反应速率

A reaction pathway for ammonolysis of O,O-dimethylphosphorochloridothioate without catalyst was proposed,based on the reaction mechanism of acyl halide ammonolysis ,and the pseudo-homogeneous reaction kinetics were founded.

模型表明：在反应前期，O，O-二甲基硫代磷酰氯浓度对速率影响很小，反应速率呈拟一级反应特征；但在反应后期，反应速率呈明显的二级反应特征。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示：复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素，它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性，还有乳液涂膜的接触角等造成不同程度的影响；引发剂主要影响反应速率和凝胶率；丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度，有机硅单体主要影响涂膜的吸水率等；聚合反应温度主要影响乳液的反应速率和转化率等；搅拌强度主要是影响到聚合过程的凝胶率。

Kinetics of methanol dehydration to dimethyl ether on modified kaolin catalyst was studied in an integral reactor under normal pressure. It is deduced that the surface reaction of methanol molecule adsorbed on the active site of catalyst with methanol molecule in gas phase is the rate determining step. The hyperbolic type kinetic equation r=ksbMpM2/(1+bMpM+bpE) is obtained according to the theory of langmuir even adsorption and using the R-E mechanism.

采用积分反应器，考察了常压下在改性高岭土催化剂上甲醇脱水生成二甲醚的反应动力学，根据Langmuir均匀吸附理论，采用R-E机理，推断吸附的甲醇分子与气相主体中的甲醇分子发生的表面反应为速率控制步骤，得到双曲线型动力学方程为： r= ksbMpM2 /(1+bMpM+bpE)（r为反应速率， ks为反应速率常数， bM为甲醇的吸附平衡常数， b为二甲醚和水的吸附平衡常数之和， pM、 pE分别为甲醇、二甲醚的分压）。

By using a fracture simulation unit,the regularity that temperature,flow rate and fracture width influence on HCl/dolomite reaction rate is investigated.The sequence of temperature,flow rate,acid concentration and fracture width influence to the acidic rock reaction rate is also studied in a four factors and four levels orthonormal test,and the sequence that acid concentration＞flow rate＞temperature＞fracture width is found.At the last,the possible HCl/dolomite reaction mechanism model which can explain the influence factors is derived.

文中利用人工模拟裂缝装置，研究了温度、注酸排量、裂缝宽度等因素对盐酸/白云岩反应速率的影响规律；并采用四因素四水平的正交试验，综合考察了温度、排量、酸浓度、缝宽四种因素对酸岩反应速率的影响的主次顺序，发现对酸岩反应速率影响力的大小次序为：酸浓度＞排量＞温度＞缝宽；最后，提出了盐酸/白云岩反应可能的机理模式，并根据这一模式对诸因素的影响进行了合理的解释。

In the first part, it was investigated the interaction between Pb2+ and La4Ti9O24 ceramic bulk. The result shows that a significant Pb2+ diffusion into La4Ti9O24 ceramic bulk and a significant crystallization of the La2/3TiO3-type phase is clearly observed in the Pb2+ diffusion layer. The reacted zone consists of the La2/3TiO3-type phase exhibits the linear dependence of the square of the thickness, x, on the heat-treated time, t, in excellent agreement with the parabolic law x2 = kt, where k is the growth rate coefficient. The kinetic study thus indicates that the Pb2+/La4Ti9O24 interaction strictly obeys the theory of the reactive diffusion. Furthermore, the experimental k values were used to determine the associated activation energy, Ea, for the formation of La2/3TiO3-type phase using the Arrhenius plot and the following least-square equation, ln =-Ea/RT + A, where T is the annealing temperature, R is the universal gas constant, and A is a constant, resulting in Ea ~ 607 ?b 60 kJ/mol.

