反应速率

The change of activity,specific rate,turnover frequency,acid coverage and the coverage ratio of acidic to alkalic surface area had a similar regularity with the change of the state and the composition of iron oxide precursor of catalyst.

随着母体铁氧化物性质和组成的变化，催化剂活性、质量反应速率、合成氨转换频率和表面酸覆盖度及其酸碱覆盖度的比例有相似的变化规律，即与Fe2+/Fe3+呈驼峰形变化曲线。

The results showed that the wastewaters from the production of dyestuff, rubber and assistants from individual discharging points had significant effects on nitrification,while some characteristic pollutants,sueh as aminobenzene,nitrobenzene,phenol as weU as Zn2+,Mn2+,and Ni2+,especially Ni2+,had obvious inhibiting effects on nitrification,resulting in obvious reduction of the rate of nitrificatiOn in the biochemical treatment system.

研究结果表明：来源于个别排放点的染料生产污水、橡胶生产污水、助剂生产污水对硝化作用有显著的影响，一些特征污染物如苯胺，硝基苯，苯酚及Zn2+，Mn2+，Ni2+均对硝化作用有明显的抑制作用，从而导致生化处理系统的硝化反应速率明显降低，而且以Ni2+最为显著。

From the results of time resolved measurements on the NCO radicals, the bimolecular rate constants for the reactions of NCO with SO2 and CS2 were obtained as (1.8±0.3)×10^(-11) and (3.1±0.4)×10^(-12)cm^3molecule^(-1)s^(-1), respectively.

得到了NCO自由基与SO2、CS2双分子反应速率常数分别为(1.8±0.3)×10^(-11)和(3.1±0.4)×10^(-12)立方公分molecule^(-1)s^(-1)。

When the hydrogenation was performed with ultrasonic irradiation, the reaction rate could be greatly enhanced while the selectivity to cinnamyl alcohol remained almost unchanged.

在加氢过程中使用超声辐射能大大提高反应速率而肉桂醇的选择性几乎保持不变。

A modified homogeneous flow model was introduced to calculate the flow field in RH degasser,thus getting rid of some earlier methods that are unavailable to be generalized,such as reducing the computation region or presetting the distribution of gas volume fraction.

分别对有、无旋转磁场作用时的RH系统进行了模拟计算。模拟结果表明：流场和脱碳过程与现有文献中实验结果相符合；当旋转磁场作用后，磁感应强度为0.04 T时，初期脱碳速度比无旋流作用时增加了约15%，这是由于旋流增加了系统的搅拌能，提高了脱碳反应速率。

Partial immersion blowing of gaseous oxygen can obviously increase the desiliconization velocity and greatly shorten treatment time.

浸入吹入部分气体O2，可显著提高前期(前10 min内)脱硅反应速率，大大缩短处理时间，且减少铁水温降。

The results show that the introducing of multivinyl monomer and CaCO3 can slow down polymerization rate to different extent.Using 1％～5％ trimethylolpropane trimetbacrylateor divinyl benzene,tight encapsulation of CaCO3 can be realized and beyond 94％PS cannot be extracted. The amount of crosslinker or emulsifier should be accommodated when the load amount of CaCO3 is increased.CaCO3 content in the product increases consequently with the increase of the loaded amount of CaCO3,which can be known from FT-IR and TGA.TEM observations reveal that when the load amount of CaCO3 is 14.8％,most CaCO3 particles are encapsulated and each latex particle contains one CaCO3 particle.Composite particles have well-defined core—shell structure and the thickness of polymer shells is around 10 nm.However,the thickness of polymer shell decreases and many free CaCO3 particles appear when the load amount of CaCO3 reaches 29.3％and 58.7％,respectively.

结果表明，多乙烯基单体以及碳酸钙的引入会使聚合反应速率有不同程度的降低；使用1%～5%的TMPTMA或DVB，可实现PS对碳酸钙颗粒的牢固包覆，不可抽提的PS达94%以上；当碳酸钙用量改变时，需要适当调整乳化剂和多乙烯基单体的用量；IR和TGA的结果表明，随着碳酸钙用量增加，产物中的碳酸钙含量也相应增加；TEM照片和计算结果显示，当碳酸钙用量为14.8%时，绝大部分碳酸钙颗粒被包覆，且基本上每个乳胶粒中包覆一个碳酸钙颗粒，复合粒子具有清晰的核壳结构，壳层厚度约为10 nm，而当碳酸钙用量增加到29.3%和58.7%时，壳层厚度减小，并且出现较多裸露的碳酸钙颗粒。

The batch seeded isothermal desupersaturation experiments of SPM in aqueous solution were carried out and the overall crystal growth kinetics parameters were determined by the nonlinear optimization techniques. Assuming that the volume diffusion rate at growth is equal to the mass transfer rate at dissolution under the same conditions, the two-step crystal growth rate parameters can be determined. At the fow supersaturation, the surface integration rate is proportional to relative surface supersaturation.

通过测量螺旋霉素均相成核动力学，获得了表面能的值，估算出表面熵因子的值在1.41～1.56之间，从而可以推断出螺旋霉素晶体生长的表面反应速率同表面相对过饱和度成线性关系，这种生长机理同第四章得到的结果是相吻合的；利用估算的表面熵因子的值，把螺旋霉素晶体看作为简单的立方科瑟尔晶体，根据能量最低原理，对螺旋霉素的晶体生长进行了模拟。

The results showed that (1) The grain size of nanometer YiO_2 was40～80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200～320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明：(1)CVD法制备的纳米TiO_2光催化剂，颗粒球形度好、粒径在40～80nm之间；最大吸光度值所对应的波长为200～320nm；含碳量约为4.6％；晶型组成主要为锐钛矿型，金红石的含量约为22.43％；(2)在相对湿度为8％～80％范围内，苯的光催化降解率随着相对湿度的增大而增大；甲苯在相对湿度为60％时达到最好降解效果，当相对湿度增大到80％时光催化效果降低；(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究，实验结果表明：三者最高降解率分别为84.5％、93.39％和93.45％；(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率；在日光灯的照射下，掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力；(5)较P25粉，在相同的光催化操作条件下：气相苯的平均降解率达15％，高于P25粉10％的降解率；气相甲苯在初始阶段具有较高的反应速率；气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

The effects of the dosage of H2O2 , initial concentration of humic acid, and initial pH were investigated.

探讨了H2O2浓度、腐殖酸初始浓度和起始溶液pH对反应速率的影响。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。