发光的

The results showed the different fluorescence property with naphthalene due to the interaction, congruence of the molecules and formation of inter- or intramolecular exciplex.;A series of dithioesters with different aromatic rings such as naphthally, anthracyl and pyrene in R groups were synthesized. The polymerizations of MMA using these dithioesters as the RAFT agents were investigated.

结果表明：在NMNDT和它获得的聚合物溶液中，由于分子间的相互作用、叠合，激发态分子与基态分子形成了激基缔合物，引起了萘环荧光的淬灭，使其发光特性与原来萘的发光特性不同；探索了二硫代酯中R基团的立体和电子等性能对MMA的RAFT聚合的影响。

The emission of N_2 in discharge gap is detected using optical emission spectrophy. The discharge reactor was put in lightproof box to avoid the disturbance from outside lights. A small hole was drilled in one sidewall of the box, and the fibre was mounted coupling to the inlet (1mm) into the hole. A tube with the inner diameter of 1.1mm was set in the front of the hole. In this way, only the light from a certain direction emitted from the discharge reactor could transfer into the inlet through the tube. The reactor could be moved in the vertical direction of the fibre, and the spectrometry can collect the total emission along the fibre inlet in single-shot measurement.

利用光学发射光谱仪对多针对板电晕放电中放电间隙内的N_2发射光谱进行测量，放电反应器置于暗箱中以避免外界对光谱测量的影响，将光谱仪的光纤耦合入口固定在暗箱侧壁的小孔内，小孔孔径为光纤耦合入口直径，在小孔前方安装孔径为1.1mm的细直管，只采集与光纤耦合入口在同一直线上的发光，避免放电区其它区域的发光被同时接收。

Since the electroluminescence materials based on our national patents are very scarce, our main work is focused on the development of new materials. Several materials was synthesized, such as electron transport and host emitting materials: organometallics, oxadiazole and quinoline derivatives; hole-transport materials: aromatic amines H40, H41; and star-shaped molecule materials TPM, TIM etc.

在有机发光材料方面，由于现有的性能较好的发光材料，其专利大都掌握在国外大公司手中，国内具有自主知识产权的高性能材料很少，本文的工作主要集中在新材料的开发方面，在前人的基础上有所创新。

Here we introduced oxadiazole moiety to theside-chain of Ph-PPV to enhance the electron transport properties. The luminescenceefficiency and luminescence brightness (1.33cd/A, 9400 cd/m~2) of the Ph-PPV withside oxadiazole moiety are much higher than non-oxadiazole Ph-PPV (0.70 cd/A,2300 cd/m~2), and these polymers emitted green light which unaffected by theintroduction of oxadiazole moiety. Anthracene has a rigidity and planar structure which shows high photoluminescenceand thermo-stability.

结果表明，以十烷氧基作为间隔基使噁二唑单元键接在苯基取代PPV的侧链，所得材料制备的电致发光器件的效率和亮度(1.33cd／A，9400 cd／m~2)明显高于不含噁二唑单元的苯基取代PPV(0.70 cd／A，2300 cd／m~2)，噁二唑单元的引入并不影响材料的发光光色，膜状态下的荧光发射光谱和电致发光光谱均呈绿光发射。

The Er3＋up-converted luminescent process in oxyfluoride glass-ceramics is discussed and it is found that the non-quadratic relation between green up-converted luminescent intensity and pump power is caused by the strong cross-relaxation process of rare earth ions.

对稀土离子共掺杂系统，分析了Er3＋在铒镱共掺杂的氟氧化物玻璃陶瓷中的上转换发光过程，认为Er3＋绿色辐射的上转换发光强度与抽运激光功率的非平方关系是由于Er3＋和Yb3＋之间的强交叉弛豫过程引起的。

The thermal stability, Raman spectra, and upconversion luminescence spectra of lead halide-modified Tm~3+/Yb~3+-codoped tellurite glasses have been investigated, and the upconversion luminescence mechanism of Tm~3+/Yb~3+-codoped oxyhalide tellurite glasses were analyzed.

研究了卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃的热稳定性能、Raman光谱和上转换发光光谱，分析了Tm3+/Yb3+共掺氧卤碲酸盐玻璃的上转换发光机理。结果发现：混合卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃具有好的热稳定性能、低的声子能量、强的上转换蓝光。这表明混合卤化铅调整Tm3+/Yb3+共掺碲酸盐玻璃是一种上转换蓝光激光器的潜在基质材料

Quantum chemical CNDO/2 method has been performed to study 20 chloranlines on the electronic structure in order to analyze their toxicities to Photobacterium Phosphoreum. The correlation analysis and the step regression analysis are put in use in this paper.

研究氯苯胺类化合物的电子结构与发光菌毒性的关系，应用CNDO/2量子化学方法计算了20个氯苯胺类化合物的电子结构，探讨了发光菌在5、15、30 min时间内的半抑制浓度的负对数P(5-EC50)、P(15-EC50)、P(30-EC50)与化合物的电子结构的关系。

The molecular designs and synthesis of triarylamine-based picolinic acid derivatives used as ancillary ligands, and their cyclometalated iridium complexes used as red-and green-emitters, as well as optoelectronics properites of these compounds were investigated in order to solve current problems of organic/polymeric electroluminescent materials and devices.

本论文针对目前有机/聚合物电致磷光材料和器件存在的问题，开展了新型三芳胺吡啶羧酸类辅助配体及其红光和绿光环金属铱配合物电致磷光材料的分子设计、合成和光电性能研究，主要包括：(1)设计、合成了三种新型的三芳胺吡啶羧酸类双齿阴离子型辅助配体；(2)以三芳胺吡啶羧酸衍生物作为双齿阴离子型辅助配体，合成得到了两个系列的红光和绿光环金属铱配合物；(3)研究了三芳胺吡啶羧酸类辅助配体分子结构对环金属配合物的紫外吸收和光致发光性能的影响；(4)以环金属配合物为客体，聚芴和恶二唑衍生物为主体，制作了聚合物电磷光器件，研究了含三芳胺吡啶羧酸类辅助配体、环金属配合物客体材料和聚合物主体材料等分子结构对电致发光性能的影响。

In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物，并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能，具体内容包括以下几个部分：设计合成了3个中位直接被三芳胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三芳胺共轭体10a-c，通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

The results from ultraviolet spectroscopy and photo -luminescence spectroscopy revealed that:(1) Europium complexes based on neutral ligands, such as azaphenanthroline 2-aryl-5-(α-pyridyl)-1,3,4-ozadiazole had a strong UV absorbance at the wavelength of 290-350 nm and the characteristic PL spectrum of europium ion at 613 nm respectively;(2) The structures of ligands had a critical role influence on PL intensity of europium complexes.

紫外光谱和光致发光光谱研究表明：(1)以氮杂邻菲罗啉、2-芳基-5--1，3，4-噁二唑为中性配体的铕配合物在290～350nm左右都有强烈的紫外吸收，且在紫外光的激发下都能产生铕离子的特征光谱(613nm)；(2)配体的结构是影响铕配合物发光强度的关键因素之一。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。