反应速率

Since the dismutation of superoxide radicals by SOD is a reaction that is rate-limited by diffusion and enhanced by electrostatic guidance, all these structural features may be related to GP-MnSOD's high catalytic activity: first, Lys38 may increase the effective enzyme-substrate association rate by enhancing the electrostatic gradient at its substrate channel; second, an excess of acidic over basic residues makes the negative surface potential of GP-MnSOD more larger than those of other known MnSODs. This may enhance the reaction rate by reducing futile collisions of superoxide radicals with GP-MnSOD's surface.

因此，GP-MnSOD的上述结构特征可能与GP-MnSOD的较高酶活有关：首先，Lys38增加了底物通道口的正静电势梯度，从而可能促进了GP-MnSOD的活性中心与底物的有效结合速率；其次，GP-MnSOD表面覆盖的过量酸性残基使得它比其它MnSOD在底物通道以外的蛋白表面更多地被负静电势所覆盖，这可能有效地减少了超氧阴离子与GP-MnSOD表面的无效碰撞，从而提高了反应速率。

Using Agilent 8453 ultraviolet-visible spectrophotometer, the affecting factors were studied on the kinetic processes in iodometry involved in the volatilization of iodine and the oxidation of iodide ion by dissolved oxygen, in particular such as the shape of the vessel, the volume of the solution tested, the concentration of KI and the temperature and the acidity of tested solution.

利用紫外－可见分光光度仪测量了I2挥发、I在酸性介质中被溶解氧氧化的动力学过程，着重研究了容器形状、溶液体积、KI浓度、温度等因素对I2挥发速率的影响以及溶液酸度与I氧化反应速率的关系。

The reaction also followed second-order kinetics with the rate constants of 3.45·10-4, 2.42×10-4, 1.36·10-4, 3.30×10-5, and 2.50×10-6L·mmol-1·h-1 for the molar := 20:1, 40:1, 60:1, 80:1, and 100:1, restively.

用初速率法测定反应速率常数为0.00253mmol×L-1×h-1。

The nanocomposite RE-W thermionic emission material can accelerate the active substance diffusion in the three aspects.

发射材料从反应速率，扩散距离及晶界扩散三方面来影响活性物质的扩散速率。

Secondly, the influences of pH value of buffer solutions on the dedolomitization of dolostone powders and the expansion of a reactive dolomitic limestone were investigated. A program was conducted to study the reaction and expansion of dolostone powders in compacts and pastes of cement, and that of dolomitic rocks with few clay and quartz in alkaline solutions and concrete.

第二部分研究了溶液pH值对白云岩粉料的去白云化反应速率及活性白云质灰岩膨胀速率的影响；分析了白云岩粉料在水泥压实体中、含很少粘土和石英的白云质岩石在碱溶液及混凝土中所发生的化学反应，并测定了伴随化学反应产生的膨胀。

For the cement, the surface hydration is the primary process at the initial stage, the kaolin disorganizes and gets into the solution in the form of the silicate tetrahedron and aluminate tetrahedron at the induce stage; the silicon-aluminum tetrahedron network structure is formed at the accelerate stage; the unti-network structure is formed and the rate of heat evolution falls at the decelerate stage; the reaction finished ultimately at the stable stage.

但其水化机理与传统的硅酸盐水泥不同：初始期主要是表面水化，诱导期是高岭土解体并以硅氧四面和铝氧四面体的形式进入液相；加速期形成硅铝四面体网络结构；减速期网络基本形成，水化放热速率降低；稳定期反应速率很低，网络结构趋于稳定。

Further, the intensity of specific bondings, C-C (285.0eV) and S-metal (162.0eV), of each sample were calculated using curve-fitting data.

后续的分析上，由C-C(~285.0eV)、S-metal(~162.0eV)两键结曲峰配凑的结果求得的衰退速率作为各组试验中反应速率比较的依据。

The adding of anatase nano-crystalline TiO_2 to the deposition solution accelerates the depositing of TiO_2 articles from the deposition solution on the silica glass fiber. A well-combined and durable TiO_2 thin film on silica glass fibers surface obtained by controlling the deposition temperature, deposition time, deposition cycles, concentration of the deposition solution, relative concentration of the deposition materials, pH value of the deposition solution. The effect of the deposition conditions, the drying conditions and the annealing treatment conditions on the surface morphology, section morphology, growth patterns, thickness of the deposited TiO_2 thin films were investigated. Growth rate and particle size of the thin films were controlled by the deposition conditions.

实验结果表明加入微量的锐钛矿型纳米TiO_2诱导晶可以使沉积液中析出的TiO_2粒子更大程度的以锐钛矿型纳米TiO_2粒子的形式析出；通过对沉积温度、沉积液中组分浓度及相对浓度、沉积溶液的pH值的调节与控制，从而控制沉积溶液中化学反应平衡的移动，研究了以上条件对沉积速率、沉积溶液中[Ti6]2–与—OH、[Ti6]2–之间的脱水聚合反应速率的影响，总结出了获得均匀致密质量较好的TiO_2薄膜的一系列实验参数，并对薄膜的生长模式进行了系统的分析研究；通过对沉积时间及沉积次数的分析，可以有效的控制TiO_2薄膜的厚度及质量；通过对薄膜的干燥条件及热处理条件的控制，可以使利用液相沉积法获得的TiO_2薄膜进一步晶化；并分析了对薄膜引起缺陷的主要原因。

The simulation points out a way for designing and manufacturing nanomaterials with totally different microstructures.2.The linear homopolymers have been added into a ABC 3-miktoarm star terpolymers system by dynamic density functional theory simulation. The areas of B phase domain and the interval between two nearest neighbour B phase domains shift with the accession of the linear polymer.3.A Petri net model was built to simulate the heat shock response in E.coli.

我们构建了大肠杆菌热休克反应的Petri网络模型，并应用化学反应动力学随机算法进行了模拟计算，观察其动力学过程，通过观测体系中平衡态下分子数目与反应速率常数间关系，总结了反应对体系平衡的影响规律，并由观测到的现象，对调控因子α的自身表达的调控机制作出推测：调控因子α的调控机制有可能是受网络控制的。4。

The results show that x does not change deuterating-dedeuterating reaction order. Activation energy increases while the rate constant decreases with x increasing. Deuterating and dedeuterating reaction order a (with respect to deutertium pressure) and b (with respect to deuterium content) are 2 and 1, 0.5 and 1, respectively.

研究结果表明，铝含量不改变合金的氘化与去氘化的反应级数；反应速率常数随x的增加而减少；活化能随x的增加而增加；氘化与去氘化反应级数 a和 b 分别为2和1及0.5和1。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。