反应速率

Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程：由苯肼和3-甲基-2-丁酮合成腙；再冰醋酸催化生成2 ，3 ，3—三甲基—3H—吲哚；再经过碘甲烷发生烷基化反应生成吲哚碘化物；碘化物在NaOH下脱去一分子HI成为费歇尔碱；在乙醇为溶剂下加5－硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃；通过红外光谱和元素分析确证其结构，并研究了环体与开环体的光致变色性能，解释了在不同溶剂介质中紫外吸收光谱的溶剂效应，并比较褪色反应速率数的差异，最后将其掺加到甲基丙烯酸甲酯，过氧化二苯甲酰有机玻璃中，测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

The formation of our 1D nickel wires can be ascribed to the cooperative effect of the reaction rate and magnetic field.The reaction rate in the system is controlled mainly by adjusting the reactant concentration when other reaction conditions are fixed.When the concentration of Ni~(2+) is low,the reaction rate is correspondingly slow,so the complex[Ni(N_2H_4)_x]~(2+) preferentially migrates to the magnetic line of force since paramagnetic metal ions are attracted toward the maximum field.

当反应物Ni~(2+)浓度较低时，反应速率相对较慢，[Ni(N_2H_4)_x]~(2+)优先选择迁移到磁力线附近并且沿着磁力线方向排列，导致电极电势增大，于是[Ni(N_2H_4)_x]~(2+)的化学还原反应也是沿着磁力线发生，结果导致了镍纳米线的形成。

The effects of solvents and salts on the formation of a third liquid phase, distribution of catalyst, reaction mechanism and reaction rate in the reaction between n-butyl bromide and sodium phenolate with tetrabutylammonium bromide as a phase transfer catalyst were investigated.

中文摘要本文系针对以溴化四丁基铵为相间转移触媒催化正溴丁烷与酚化钠之反应，研究溶剂种类及盐类与碱类之添加量对形成第三液相、触媒分布、反应机构及反应速率之影响，被测试之溶剂包括氯苯、甲苯与正己烷，而在盐类与碱类效应的研究中，则测试溴化钠与氢氧化钠。

The solvent effects were studied with the conductor-like polarizable continuum model respectively in the solvents acetonitrile and water, and we found that the solvent effects reduce the activation energy, but the reduction is small, these reactions are not sensitive to the solvent polarity.

采用导电极化连续介质模型分别研究了在乙腈与水溶液中反应的溶剂化效应，发现这些溶剂可降低反应的活化能，但降低的程度比较小，反应速率变化不大。

In the field of visible photosensitive resin, the absorption spectrum, excited state, solvent polarity effect, fluorescence spectrum, fluorescence quenching, concentration effect, photo fading, reaction mechanism as well as photopolymerization kinetics of xanthene iodonium salts and cyanine dye-borate were discussed. It is found that under the radiation of visible light, intra-ion-pair electron transfer reactions occur in bis salt of fluorescein and unsymmetrical trimethine cyanines containing quinoline end group triphenyl-butylboron, and the fading rate is very high.

在可见光敏树脂部分，通过对呫吨染料碘鎓盐和菁染料-硼盐体系的吸收光谱性质、激发态性质、溶剂极性效应、荧光光谱、荧光猝灭、浓度效应、光褪色反应、光聚合动力学等的研究，结果发现：荧光黄双二苯基碘鎓盐体系和含喹啉环端基不对称三甲川菁染料-三苯基丁基硼盐体系在可见光作用下均发生离子对内电子转移反应，且光褪色反应速率很高。

The catalytic reaction rate constant for amidopyrine in different conditions are also determined, and the rate constants agreed closely with the mechanism presented by us.

讨论了影响其催化反应速度的因素及条件；并对不同条件下氨基比林对亚铁氰化钾的催化反应速率常数进行了测定，所得结果很好的符合提出的反应机理。

For thermodynamic and kinetic reasons, a relatively large number of materials can not be directively synthesized by self-propagating high-temperature synthesistechnology. In addition, SHS process is generally difficult to effectively control. These limitations retard the further development of SHS technology. In this project, the imposition of an external electric field is utilized to activate self-sustaining reactions and to simultaneously control SHS process.

为了扩大自蔓延高温合成技术的合成材料范围，并实现对SHS过程的有效控制，本项目分别以反应热小和反应速率低的反应体系为对象，利用外加电场诱发了体系的自蔓延燃烧，合成了在普通SHS工艺下难以合成的材料；同时，将外加电场作为SHS技术中一个重要的工艺参数，同步实现了对SHS过程的柔性控制。

Parameters in the kinetical equation have been work out. Decomposition reaction of MnCO〓 is followed the shrinking core model, and the control step is chemical reaction.

当离解反应结束后，已没有新的MnO表面产生，反应由通过较致密的MnO〓层氧扩散所控制，因此反应速率明显减慢。

The transesterification reaction among poly,poly(ethylene 2,6- naphthalate),and PET／PEN copolymer were studied with1H-NMR.

通过用1H-NMR对聚对苯二甲酸乙二酯与聚2，6-萘甲酸乙二酯、PET/PEN共聚物的共混物酯交换反应的研究，测得了反应速率常数、反应活化能和诱导期。

The nitrosification of suspended activated sludge of SBBR one-step completely nitrogen removal process could be defined as the first order reaction.

单级自养脱氮系统中悬浮态活性污泥的亚硝化反应可以近似按一级反应表示，反应速率随生物量的增加而增加。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。