首先， 以巨观的方式观察PbO与La4Ti9O24陶瓷体介面的反应现象；利用X-ray绕射分析以及扫描式电子显微镜来观察不同的热处理温度以及不同的持温时间所制作的样品，研究结果发现， Pb2+离子会渗入到La4Ti9O24陶瓷内，同时在Pb2+离子所渗入的区域内会产生新的La2/3TiO3-type钙钛矿斜方晶相；藉由量测不同温度与时间之样品，其因Pb2+离子渗入而产生之La2/3TiO3-type相层厚度之关系，符合反应式扩散机制中 x2 = kt 之关系式(其中 x：扩散层厚度； k：反应速率常数； t：反应时间)；进一步将不同实验条件所得到之反应速率常数值代入Arrhenius方程式ln (k =-Ea/RT + A ，其中Ea：活化能； T：绝对温度； R：气体反应常数； A：常数，可以求得Pb2+离子与La4Ti9O24陶瓷发生反应式扩散所需之活化能为607 ± 60 kJ/mol。

The rotating disc of Cu has been used to study the kinetics of Ag cementation on metallic Cu in ammoniacal solution. Two stages of reaction rate were found in this cementation process, i.e., an initial slow rate and a second enhanced rate.

用Cu的旋转圆盘研究了氨性溶液中Cu置换Ag的动力学，观察到有两段反应速率，即初始段反应速率慢和第二段反应速率增快。

The molar extinction coefficient, maximum absorption wavelength, reaction rate constants of trans-cis photochemical isomerization, thermal back-isomerization and photochemical back-isomerization and equilibrium constant of photochemical back-isomerization reaction of a novel photochromic liquid crystalline dendrimer G1 of the first generation containing nitroazophenyl groups on its periphery and small molecular azophenyl moiety M1 in solution were described.

张其震*1，盛昕1，李爱香1，王艳2摘要：研究了树外围含12个硝基偶氮苯基元新型一代碳硅烷光致变色液晶树枝状大分子G1和基元小分子M1在溶液中的最大吸收波长、摩尔消光系数、反-顺光化学异构化反应速率常数、热回复异构化反应速率常数、光化学回复异构化反应平衡常数及速率常数。

The metabolic confuse sth with sth else of the shift that will not balance and rate rises, if think chemistry balances Xiang Zheng to should move instead, so reacting rate greatens, the view of decrescent of reverse reaction rate is wrong.

不要将平衡的移动和速率的变化混同起来，假如认为化学平衡向正反应移动，那么正反应速率变大，逆反应速率变小的说法是错误的。

By use of titration analysis, the thesis investigated various factors such as isocyanate, PE molecular weight, reacting substance molecular ratio, reacting temperature and time etc. influencing upon prepolymerization step. It was found that 2, 4-tolulene diisocyanate and 4, 4'diphenylmethane diisocyanate is more rapidly reacted with PE600 than HDI. With PE molecular weight increasing, the reacting temperature or time should be raised or extended relevantly. Thus PE2000+2HDI pre-polymerization should be better carried out under some catalyst, for example, Triethylene diamine , Dibutyltin dilaurate and Tin octoate were used.

首先采用滴定分析方法对WRPU预聚反应的影响因素进行了研究：芳香族二异氰酸酯TDI、MDI比脂肪族二异氰酸酯HDI反应活性高，其中TDI在反应初始阶段的反应速率比MDI快，不过随着反应的进行，MDI比TDI反应速率加快，这主要是因为TDI分子中的两个-NCO反应活性差异大所致；二元醇分子量越大，反应速度越慢；聚醚二元醇比聚酯二元醇的反应速度快；当分子量超过2000的二元醇与HDI进行预聚反应时，需借助适当的催化剂来加快反应速度，从而使预聚反应能够顺利进行，分别选择DABCO、TOA和DBDTL三种催化剂进行催化反应，发现不同的催化剂，其催化效果相差较大。

It is shown that the chlorinating process for fluorine-fixed calcine agreed well with the regional reaction rate model presented by Bagdasarym. The process consisted of two tandem steps, Erofeev Equation ln[ln(1a)]=lnk+nlnt was used to deal with the equation of reaction rate,the function between rate constant and temperature was k=2.7?07e125900/RT. The a...

结果表明：固氟焙砂的氯化反应动力学过程是区域反应速率模型，氯化反应过程经过了2个串联反应步骤，用Erofeev方程ln[ln(1a)]=lnk+nlnt处理反应速率，反应速率常数与温度T的函数关系式为k=2.7107eEa/RT，表观活化能Ea为125.9 kJ/mol，过程限制环节主要是界面化学反应控制。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。