反应速率

The mechanism of the dehydrogenation reaction of OsO〓 with methane For the reaction, OsO〓+CH〓→OOs〓+H〓, the minimum energy reaction path involves two PESs of quartet and doublet states.

因此整个反应的速率决定步骤是分子氢从二重态的亚甲基二氢化物中还原消去，能垒大约为30.4kcal/mol.c。

The concentrations of petroleum in photolytic processes were analyzed by UV-Vis.

结果表明，石油在土壤表面上的光化学降解行为符合准一级反应动力学，实验测得石油的光解速率常数为0.002 6-0.017 2 h^-1，半衰期为

The results of batch experiments showed that the anaerobic biodegradation kinetics of 2-CNB and 4-CNB by granular sludge were follwed by first-order reaction. The nitro groups of 2-CNB and 4-CNB were more easily attacked by electron than chlorines and they were reductively biotransformed to amino groups under anaerobic conditions. The acclimated anaerobic granular sludge, which could dechlorinate 4-chloroanline to aniline, showed that it had the ability of para-dechlorinating. The anaerobic biodegradating on pathway of 2-CNB and 4-CNB were suggested as follows:AbstractIn ZVI(zero-valent iron, Fe0)-reduction system, the nitro groups of 2-CNB and 4-CNB were reductively transformed to amino groups.

2分批试验结果证明，颗粒污泥降解2-CNB和4-CNB遵循一级动力学，在厌氧条件下，CNB发生序列的硝基还原与脱氯作用，苯环上的硝基比氯原子更容易受到亲电子攻击，发生还原反应生成氨基；所获得的颗粒污泥具有对位脱氯活性，可使4-CA进一步脱氯形成苯胺。2-CNB和4-CNB厌氧降解的建议性途径为： ZVI(Zero-valentiron)对2-CNB和4-CNB的作用主要是将苯环上的硝基还原为氨基；在ZVI与污泥共还原转化体系中，ZVI对氯代硝基苯的硝基转化具有一定的促进作用，但因ZVI对中间产物的吸附特性，终产物形成速率趋慢。

Dissolution process of a-TCP cement hardened body accords with the kinetic model equation: y =-ln =kt05 , its activation energy is 9.87 kJ/mol, which means dissolution is diffusion control. The dissolution mechanism of a-TCP cement may be considered as dissolution and reprecipitation of defective calcium hydroxy- apatite hydrated from a-TCP.

含有TTCH的a一TCP骨水泥固化体在生理盐水中的溶解动力学方程为：y二一In(1一x)=kto.4；溶解过程为扩散控制；其中含l%TTCH的骨水泥溶解反应活化能约为7.17kJ/mol，随着药物含量的增加，骨水泥固化体的溶解速率常数下降。

XRD results reveal that the addition of HF decreases the defects in the crystal lattice of SAPO 34, which is proved by the two distinct double peaks at 2 θ=26°and 31° and other ...

以氟化氢三乙胺复合模板剂合成的分子筛，在催化甲醇制低碳烯烃反应中结焦速率降低，生成乙烯及丙烯的选择性则略有提高

In this paper,the rate constant and equilibrium constant of the crack reaction of methyl silicane were obtained with the transition state theory and quantum chemistry calculation.

本文采用过渡态理论和量子化学计算方法，首次计算得到了甲硅烷裂解反应的速率常数和平衡常数，并对结果进行了讨论。

In the photopolymerization system of AN initiated by AQ and P , the polymerization rates sensitized by addition of carbon tetrabromide to AQ or P are much higher than that of AQ or P alone.

当在AQ引发的AN光聚合体系中，加入四溴化碳后，聚合速率明显加快，所得聚合物特性粘度低于不加四溴化碳的产物，证明四溴化碳与AQ在光照射下，形成激基复合物，参与了引发反应。

The rate constant was calculated by TST over a wide temperature range of

用TST方法计算了在600一1450K温度范围内各反应的速率常数。

His paper focus to research that how Tr and WUE of sexual-reproductive Vetiveria zizanioides under inundation respond to photosynthetic active radiation and CO2 concentrations doubling, we used LI-6400 Portable Photosynthesis System.

使用LI-6400便携式光合作用系统研究了淹水条件下有性繁殖香根草蒸腾速率和水分利用效率等光合生理生态参数对有效光辐射增强和CO2倍增的反应。

Taking into account the chemical reaction rate, internal diffusion and reaction heat, the theoretical model of regeneration process was established to investigate the regeneration within large coked catalyst particle.

综合考虑化学反应速率、内扩散和反应热的影响，建立单个催化剂颗粒表面烧焦过程的数学模型，模拟研究了粒径1000μm的球形催化剂的表面烧焦过程。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。