反应速率

Kinetic reaction behavior of neo- polyhydric alcohols with fatty acids catalyzed by sulfuric acid was studied.

比较了Brnsted酸，包括硫酸、磷酸、对甲苯磺酸，催化季戊四醇与脂肪酸的酯化反应行为，结果表明，硫酸催化酯化反应速率最快，能有效催化不同类型的新戊基多元醇与脂肪酸的酯化反应，羟基转化率达到98%以上。

In order to discuss the regioselectivity of nitrile oxide 1,3-dipolar cycloaddition to propyne , 1,3-dipolar cycloaddition reaction of substituted nitrile oxide (RCNO, R=F, NO2, OCH3, OH, COOCH3, CHO, CONH2, H, CH3) with propyne was studied using density functional theory at the 6-311++G** level, and the reaction rates were calculated at different temperature from 200 to 400 K.

用密度泛函B3LYP/6-311++G**方法研究了氧化腈(RCNO，R=F，NO2，OCH3，OH，COOCH3，CHO，CONH2，H，CH3)与丙炔的1，3-偶极环加成反应，并且计算了不同温度下的反应速率常数，讨论了氧化腈上不同取代基R的取代效应和温度对反应区域选择性的影响。

As to the initial reaction rate,the influence of sulphation temperature is stronger than that of specific surface area of MgO.

提高MgO硫酸盐化的反应温度能够增加MgO变成MgSO4的转化率。就最初反应速率而言，硫酸盐化反应温度的影响大于比表面积的影响。

The experimental results indicate that the reaction rate exhibited first-order with respect to aniline and half-order to APS and dodecylbenzene sulfonic acid.

研究结果表明，苯胺的乳液聚合反应速率对苯胺是一级反应；对APS和十二烷基苯磺酸均为0.5级反应。

In addition, some transformation reactions of imines were also examined.

而且在水相中，反应速率有较大程度提高，反应条件更加温和，一些在有机相中不能发生的反应在水相中也能顺利进行。

Result and conclusion: The electrochemical experimental results show that the two totally irreversible oxidation peaks in the region of 0.3-1.2 V vs SCE for both MT and SR were observed,and the electrode reactions processes were diffusion-controlled.Their electron transfer number n and electron transfer coefficient α were obtained by CV and electrolysis with coulometry.The diffusion coefficient D and rate constant k f were also calculated by CC and CA.

结果与结论：在0.30~1.2 V电位窗口内，MT和SR均产生1个不可逆氧化峰，并且它们的电极反应均受扩散步骤控制；用控制电位电解库仑法和循环伏安法得到MT和SR的电极反应电子转移数n和电荷转移系数α，运用计时库仑法和计时电流法测定了它们的扩散系数 D 及电极反应速率常数kf。

At Hcy/Au electrode, there were electrocatalytic responses of DA and E with ΔEp 57.5mV and 63.5mV, respectively. The standard rate constants k〓 were calculated as 2.1×10〓 cm s〓 and 1.6×10〓 cm s〓 corresponding to DA and E. The electron transfer number n〓=1 was achieved, which revealed that the 2e transfer of DA and E is not completed by one step at the electrode. Because AA also displayed electrocatalytic behavior at Hcy/Au electrode, DA and E can be determined in presence of AA.At Hcy/Au electrode, a pair of very stable and well-defined redox waves of Mb were obtained.

在Hcy/Au电极上分别得到多巴胺、肾上腺素的一对可逆的氧化还原波，求出两者的电极反应速率常数分别为2.2×10〓cm s〓和1.6×10〓cm s〓，推导出在两者的电极反应过程中均存在一个自由基并且它的形成决定了整个电极反应的速度；由于抗坏血酸在此电极上也具有电催化响应，可以在抗坏血酸存在下对多巴胺和肾上腺素进行测定。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围内，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不随NaBr浓度增大而增大。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围內，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不隨NaBr浓度增大而增大。

The hydrolysis kinetics of two salicylates (n-butyl salicylate, phenyl salicylate) are studied in CTAB surfactant solution by using UV-vis spectroscopy.

应用UY—vis法，在不同温度条件下，对水杨酸酯在CTAB溶液中的水解反应进行跟踪，测定了不同浓度的表面活性剂存在下的反应速率常数，得出CTAB对其反应是禁阻作用。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。