polymers.4.Solid-state ~1H wide-line NMR and ~(31)p magic angle spinningNMR were applied to a series of PEI/DNA complex samples with different PEI molecular weights and nitrogen/phosphatemolar ratios,in order to disclose the influence of various structural factors on the interactions and morphology.The results of ~1H NMR spectra showed that the linewidth of the PEI signal was greatly broadened with increasing the N/P ratio.Meanwhile,in the ~(31)p M_AS experiment,the signal was found to shift upfield with the increase of the N/P ratio.Both ~1H and ~(31)P NMR experiments demonstrated that the interaction between two constituents and subsequently the morphology of the complexes vary with the N/P ratio.

首次将固体核磁共振应用到聚合物/DNA复合物体系，观察复合物体系中不同N/P比对其相互作用和相结构的影响，研究表明N/P比的变化对聚乙烯亚胺/DNA基因递送体系分子水平上相互作用有着很大的影响；另外，还发现不同分子量的聚乙烯亚胺聚合物载体在N/P比为3的情况下对复合物中DNA的微观尺度没有明显影响；通过氢的自旋扩散实验，首次测得在PEI/DNA复合物体系中DNA相尺寸的大小，并发现在体系中N/P比达到3以上的复合物中DNA和PEI达到了分子水平上的相容。

Furthermore, the one-dimensional complexes 26 and 28 with strongπ-πpacking interactions are prepared from DMF solvent, which indicates that the traditional solvent volatilizing method could bring low-dimensional complex.4. By measuring the enthalpy changes of the liquid phase formation reaction for complexes a~e, and calculating the electronic densities of five 5-substituted derivation of isophthalic acid, we can make a conclusion that 5-substituted group changing of the ligand has a little influence on oxygen atoms of carboxyl groups.5. Fluorescence experiments of these complexes indicated that they could be used for luminescence materials in future.6. Using packing saturation rule we calculated and analyzed these series of complexes, and the results showed that the changes of complexes with changes of ligands could be explained from the rule.

在DMF溶剂中得到了具有强π-π堆积作用力的一维配位聚合物[Ln(5-NO_2-bdc)(NO_3)]Ln=Pr(26和Ho(28)，表明传统的溶剂挥发合成条件可以得到低维的配合物。4、通过配合物a～e的液相生成反应焓的测定，以及配体阳离子的电子密度计算，进一步佐证了间苯二甲酸的5位取代基变化对配体的羧基氧原子配位能力影响不大的结论。5、荧光特性表明此类配合物可以用于发光材料。6、利用堆积饱和规律对所得系列的配合物的进行计算和分析，发现随着配体的变化，配合物的变化可以从堆积饱和规律出发进行解释。

The results showed that the different molecular weight of the complexes of Chitosan with copperor zinc, the complexes of carboxymethyl Chitosan with copper and the low-molecular-weight iii complexes of sulfation chitosan with copper had excellent inhibition on Valsa mali. The low-molecular-weight complexes of chitosan with copper had inhibition on Botyosphaeria berengeriana. All of samples had no inhibition on Fusarinm oxysporium.f.sp.vasinfectum and Alternaria Solani under this test conditions.

结果 发现，不同分子量的壳聚糖 Cu、Zn配合物、羧甲基壳聚糖 Cu配合物及低分子量的壳聚糖硫酸酯 Cu配合物对苹果腐烂病菌有明显的抑制作用；低分子量壳聚糖 Cu配合物对苹果轮纹病菌有一定的抑制效果；所有配合物在试验浓度范围内，对棉花枯萎病菌和蕃茄早疫病菌均无抑制作用。

The blends of PE-g-MAH and gelatin were prepared by melting process and the compatibility of PE-g-MAH and gelatin in blends were characterized. The results of FTIR showed that the characteristic absorption band peaks of amine and amide groups of gelatin were shifted in PE-g-MAH/Gelatin blends, the equilibrium values of torque were higher with the increase of blending temperature, which proved that graft copolymer PE-g-MAH-g-gelatin was formed during the preparation process, and the amount of PE-g-MAH-g-gelatin was increased with increasing the amount of PE-g-MAH. SEM micrographs exhibited that there was PE-g-MAH-g-gelatin formed in surface of gelatin phase.

