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反离子

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The neighbor-ing two Gd3+ ions are connected by two simple bridged carboxyl groups and a μ2-bridging carboxylgroup. Each G-d3+ ion is simuetaneosly coordinated by two water molecules. So the coordination num-ber of Gd3+ is nine, forming a coordination polyhedron of distorted mono capped square antiprism.

相邻Gd3+离子通过2个简单羧基桥和1个μ2羧基桥联结起来,还有2个水分子配位于每个Gd3+离子,所以Gd3+的配位数为9,形成变形的单帽四方反棱柱体。

The effects of ,, and temperature on the distribution ratio have been investigated. The composition of the extracted species is determined by the methods of slope ratio, continuous variation,extraction isotherm curves and their chemical analyses. The extraction is found to proceed according to the reaction:AuCl_4 ~-+DEOTA_(0)TAuCl3 .DEOTA_...

着重研究了盐酸浓度、氯离子浓度、氢离子浓度和温度诸因素对萃取的影响;对有机相中金的反萃行为也进行了初探;通过斜率法、等摩尔系列法、萃取等温线法确定了配合物的组成;推定了DEOTA在盐酸体系中萃取金的机理为配位取代反应;计算了萃取反应的表观平衡常数和配合物的稳定常数。

ABSTRACT The ionic strength of mobile phase can significantly affect the peak shape of ionogenic compounds such as antibiotics in reversedphase high performance liquid chromatography.

在反相高效液相色谱过程中。流动相的离子强度可显著影响可解离的化合物如抗生素的色谱峰形,原因在于流动相的离子强度较低时,色谱填料的固定相易于过载。

ABSTRACT The ionic strength of mobile phase can significantly affect the peak shape of ionogenic compounds such as antibiotics in reversedphase high performance liquid chromatography. The influence may be attributed to overloading of ionogenic analytes in lower ionic strength mobile phase.

在反相高效液相色谱过程中,流动相的离子强度可显著影响可解离的化合物如抗生素的色谱峰形,原因在于流动相的离子强度较低时,色谱填料的固定相易于过载,使离子化的化合物的色谱峰形呈典型的过载特征――峰形接近直角三角形。

ABSTRACT The ionic strength of mobile phase can significantly affect the peak shape of ionogenic compounds such as antibiotics in reversedphase high performance liquid chromatography. The influence may be attributed to overloading of ionogenic analytes in lower ionic strength mobile phase. In such phase, peak becomes increasingly rightangled triangle in shape with increasing sample load together with increasing peak width and tailing.

在反相高效液相色谱过程中,流动相的离子强度可显著影响可解离的化合物如抗生素的色谱峰形,原因在于流动相的离子强度较低时,色谱填料的固定相易于过载,使离子化的化合物的色谱峰形呈典型的过载特征――峰形接近直角三角形。

ABSTRACT ionic strength of mobile phase can significantly affect the peak shape of ionogenic compounds such as antibiotics in reversedphase high performance liquid chromatography. The influence may be attributed to overloading of ionogenic analytes in lower ionic strength mobile phase. In such phase, peak becomes increasingly rightangled triangle in shape with increasing sample load together with increasing peak width and tailing.

在反相高效液相色谱过程中,流动相的离子强度可显著可解离的化合物如抗生素的色谱峰形,原因在于流动相的离子强度较低时,色谱填料的固定相易于过载,使离子化的化合物的色谱峰形呈典型的过载特征――峰形接近直角三角形。

Contrasted with the activity of the same reaction in oil-water double phased system, the hydrolyzing behavior of Camlicla Lipolytica Lipase in reversed micellar systems is much like that in oil-water double phased system. The stability and catalyzing activity are both enhanced and give rise to "superactivity". except in reverse micelles composed of cationic surfactant.

实验表明,脂肪酶CLL在反胶束体系中催化水解反应的行为与油-水双相体系中的行为大体相似,在阴离子和非离子型表面活性剂构建的反胶束中,酶的稳定性和催化活性都有所增加,呈现&超活性&。

The authors carried many researches of the feasibility about enriching and separating trace zinc from almost cadmium, and the rate of recoveries of several common metal ions according to this methodo Through repeatedly probed and tried out, at last, a thought as collaborated with traditional methods was established - using diantipyrinylmethane as complex reagent ,with ammonium thiocyanate and zinc forming the triple ionic compound in the medium of hydrochloric acid , extracted by trichloromethane, extracted the organic system by ammonium hydroxide in order to gain zinc .

本文主要研究了从镉基体中富集分离微量锌的可行性,以及采用该方法几种常见金属离子的回收率。通过反复的摸索、试验,最终确立了与传统方法相结合的思路—采用二安替比林甲烷作为络合剂和硫氰酸铵、锌在盐酸介质中形成三元离子缔合物,用三氯甲烷作为萃取剂,最后用氨水作为反萃剂将有机相中的锌洗脱出来与镉分离。

It was found that the adding of non-ionic surfactant increased the activity and stability of enzymes.

原因是非离子表面活性剂分子降低了反胶束离子层的电荷密度,减弱了可导致酶变性的静电相互作用。

The result shows that to improve the anodic current efficiency, we should decrease the reactions in the anodic solution between dissolving chlorine and transferring sodium hydrate and reduce a series of the reactions between the anode and the cathode.

本论文首先阐述了氯碱工业生产技术发展历史,并介绍离子膜法电解产生、发展过程以及其发展方向,考察了影响电流效率的各种因素,并提出提高电流效率的措施,得出要提高阳极电流效率,就要尽量减少在阳极液中产生的溶解氯与迁移烧碱之间发生的副反应,减少阳极上氧的析出量;要提高碱的电流效率,就要尽量减少氢氧根离子向阳极室的反渗。

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