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Basing on thermo-simulation in laboratory, experimental study was accomplished to analyze the function mechanism of foaming agent and the foaming influence of its decompound production. The results indicated: function of foaming agents was due to their decompound and inter-reaction at high temperature. And some decompound production of foaming agent can reinforce the foaming ability of refining slag.

采用实验室模拟的方法,针对钢包精炼炉常用发泡剂的作用机理以及发泡剂高温分解产物对熔渣泡沫化性能的影响进行了研究,结果表明:发泡剂的作用主要来源于其组成物质的高温分解以及相互反应;发泡剂分解后部分产物作为高熔点粒子存在于熔渣中,提高了精炼渣的泡沫化性能。

Results indicate that, by PCS, vesicant particle can be well dispersed in the composite to form micropore composite. After frothing, the composite can keep high strength.

结果表明,通过PCS,ADC发泡剂微颗粒能够较好的分散于材料中以实现微孔发泡,发泡后材料能够保持较高的强度。

The influence of high temperature and high pressure on foaming agent's properties in opened and closed system, and influence of the change of foaming agent's properties on foaming capacity and foam stabilizing capacity are also studied. The multiple regression theory is used to establish the quantitative characteristic functions of foaming agent versus temperature and pressure. Based on the Gibbs Principle, the quantitative characterization is carried out on relation of foam system's free energy versus its surface tension, surface area and concentration, and the analysis of energy concluded that the disintegration of the foam is inconvertible. At the same time, the influence of change of foam's shape and structure on distribution of reservoir temperature and pressure is qualitatively described, and the coupling mechanism between temperature field, pressure field and chemical field is systematically expounded.

同时,研究了不封闭体系、封闭体系下高温、高压对发泡剂性质的影响,以及发泡剂性质的改变对其发泡性能、稳泡性能的影响;采用泡沫实验的相关结果,运用多元回归理论,建立温度、压力与发泡剂浓度的定量表征函数;基于Gibbs原理,对高温、高压下泡沫体系的自由能与其表面张力、体系中液体的表面积以及浓度关系进行定量化的表征研究,从能量的角度得出了泡沫衰变过程具有不可逆性;同时定性地描述了泡沫形态、结构的变化对油藏温度和压力分布的影响,系统地阐述了温度场、压力场、化学场间的耦合作用机理。

The present invention adopts polyvinyl perchloride and organosilicon modified acrylic resin as main filming material and adds cyanuramide phosphate and expanding graphite into common polytriammonium phasphate as fireproof assistant to constitute foaming material. The present invention has greatly raised foaming rate and the foamed layer has thickness of 30-50 times the original coating thickness and fireproof limit up to 90 min.

本发明采用高氯化聚乙烯和自行合成的有机硅改性丙烯酸酯树脂为主要成膜物质,并在通常所用的聚磷酸铵类防火助剂的基础上,加入三聚氰胺磷酸盐和可发性膨胀石墨作为发泡材料组成,大大提高了涂层的发泡率,发泡层厚度可达原涂层厚的30~50倍,耐火极限可达90min(涂层厚度2mm)。

Paper pulp and mixed blowing agent (sodium bicarbonate,potassium alum,starch,potas- sium D-bitartrate,and calcium carbonate) was used to produce the foaming pulp material.

以纸浆为原料,使用复合发泡剂(碳酸氢钠、钾明矾、淀粉、酒石酸氢钾、轻质碳酸钙),制作纸浆发泡缓冲材料,得到稳定的实验配方,所得发泡材料的静态缓冲系数在4~5之间。

The effect of additive is investgated by measuring solution loss, foam multiple, the quotiety of water retention, and the causation also are discussed.

通过测量发泡剂携液量、发泡倍数、保水系数的变化规律表征外加剂对发泡剂泡沫性能的影响,并对产生影响的原因进行了解释。

Based on the experiment of dissolving EPS plastics by two essential oils, 1g terpenoid oil dissolves 0.65g EPS plastics, after dissolving the volume of EPS plastics decreases to 5%; terpeneless compound can not dissolve EPS plastics.

实验研究了两类精油对发泡聚苯乙烯塑料的溶解效果。1g萜烯烃类精油溶解0.65g发泡聚苯乙烯塑料,溶解后的塑料体积约为原体积的5%。低萜精油不能溶解发泡聚苯乙烯塑料。

After the studies of basic material, citric acid/sodium carbonate, OBSH and Azodicarbonamide were used as foam agents of starch, fiber reinforced starch and starch/PVA blends. The expansion ratio and foam frame of the foams was studied.

在基础材料研究基础上,采用柠檬酸/碳酸钠、OBSH和AC发泡剂对淀粉、纤维增强淀粉和淀粉/PVA共混体系进行了挤出发泡研究,并就体系的发泡倍率和泡孔结构进行了研究。

In the paper the main topics are:(1) to analyze the chemistry composition, the X-ray diffraction, the DTA, and the functions of all raw materials;(2) to define the best direction for producing glass and foam glass, and the best burning technical process;(3) to characterize the unit weight and thermal conductivity of foam glass;(4) to analyze the reason of bubbling up, including the influence factor of temperature, time and so on;(5) to discuss the reasons of leading to shortcomings.There is high content quartz (SiO2) in the two gangues from gold mine and potassium feldspar mine respectively. They can be used to prepare glass, because the quartz (SiO2) is the main raw material.

论文的主要内容包括:1、对矿山尾矿的湿化学分析,粒度、X射线衍射和热稳定性的分析,以及硼砂、碳酸钙及制备泡沫玻璃的玻璃粉、磷酸钠实验原料在实验中的作用进行分析;2、确定尾矿烧结成玻璃体和利用玻璃体烧结泡沫玻璃的最佳配方以及两次烧结的最佳烧成工艺条件;3、泡沫玻璃制品的体积密度和导热系数等物理性能的测定;4、泡沫玻璃的发泡机理分析,包括发泡温度、发泡时间、发泡剂的用量、稳定剂的用量及其它因素对发泡作用的影响;5、讨论造成泡沫玻璃成品各种缺陷的原因及其解决方法。

In order to accomplish this change, our research have made several important break-through by revising new formulation especially in (1) catalyst mix,(2) adjustment of water content,(3) addition of chain extenders and crosslinkers, and(4) utilization of long-chained polyols. By doing so, the general performances of our new non-yellowing foam products are comparable to those of the traditional TDI based products. In certain mechanical properties in areas such as tensile strength, split tear strength, and elongation our measured values of 1.89 kg/cm2, 1.47 kg/cm, and 355 % respectively have out-performed the old materials.

能在研究中突破的原因,是因针对聚胺酯发泡体配方中的催化剂、水含量、链长剂种类、交联剂及搭配商业之改质长链三元醇,做各式各样之配方调整而成,与传统商业用之芳香族发泡体相比较,基本的成泡指数及性质相比拟上已相近,在抗张(1.89 kg/cm2,比TDI系统增加2.2倍)、撕裂(1.47 kg/cm,比TDI系统增加1.7倍)、延伸率(355 %,比TDI系统增加1.6倍)等机械性质上甚至比芳香族发泡体有更佳的表现。

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