通过红外光谱分析、HAAKE流变分析、抽提等实验证明：共混物中明胶的氨基、酰胺基团吸收峰峰位发生了明显的变化；在熔融共混过程中，随着温度的提高，平衡扭矩增大；明胶与PE-g-MAH发生了反应形成PE-g-MAH-g-明胶接枝共聚物，而且随着PE-g-MAH用量的增加，形成接枝共聚物的量也提高；SEM的实验结果表明，在明胶的表面确有接枝物形成；通过DMA测试共混物的玻璃化转变温度，发现两组分的玻璃化转变温度差值减小，二者的相容性提高，实现了共混体系的自增容。

It was shown that the absorption peaks of amine and amide groups of gelatin were shifted in HDPE/PE-g-MAH/Gelatin blends because of the reaction of PE-g-MAH with gelatin. The addition of PE-g-MAH made the increase of HDPE glass transition temperature. The compatibilizing effect of PE-g-MAH was due to the crystal compatibility produced by forming the co-crystals of HDPE, PE-g-MAH and PE-g-MAH-g-gelatin. The blends of EAA and gelatin were prepared by melting process and the compatibility of the blends was also studied. The FTIR results showed that absorption peaks of amine and amide groups of gelatin were shifted in EAA/Gelatin blends.

通过红外光谱分析、HAAKE流变分析、抽提等实验证明：共混物中明胶的氨基、酰胺基团吸收峰峰位发生了明显的变化；在熔融共混过程中，随着温度的提高，平衡扭矩增大；明胶与PE-g-MAH发生了反应形成PE-g-MAH-g-明胶接枝共聚物，而且随着PE-g-MAH用量的增加，形成接枝共聚物的量也提高；SEM的实验结果表明，在明胶的表面确有接枝物形成；通过DMA测试共混物的玻璃化转变温度，发现两组分的玻璃化转变温度差值减小，二者的相容性提高，实现了共混体系的自增容。

The method is just like the QuikChange site-directed mutagenesis method except for its special primer. This pair of primers is composed of a long primer and a short primer which is central overlapped.Both of the Tm of 5\'sequence in long primer and Tm of 3\'sequence in short primer are above 66℃.The Tm of short primer is almost half of that of long primer.It is convenient to perform insertion or substitution mutation of DNA fragments larger than 20bp,In addition,it is highly applicable in research about the deletion mutation of DNA fragments larger than 2000bp.

我们实验室一直在寻找一种简单高效的可以用于基因的删除、插入及替代突变的方法，通过大量研究和实验发现，可以使用一种基于反向PCR原理，使用全新的引物设计的突变方法——&COP&突变法，该方法采用与QuikChange点突变法相同的操作步骤，其策略是设计一对中心重合的引物，长引物的5\'端序列和3\'端序列的Tm值均不低于66℃，短引物Tm值约为长引物一半，且与长引物中心重合互补。

Sediments of this system were sequentially extracted in natural granularity. The result showed that there was a good linear relationship between organic matter and org / bact P contents in sediments. This organic matter in sediments was the source of org / bact P. The total phosphorus in sediments dominated the content of total dissolved phosphorus and phosphate in interstitial water. In addition, there were good relatiohships between total phosphorus in sediment and the total dissolved phosphorus in interstitial water, and between total phosphorus in sediment and phosphate in interstitial water. FeP and AlP in sediments were correlative with Eh and phosphate in interstitial water, respectively. This showed that the FeP and AlP contents were affected by Eh in interstitial water and the total content of FeP and AlP dominated the content of phosphate in interstitial water.

对沉积物—间隙水中磷形态的连续提取分析发现，自然粒度下，沉积物中有机质含量与沉积物中有机/细菌聚合磷存在很好的线性相关性，说明沉积物中有机质是有机/细菌聚合磷的源；沉积物中总磷决定间隙水中总溶解性磷和溶解性磷酸盐的含量，并且总磷与间隙水中总溶解性磷和溶解性磷酸盐存在很好的相关性；沉积物中FeP和AlP分别与间隙水中的Eh和溶解性磷酸盐存在相关性，说明Eh的大小严重影响FeP和AlP的含量，但是FeP和AlP含量之和又主导着间隙水中溶解性磷酸盐的含量。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。