发光基团

Effects of polymer structure on light-emitting properties were investigated by using different copolymerizing units, such as biphenyl and fluorene.

通过改变不同的共聚基团，如芴和联苯等，研究了聚合物结构对其发光性能的影响。

All of these results confirmed that the quenching effect of sulfur atom. The distance between sulfur atom and chromophore played an important role in the self-quenching effect.

通过实验，进一步证实了硫原子对发光基团的荧光淬灭作用，说明二硫代酯与发光基团之间的距离对硫的荧光淬灭作用有很大的影响。

Fluorescent switches and fluorescent sensors are supermoleculesconsisted of three parts — receptor, fluor and spacer.

荧光开关和荧光探针一般是由三部分组成的超分子，包括识别基团，发光基团和位于两者之间的隔离基团。

These Ir complexes, bearing the chromophore ligand pyridine, isoquinoline and quinazoline respectively, exhibit green-to-red photoluminescence with moderate to high quantum efficiencies in the degassed fluid state and bright emission in solid state.

首先，描述一系列含P^O辅助基的铱金属错合物发光材料之设计概念，这些铱金属错合物藉由pyridine， isoquinoline和quinazoline不同的发光基团调控，磷光放光可以由绿色改变至红色，不论在除氧的溶液态以及固态都有相当不错的量子效率，并且具有效率高、寿命长的优点。

The results showed the different fluorescence property with naphthalene due to the interaction, congruence of the molecules and formation of inter- or intramolecular exciplex.;A series of dithioesters with different aromatic rings such as naphthally, anthracyl and pyrene in R groups were synthesized. The polymerizations of MMA using these dithioesters as the RAFT agents were investigated.

结果表明：在NMNDT和它获得的聚合物溶液中，由于分子间的相互作用、叠合，激发态分子与基态分子形成了激基缔合物，引起了萘环荧光的淬灭，使其发光特性与原来萘的发光特性不同；探索了二硫代酯中R基团的立体和电子等性能对MMA的RAFT聚合的影响。

In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物，并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能，具体内容包括以下几个部分：设计合成了3个中位直接被三芳胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三芳胺共轭体10a-c，通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

Acetate groups charge ZnO nanocrystals negatively and passivate the surfaces,reducing the surface defects and visible emission centers. Resultantly, the increase of acetategroups lead to the quench of visible emission and improvement of photoluminescenceproperties. At appropriate concentrations, the hydroxide groups mainly passivate the surfaceand improve the photoluminescence properties.

研究发现，氢氧化锂/醋酸锌的比值对胶体氧化锌量子点的发光性质有重要影响；醋酸根基团通过使氧化锌粒子带负电荷并钝化其表面，使得氧化锌纳米点的表面缺陷和可见发射中心大大减少，因此醋酸根浓度的增大导致了可见发光的淬灭和发光性质的增强；氢氧根基团在中等浓度时主要起钝化氧化锌表面的作用，使产物的发光性质得到改善。

The carboxyl of the tripodal ligand is a goodbridging group. The building blocks are linked together by the bridging group andother weak interactions (hydrogen bond and π-π stacking interaction, etc), thusgenerating a one, two or three-dimensional metal complexes.2. Studies on the fluorescence properties of the lanthanide complexes indicated that:(1) The excitations in the ligand-based π-π〓 transitions cause the structuredemission of lanthanide complexes while the ligand luminescence is completelyquenched showing that ligand-to-metal energy transfer occurs.

三脚架配体所带的羧基是一个很好的桥联基团，配合物的结构基元通过这种基团的桥联作用及其它一些弱的作用力(如氢键、π-π堆积作用等)联系起来，构成了一维、二维或三维的超分子空间结构。2、稀土配合物的发光研究发现：(1)用配体的π-π〓跃迁波长进行激发，配合物均显示出稀土离子的特征发射峰，同时，配体的荧光峰没有出现，这说明在三脚架配体与稀土离子间进行了有效的能量传递。

This part includes chapter 5, 6, 7, 8, and chapter 9. In chapter 5, we synthesized four Ruthenium chelates, which can be used as ECL reagents. We also investigated their fluorescent properties as well as their electrochemical and ECL properties.

在第5章中，我们合成了四种带有标记基团的钌配合物电化学发光试剂，并对所合成的四种化合物的荧光性质、电化学性质及电化学发光性质等进行了初步探讨。

Further picosecond PL studies on dendronized PFs show that the fluorene-based emission in dilute solution follows a single exponential decay, whereas those in thin film decayed in a multi-phase manner and the lifetime prolongs with the generation of dendronization. These observations are discussed in terms of dispersive transport happening between adjacent chains in film. The dispersive relaxation can be controlled by site isolation of bulky dendrons. Our results prove that dendronization is highly effective in controlling the inter-chain interactions of fluorene-based polymers.

不同代数树枝化聚芴的时间分辨荧光动力学研究结果表明，溶液状态下的发光为单指数衰减行为，而薄膜状态下的发光为多指数衰减行为，且其发光寿命随树枝化代数增加而增长，表明树枝化基团抑制了邻近的聚芴分子之间能量传递所致的激发态能量耗散。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。